Search Results - "Ramírez de Arellano, Carmen"
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1
Synthesis of Oxaspiranic Compounds through [3 + 2] Annulation of Cyclopropenones and Donor–Acceptor Cyclopropanes
Published in Journal of organic chemistry (16-01-2015)“…The Sc(OTf)3-catalyzed [3 + 2]-annulation reaction between cyclopropenones and donor–acceptor cyclopropanes is described. The process leads directly to the…”
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2
Competitive Gold-Activation Modes in Terminal Alkynes: An Experimental and Mechanistic Study
Published in Chemistry : a European journal (13-01-2014)“…The competition between π‐ and dual σ,π‐gold‐activation modes is revealed in the gold(I)‐catalyzed heterocyclization of 1‐(o‐ethynylaryl)urea. A noticeable…”
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3
Ion Pair Recognition Receptor Based on an Unsymmetrically 1,1′-Disubstituted Ferrocene–Triazole Derivative
Published in Journal of organic chemistry (16-11-2012)“…The ferrocene–triazole derivative 4, available from 1,1′-bis(diazido)ferrocene by sequential functionalization through click-type chemistry and the Staudinger…”
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4
Remote Control by π‑Conjugation of the Emissive Properties of Fischer Carbene-BODIPY Dyads
Published in Inorganic chemistry (21-03-2016)“…The synthesis, structure, and complete characterization of mono- and bimetallic dyads joining Fischer carbene complexes and BODIPY chromophores are reported…”
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5
NHC-Stabilized Gold(I) Complexes: Suitable Catalysts for 6-exo-dig Heterocyclization of 1-(o-Ethynylaryl)ureas
Published in Organic letters (07-05-2010)“…3-substituted 1-(o-ethynylaryl)ureas 1 selectively undergo either 6-exo-dig or 5-endo-dig cyclization (to give 4-methylene-3,4-quinazolin-2-ones 2 or indoles…”
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6
On the Use of Metal Purine Derivatives (M=Ir, Rh) for the Selective Labeling of Nucleosides and Nucleotides
Published in Chemistry : a European journal (24-03-2014)“…The reactions of neutral or cationic IrIII and RhIII derivatives of phenyl purine nucleobases with unsymmetrical alkynes produce new metallacycles in a…”
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7
Direct Assembly of Polyarenes via C−C Coupling Using PIFA/BF3·Et2O
Published in Journal of the American Chemical Society (29-12-2010)“…Direct oxidative Kita-type coupling between naphthalene and substituted benzenes was found to proceed via four-component coupling, leading to a linear…”
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8
Electrocatalytic Behavior of Tetrathiafulvalene (TTF) and Extended Tetrathiafulvalene (exTTF) [FeFe] Hydrogenase Mimics
Published in ACS Organic & Inorganic Au (02-02-2022)“…TTF- and exTTF-containing [(μ-S2)Fe2(CO)6] complexes have been prepared by the photochemical reaction of TTF or exTTF and [(μ-S2)Fe2(CO)6]. These complexes…”
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9
Alternating Ferro/Antiferromagnetic Copper(II) Chain Containing an Unprecedented Triple Formato/Hydroxido/Sulfato Bridge
Published in Inorganic chemistry (07-03-2016)“…The first example of a triple formato/hydroxido/sulfato (FHS) bridge for any metal is reported in compound [Cu2(bpym)(OH)(HCO2)(SO4)(H2O)2]·3H2O (1). Its…”
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10
Synthesis of Known and Previously Inaccessible Poly(pyrazolyl)Borates under Mild Conditions
Published in Journal of organic chemistry (07-07-2023)“…Poly(pyrazolyl)borate ligands have been obtained through the reaction of highly reactive haloboranes with in situ formed pyrazolides under very mild…”
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11
Host-Guest Chemistry: Oxoanion Recognition Based on Combined Charge-Assisted C−H or Halogen-Bonding Interactions and Anion⋅⋅⋅Anion Interactions Mediated by Hydrogen Bonds
Published in Chemistry : a European journal (23-05-2016)“…Several bis‐triazolium‐based receptors have been synthesized and their anion‐recognition capabilities have been studied. The central chiral 1,1′‐bi‐2‐naphthol…”
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12
Heteropolymetallic [FeFe]-Hydrogenase Mimics: Synthesis and Electrochemical Properties
Published in Inorganic chemistry (27-02-2023)“…The synthesis and electrochemical properties of tetranuclear [Fe2S2]-hydrogenase mimic species containing Pt(II), Ni(II), and Ru(II) complexes have been…”
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13
Properties of a Triazolopyridine System as a Molecular Chemosensor for Metal Ions, Anions, and Amino Acids
Published in Journal of organic chemistry (24-11-2006)“…The characteristics as a chemosensor of the compound 3-methyl-6,8-di(2-pyridyl)-[1,2,3]triazolo[5‘,1‘:6,1]pyrido[2,3-d]pyrimidine (1) have been analyzed…”
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14
Triazole-Containing [FeFe] Hydrogenase Mimics: Synthesis and Electrocatalytic Behavior
Published in Inorganic chemistry (02-12-2019)“…Through a Cu-catalyzed Huisgen cycloaddition between terminal alkynes and azides (CuAAC) reaction, azide [(μ-SCH2)2N(4-N3C6H4)Fe2(CO)6] has demonstrated to…”
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15
Single Heteroatom Fine-Tuning of the Emissive Properties in Organoboron Complexes with 7‑(Azaheteroaryl)indole Systems
Published in Journal of organic chemistry (15-04-2016)“…The application of organoboron compounds as light-absorbing or light-emitting species in areas as relevant as organic electronics or biomedicine has motivated…”
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16
Dual Role of Vinyl Sulfonamides as N‐Nucleophiles and Michael Acceptors in the Enantioselective Synthesis of Bicyclic δ‐Sultams
Published in Advanced synthesis & catalysis (06-08-2018)“…A new methodology for the synthesis of enantiomerically enriched bicyclic δ‐sultams is described, involving an initial organocatalytic intramolecular…”
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17
An Entry to Mixed NHC-Fischer Carbene Complexes and Zwitterionic Group 6 Metal Alkenyls
Published in Chemistry : a European journal (12-09-2016)“…The addition of NHCs to α,β‐unsaturated Cr0 and W0 (Fischer) carbene complexes is strongly dependent on the electrophilicity of the carbene carbon…”
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18
Preorganized Fluorescent Receptor for the Preferential Binding of the Glutarate Anion
Published in European journal of organic chemistry (01-08-2016)“…A carbazolo[1,2‐a]carbazole‐2,11‐dicarboxamide has been synthesized and studied as a dicarboxylate anion receptor. The preorganized structure of this ligand…”
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19
Sequential Reactions of Alkynes on an Iridium(III) Single Site
Published in Chemistry : a European journal (03-07-2017)“…Sequential insertion of terminal alkynes on IrIII cyclometalated complexes allow the formation of novel metallapolycycles in a controlled and efficient manner…”
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20
Asymmetric Synthesis of Fluorinated Amino Macrolactones through Ring-Closing Metathesis
Published in Journal of organic chemistry (09-11-2007)“…The synthesis of new chiral fluorinated amino and azamacrolactones of types 1 and 2 is described. A ring-closing metathesis (RCM) reaction constitutes the key…”
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