Search Results - "Rakhlin, V. I"
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Thermal properties of some organosilicon precursors for chemical vapor deposition
Published in Journal of thermal analysis and calorimetry (01-11-2016)“…Five volatile organosilicon compounds: trimethyl(phenyl)silane Me 3 SiC 6 H 5 ( I ), trimethyl(cyclohexyl)silane Me 3 SiC 6 H 11 ( II ),…”
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2
Preparation of a mixed Mg–Si cellosolvate
Published in Inorganic materials (01-12-2016)“…We have studied reactions of metallic magnesium with ethyl cellosolve and a mixture of ethyl cellosolve and tetraethyl orthosilicate and demonstrated the…”
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3
Synthesis and investigation of properties of N-[[bis(trimethylsilyl)amino](fluoro)boryl]-(trimethyl)-N-(trimethylsilyl)silanamine
Published in Glass physics and chemistry (01-03-2014)“…The synthesis and investigation of properties of N-[[bis(trimethylsilyl)amino](fluoro)boryl]-(trimethyl)-N-(trimethylsilyl)silanamine as a possible precursor…”
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4
Tris(diethylamino)silane—A new precursor compound for obtaining layers of silicon carbonitride
Published in Glass physics and chemistry (01-02-2012)“…Silicon carbonitride layers have been obtained by chemical deposition from the gas phase with thermal (LPCVD) and plasma (PECVD) activation of the gas mixture…”
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5
Plasma enhanced chemical deposition of nanocrystalline silicon carbonitride films from trimethyl(phenylamino)silane
Published in Glass physics and chemistry (01-06-2011)“…Synthetic process for nanocrystalline silicon carbonitride films was developed using plasma-chemical decomposition of a new organosilicon reagent, namely,…”
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6
Films based on the phases in the Si-C-N System: Part 1. Synthesis and characterization of bis(trimethylsilyl)ethylamine as a precursor
Published in Glass physics and chemistry (01-02-2012)“…The characterization of bis(trimethylsilyl)ethylamine was carried out using a combination of IR, UV, 1 H, 13 C, 29 Si, and 15 N NMR spectroscopy, as well as…”
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7
4-(Trimethylsilyl)morpholine: synthesis, characterization, and prospects of use in film deposition processes
Published in Russian chemical bulletin (01-12-2017)“…4-(Trimethylsilyl)morpholine (TMSM) was synthesized and shown to be applicable as a precursor for plasma-enhanced chemical vapor deposition of films. The…”
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8
On the possibility of homolytic addition of N-bromohexamethyldisilazane to the triple carbon–carbon bond
Published in Russian journal of general chemistry (01-04-2017)“…By an example of a reaction of N -bromohexamethyldisilazane with phenylacetylene the possibility of its homolytic addition to the triple carbon-carbon bond…”
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9
N-bromohexamethyldisilazane: Investigation of properties and thermodynamic simulation of precipitation of thin-layer structures from the vapor phase
Published in Glass physics and chemistry (01-02-2011)“…N -Bromohexamethyldisilazane has been characterized using an elemental analysis and IR, UV, 1 H NMR, 13 C NMR, and 29 Si NMR spectroscopy. The spectral…”
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10
Plasma-chemical synthesis of silicon carbonitride films from trimethyl(diethylamino)silane
Published in Glass physics and chemistry (01-08-2010)“…Silicon carbonitride films of different compositions have been synthesized by plasma-enhanced chemical vapor deposition with the use of…”
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11
Reaction of sodium bis(trimethylsilyl)amide with 2-bromopyridine
Published in Russian chemical bulletin (01-02-2016)“…A reaction of sodium bis(trimethylsilyl)amide with 2-bromopyridine leads to N , N -bis(trimethylsilyl)- and N ,3-bis(trimethylsilyl)-2-pyridinamine…”
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12
Synthesis of volatile bis[bis(trimethylsilyl)amide]-substituted boron derivatives
Published in Russian journal of general chemistry (01-02-2017)“…General strategy for the synthesis of organoboron compounds containing bis(trimethylsilyl)amide substituents has been suggested…”
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13
Acyl iodides in organic synthesis: XI. Unusual N-C bond cleavage in tertiary amines
Published in Russian journal of organic chemistry (01-04-2008)“…Acyl iodides reacted with excess primary and secondary amines in a way similar to acyl chlorides, yielding the corresponding carboxylic acid amide and initial…”
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Acyl iodides in organic synthesis. Reactions with morpholine, piperidine, and N-hydrocarbylpiperidines
Published in Russian journal of organic chemistry (01-06-2010)“…Acyl iodides RCOI (R = Me, Ph) reacted with morpholine and piperidine to give the corresponding N-acyl derivatives and morpholine or piperidine hydroiodides…”
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15
Acyl Iodides in Organic Synthesis. Reaction of Acyl Iodides with N,N-Dimethyl Carboxylic Acid Amides
Published in Russian journal of organic chemistry (01-10-2010)“…Acyl iodides RCOI (R = Me, Ph) reacted with N,N-dimethylformamide and N,N-dimethylacetamide Me₂NC(=O)R' (R' = H, Me) along two concurrent pathways involving…”
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16
Acyl iodides in organic synthesis. Reaction of acyl iodides with triphenylethoxy- and triphenylhydroxysilane
Published in Russian journal of organic chemistry (01-11-2009)“…The reaction of triphenylethoxysilane with acetyl or benzoyl iodide led to the formation of triphenyliodosilane and ethyl ester of the corresponding carboxylic…”
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17
Characterization of some trimethyl(organylamino)silanes—precursors for preparation of silicon carbonitride films
Published in Glass physics and chemistry (01-06-2010)“…A series of aminosilanes has been synthesized by the reaction of carboxylic acid di(organyl)amides with trimethyliodsilane. A purification method providing an…”
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18
Plasma-chemical deposition of SiCN films from volatile N-bromhexamethyldisilazane
Published in Inorganic materials (01-12-2008)“…Process of silicon-carbonitride (SiCN) film production from a new volatile organosilicon, N-bromhexamethyldisilazane, is developed. The use of this chemical…”
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19
Et3GeN(SiMe3)2 and Et3SnN(SiMe3)2: New precursors for chemical vapor deposition processes
Published in Inorganic materials (01-04-2013)“…We have synthesized the germanium- and tin-containing organosilicon compounds Et 3 GeN(SiMe 3 ) 2 and Et 3 SnN(SiMe 3 ) 2 as new precursors for the preparation…”
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Effect of the chemical structure of silyl derivatives of unsymmetrical dimethylhydrazine on the composition and structure of silicon carbonitride films: Theoretical and experimental studies
Published in Inorganic materials (01-04-2007)“…Quantum-chemical calculations are used to analyze the homolytic decomposition of 1,1-dimethyl-2-(dimethylhydrazino)silane (DMDMHS) and…”
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