Search Results - "Rameshan, Raffael"
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Support effect on the reactivity and stability of Au25(SR)18 and Au144(SR)60 nanoclusters in liquid phase cyclohexane oxidation
Published in Catalysis today (01-10-2019)“…[Display omitted] •Under pretreatment, supported Au144 cluster structure is more stable than Au25.•Clear cluster size/structure and support effect on the…”
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Role of Precursor Carbides for Graphene Growth on Ni(111)
Published in Scientific reports (08-02-2018)“…Surface X-ray Diffraction was used to study the transformation of a carbon-supersaturated carbidic precursor toward a complete single layer of graphene in the…”
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Modifying the Surface Structure of Perovskite-Based Catalysts by Nanoparticle Exsolution
Published in Catalysts (01-03-2020)“…In heterogeneous catalysis, surfaces decorated with uniformly dispersed, catalytically-active (nano)particles are a key requirement for excellent performance…”
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In Situ Growth of Exsolved Nanoparticles under Varying rWGS Reaction Conditions—A Catalysis and Near Ambient Pressure-XPS Study
Published in Catalysts (01-12-2021)“…Perovskite-type oxides are highly flexible materials that show properties that are beneficial for application in reverse water-gas shift processes (rWGS). Due…”
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High Temperature Water Gas Shift Reactivity of Novel Perovskite Catalysts
Published in Catalysts (01-05-2020)“…High temperature water-gas shift (HT-WGS) is an industrially highly relevant reaction. Moreover, climate change and the resulting necessary search for…”
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Novel Sample-Stage for Combined Near Ambient Pressure X-ray Photoelectron Spectroscopy, Catalytic Characterization and Electrochemical Impedance Spectroscopy
Published in Crystals (Basel) (01-10-2020)“…For an in-depth characterization of catalytic materials and their properties, spectroscopic in-situ (operando) investigations are indispensable. With the rapid…”
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Enhancing Electrochemical Water-Splitting Kinetics by Polarization-Driven Formation of Near-Surface Iron(0): An In Situ XPS Study on Perovskite-Type Electrodes
Published in Angewandte Chemie (23-02-2015)“…In the search for optimized cathode materials for high‐temperature electrolysis, mixed conducting oxides are highly promising candidates. This study deals with…”
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Operando Insights into CO Oxidation on Cobalt Oxide Catalysts by NAP-XPS, FTIR, and XRD
Published in ACS catalysis (07-09-2018)“…Cobalt oxide Co3O4 has recently emerged as promising, noble metal-free catalyst for oxidation reactions but a better understanding of the active catalyst under…”
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Absorbance-based Spectroelectrochemical Sensor for Determination of Ampyra Based on Electrochemical Preconcentration
Published in Sensors and actuators. B, Chemical (01-12-2020)“…[Display omitted] •Ampyra can be selectively electropolymerized.•A colored film on the surface of FTO/AgNPs as an optically transparent electrode.•The…”
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Cu-doped perovskite-type oxides: A structural deep dive and examination of their exsolution behaviour influenced by B-site doping
Published in Catalysis today (01-07-2024)“…Perovskite-type oxides have gained significant attention in the scientific community due to their unique properties and potential applications. Their ability…”
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Enhancing Electrochemical Water-Splitting Kinetics by Polarization-Driven Formation of Near-Surface Iron(0): An In Situ XPS Study on Perovskite-Type Electrodes
Published in Angewandte Chemie International Edition (23-02-2015)“…In the search for optimized cathode materials for high‐temperature electrolysis, mixed conducting oxides are highly promising candidates. This study deals with…”
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12
Ambient Pressure XPS Study of Mixed Conducting Perovskite-Type SOFC Cathode and Anode Materials under Well-Defined Electrochemical Polarization
Published in Journal of physical chemistry. C (28-01-2016)“…The oxygen exchange activity of mixed conducting oxide surfaces has been widely investigated, but a detailed understanding of the corresponding reaction…”
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13
Operando probing of the surface chemistry during the Haber–Bosch process
Published in Nature (London) (11-01-2024)“…The large-scale conversion of N 2 and H 2 into NH 3 (refs. 1 , 2 ) over Fe and Ru catalysts 3 for fertilizer production occurs through the Haber–Bosch…”
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14
Structural modification of perovskites by tailored exsolution for enhanced catalytic activity
Published in Acta crystallographica. Section A, Foundations and advances (18-08-2019)“…Abstract only…”
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Structural and kinetic aspects of CO oxidation on ZnOx-modified Cu surfaces
Published in Applied catalysis. A, General (25-02-2019)“…[Display omitted] •Temporarily enhanced CO-oxidation reaction observed at Cu0/ZnO interface.•Mechanistic explanation of temporary nature.•Cu0/ZnO interface…”
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How reduction temperature influences the structure of perovskite-oxide catalysts during the dry reforming of methane
Published in RSC sustainability (31-10-2024)“…Dry reforming of methane is a promising reaction to convert CO and combat climate change. However, the reaction is still not feasible in large-scale industrial…”
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Tailored exsolution of metal nanoparticles: structural and chemical characterisation of doped perovskites by XPS and XRD
Published in Acta crystallographica. Section A, Foundations and advances (18-08-2019)“…Abstract only…”
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Ca‐doped rare earth perovskite materials for tailored exsolution of metal nanoparticles
Published in Acta crystallographica Section B, Structural science, crystal engineering and materials (01-12-2020)“…Perovskite‐type oxide materials (nominal composition ABO3) are a very versatile class of materials, and their properties are tuneable by varying and doping A‐…”
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Perovskite-Type Oxide Catalysts in CO2 Utilization: A Principal Study of Novel Cu-Doped Perovskites for Methanol Synthesis
Published in Compounds (01-12-2022)“…Six different perovskite-type oxides were investigated with respect to their ability for methanol synthesis via H2 and CO2: Fe-, Mn-, and Ti-based perovskites…”
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Near-Ambient-Pressure X‑ray Photoelectron Spectroscopy Study of Methane-Induced Carbon Deposition on Clean and Copper-Modified Polycrystalline Nickel Materials
Published in Journal of physical chemistry. C (03-12-2015)“…In order to simulate solid-oxide fuel cell (SOFC)-related coking mechanisms of Ni, methane-induced surface carbide and carbon growth was studied under…”
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