Magnesium catalyzed biphasic solvent mediated microwave assisted synthesis of 5-hydroxymethylfurfural

Direct transformation of fructose into 5-hydroxymethylfurfural (5-HMF) was carried out by using single or combination of catalysts like, MgF2, MgTiO3 and Mg (CF3SO3)2 in a polar and biphasic solvent system under microwave assisted heating. We studied several metal catalysts but, the combination of M...

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Bibliographic Details
Published in:	Chemical Data Collections Vol. 34; p. 100728
Main Authors:	Rasvan Khan, P., Deepti, K., Kamble Dhanraj, P., Kumar Devarakonda, Ravi, Raju Talam, Naga, Pushpalatha, Kavuluri, Basaveswara Rao, Mandava V.
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 01-08-2021
Subjects:	Biphasic solvent system Fructose Mg catalysts Microwave assisted reaction Mg catalysts Microwave assisted reaction Biphasic solvent system Fructose
Online Access:	Get full text
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Summary:	Direct transformation of fructose into 5-hydroxymethylfurfural (5-HMF) was carried out by using single or combination of catalysts like, MgF2, MgTiO3 and Mg (CF3SO3)2 in a polar and biphasic solvent system under microwave assisted heating. We studied several metal catalysts but, the combination of Mg mediated catalysts were the most effective enabling up to 84% of 5- HMF yield from the fructose. We have developed a simple and eco-friendly method to the synthesis of 5-HMF for the industrial usage. Thus, the main advantage of current catalytic system based on cheap, readily abundant, recycled, reused and ecofriendly. [Display omitted]
ISSN:	2405-8300 2405-8300
DOI:	10.1016/j.cdc.2021.100728