Search Results - "Ramachandran, P"
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1
One-Pot, Tandem Reductive Amination/Alkylation–Cycloamidation for Lactam Synthesis from Keto or Amino Acids
Published in Journal of organic chemistry (17-11-2023)“…Monotrifluoroacetoxyborane-amines, prepared by treating borane-amines with trifluoroacetic acid, have been shown to be efficient reagents for a one-pot, tandem…”
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2
Ammonia-borane as a Catalyst for the Direct Amidation of Carboxylic Acids
Published in Organic letters (16-04-2021)“…Ammonia-borane serves as an efficient substoichiometric (10%) precatalyst for the direct amidation of both aromatic and aliphatic carboxylic acids. In situ…”
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3
Trimethyl Borate-Catalyzed, Solvent-Free Reductive Amination
Published in Journal of organic chemistry (05-03-2021)“…Solvent-free reductive amination of aldehydes and ketones with aliphatic and aromatic amines in high-to-excellent yields has been achieved with…”
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4
Comparative Human Salivary and Plasma Proteomes
Published in Journal of Dental Research (01-10-2010)“…The protein compositions, or the proteomes, found in human salivary and plasma fluids are compared. From recent experimental work by many laboratories, a…”
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Book Review Journal Article -
5
Amine-boranes as Dual-Purpose Reagents for Direct Amidation of Carboxylic Acids
Published in Organic letters (06-11-2020)“…Amine-boranes serve as dual-purpose reagents for direct amidation, activating aliphatic and aromatic carboxylic acids and, subsequently, delivering amines to…”
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6
Titanium-Mediated Reduction of Carboxamides to Amines with Borane-Ammonia
Published in Molecules (Basel, Switzerland) (01-06-2023)“…In this study, the successful titanium tetrachloride-catalyzed reduction of aldehydes, ketones, carboxylic acids, and nitriles with borane-ammonia was extended…”
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7
Preparation of Ammonia Borane in High Yield and Purity, Methanolysis, and Regeneration
Published in Inorganic chemistry (17-09-2007)“…Ammonia borane (AB) is emerging as a promising solid hydrogen carrier, particularly for power generation in portable devices that employ proton-exchange…”
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8
A Safer Reduction of Carboxylic Acids with Titanium Catalysis
Published in Organic letters (25-11-2022)“…Ammonia-borane, shown previously to react with carboxylic acids under reflux to form primary amides, reduces acids to alcohols at room temperature in the…”
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9
Room Temperature Reduction of Titanium Tetrachloride-Activated Nitriles to Primary Amines with Ammonia-Borane
Published in Molecules (Basel, Switzerland) (21-12-2022)“…The reduction of a variety of aromatic and aliphatic nitriles, activated by a molar equivalent of titanium tetrachloride, has been achieved at room temperature…”
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10
Female ageing affects the DNA repair capacity of oocytes in IVF using a controlled model of sperm DNA damage in mice
Published in Human reproduction (Oxford) (27-03-2020)“…Abstract STUDY QUESTION Does female ageing have a negative effect on the DNA repair capacity of oocytes fertilised by spermatozoa with controlled levels of DNA…”
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11
TiCl4‑Catalyzed Hydroboration of Ketones with Ammonia Borane
Published in Journal of organic chemistry (07-10-2022)“…Investigation of a variety of Lewis acids for the hydroboration-hydrolysis (reduction) of ketones with amine-boranes has revealed that catalytic (10 mol %)…”
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12
Liver fibrosis: a bidirectional model of fibrogenesis and resolution
Published in QJM : An International Journal of Medicine (01-09-2012)“…Liver fibrosis is the generic response to chronic injury of varying aetiologies. A number of common mechanisms link this response to the pathogenesis of…”
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13
Dehydroborylation of Terminal Alkynes Using Lithium Aminoborohydrides
Published in Molecules (Basel, Switzerland) (13-04-2023)“…Dehydrogenative borylation of terminal alkynes has recently emerged as an atom-economical one-step alternative to traditional alkyne borylation methodologies…”
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14
Catalyst- and Stoichiometry-Dependent Deoxygenative Reduction of Esters to Ethers or Alcohols with Borane–Ammonia
Published in Organic letters (22-09-2023)“…A facile and selective room temperature deoxygenation of both aromatic and aliphatic carboxylic esters to ethers has been achieved by regulating the…”
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15
Borane-Pyridine: An Efficient Catalyst for Direct Amidation
Published in Molecules (Basel, Switzerland) (01-01-2024)“…Borane-pyridine acts as an efficient (5 mol%) liquid catalyst, providing improved solubility for the direct amidation of a wide range of aromatic and aliphatic…”
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16
Balancing Lewis Acidity and Carbocation Stability for the Selective Deoxyhalogenation of Aryl Carbonyls and Carbinols
Published in Organic letters (30-06-2023)“…Deoxyhalogenation of aryl aldehydes, ketones, carboxylic acids, and esters has been achieved utilizing an appropriate metal halide Lewis acid acting as a…”
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17
Titanium tetrafluoride catalysis for the dehydrative conversion of diphenylmethanols to symmetric and unsymmetric ethers
Published in RSC advances (26-07-2024)“…In contrast to the conversion of diphenylmethanol to the corresponding halides with an equivalent of titanium tetrachloride or -bromide, catalytic (50 mol%)…”
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18
Aryl carbonyls and carbinols as proelectrophiles for Friedel-Crafts benzylation and alkylation
Published in RSC advances (10-05-2024)“…Friedel-Crafts benzylation/alkylation using benzylic, tertiary, and homobenzylic alcohols; aryl aldehydes, aryl ketones, and the highly challenging aryl…”
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19
Role of Tim4 in the regulation of ABCA1+ adipose tissue macrophages and post-prandial cholesterol levels
Published in Nature communications (21-07-2021)“…Dyslipidemia is a main driver of cardiovascular diseases. The ability of macrophages to scavenge excess lipids implicate them as mediators in this process and…”
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20
TiF4-mediated, one-pot, reductive amination of carboxylic acids with borane–ammonia
Published in RSC advances (24-09-2024)“…A facile one-pot, two-step, reductive alkylation of amines with carboxylic acids has been achieved with BH3–NH3 as an air- and moisture-stable reductant in the…”
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