Search Results - "Raghavan, Adharsh"

Bisaryl Diruthenium(III) Paddlewheel Complexes: Synthesis and Characterization by Raghavan, Adharsh, Ren, Tong

“…Aryls represent a class of both σ- and π-donating electron-rich axial ligands that is underexplored in the field of metal–metal multiply bonded paddlewheel…”
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Influence of Metal Identity and Complex Nuclearity in Kumada Cross-Coupling Polymerizations with a Pyridine Diimine-Based Ligand Scaffold by King, Andrew J., Wang, Jiashu, Liu, Tianchang, Raghavan, Adharsh, Tomson, Neil C., Zhukhovitskiy, Aleksandr V.

“…Cross-coupling polymerizations have fundamentally changed the field of conjugated polymers (CPs) by expanding the scope of accessible materials. Despite the…”
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Oxidation of dimethylsulfoxide in the presence of uranyl salts by Raghavan, Adharsh, Cahill, Christopher L.

“…Uranyl salts, even in the absence of light, appear to accelerate the well-known oxidative decomposition of DMSO in air. Sulfate, a product of the…”
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Drastic Tuning of the Electronic Structures of Diruthenium Aryl Complexes by Isoelectronic Axial Ligands by Raghavan, Adharsh, Yuan, Fang, Ren, Tong

“…Reported herein is the use of aryls as axial ligands to manipulate reactivity at the distal metal site through metal–metal–ligand interactions in diruthenium…”
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Orbital Engineering Mediated by Cation Conjugation in Luminescent Uranyl‐Organic Hybrid Materials by Raghavan, Adharsh, Cahill, Christopher L.

“…A series of compounds of the form [HAr]2[UO2X4] is reported here, wherein Ar is systematically varied between pyridine (1‐X), quinoline (2‐X), acridine (3‐X),…”
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I–/I3 – Redox-Assisted Synthesis and Properties of Low Dimensional, Mixed-Valent Gold Iodide Perovskite Derivatives by Walusiak, Benjamin W., Raghavan, Adharsh, Cahill, Christopher L.

“…We report a set of three new mixed-valent AuI AuIII iodides: (ClPy)3[AuI2]2[AuI4] [1], (BrPy)3[AuI2]2[AuI4] [2], and (ClPy)2[AuI2]­[AuI4] [3], as well as three…”
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I – /I 3 – Redox-Assisted Synthesis and Properties of Low Dimensional, Mixed-Valent Gold Iodide Perovskite Derivatives by Walusiak, Benjamin W., Raghavan, Adharsh, Cahill, Christopher L.

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Synthesis and Characterization of CoIII(TIM) Complexes Bearing Alkenyl or 1‑Aza-2-cobalt-cyclopropane Moieties by Rodriguez Segura, Leobardo, McGuire, Kyle J., Raghavan, Adharsh, Roos, Jeremy J., Ren, Tong

“…Reported herein are the synthesis and characterization of mono- and bis-alkenyl CoIII(TIM) (TIM =…”
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NiII Complexes of C‐Substituted Cyclam as Efficient Catalysts for Reduction of CO2 to CO by Mash, Brandon L., Raghavan, Adharsh, Ren, Tong

“…Two new nickel(II) complexes of cyclams bearing C‐alkyl groups, Ni(MEC)OTf2 (1, MEC = 5,12‐diethyl‐7,14‐dimethyl‐1,4,8,11‐tetraazacyclotetradecane) and…”
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Synthesis and Characterization of Co III (TIM) Complexes Bearing Alkenyl or 1-Aza-2-cobalt-cyclopropane Moieties by Rodriguez Segura, Leobardo, McGuire, Kyle J., Raghavan, Adharsh, Roos, Jeremy J., Ren, Tong

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Structural, Spectroscopic, and Computational Analysis of Halogen- and Hydrogen-Bonding Effects within a Series of Uranyl Fluorides with 4‑Halopyridinium by Decoteau, Elizabeth A., Raghavan, Adharsh, Cahill, Christopher L.

“…Reported are the syntheses and characterization of five compounds containing one-dimensional uranyl fluoride chains charge balanced by 4-X-pyridinium (X = H,…”
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Review: Structurally characterized α-diimine complexes of s- and p-block elements by Raghavan, Adharsh, Venugopal, Ajay

“…This review provides an account on the structurally characterized s- and p-block element complexes of neutral α-diimine ligands and their chemical properties…”
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Cover Feature: NiII Complexes of C‐Substituted Cyclam as Efficient Catalysts for Reduction of CO2 to CO (Eur. J. Inorg. Chem. 15/2019) by Mash, Brandon L., Raghavan, Adharsh, Ren, Tong

“…The Cover Feature shows a plant in place of an electrochemical cell and the featured catalyst, [Ni(CTMC)]2+, as a leaf on the plant. This represents the…”
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Cover Feature: Ni II Complexes of C ‐Substituted Cyclam as Efficient Catalysts for Reduction of CO 2 to CO (Eur. J. Inorg. Chem. 15/2019) by Mash, Brandon L., Raghavan, Adharsh, Ren, Tong

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Ni II Complexes of C ‐Substituted Cyclam as Efficient Catalysts for Reduction of CO 2 to CO by Mash, Brandon L., Raghavan, Adharsh, Ren, Tong

“…Two new nickel(II) complexes of cyclams bearing C ‐alkyl groups, Ni(MEC)OTf 2 ( 1 , MEC = 5,12‐diethyl‐7,14‐dimethyl‐1,4,8,11‐tetraazacyclotetradecane) and…”
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Forging Ru–Csp2 Bonds in Paddlewheel Complexes Using the Lithium–Halogen Exchange Reaction by Raghavan, Adharsh, Mash, Brandon L, Ren, Tong

“…Reported herein are the first examples of the formation of Ru–Csp2 bonds in paddlewheel diruthenium species. A series of six Ru2(ap)4(C6H4-4-X) type compounds…”
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Bandgap modification in 0D tellurium iodide perovskite derivatives via incorporation of polyiodide species by Walusiak, Benjamin W, Raghavan, Adharsh, Cahill, Christopher L

“…Halide perovskites provide a versatile platform for exploring the effect of non-covalent interactions, including halogen bonding, on material properties such…”
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Forging Ru-C sp 2 Bonds in Paddlewheel Complexes Using the Lithium-Halogen Exchange Reaction by Raghavan, Adharsh, Mash, Brandon L, Ren, Tong

“…Reported herein are the first examples of the formation of Ru-C bonds in paddlewheel diruthenium species. A series of six Ru ( ap) (C H -4-X) type compounds (…”
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Co(cyclam) Complexes of Triarylamine-acetylide: Structural and Spectroscopic Properties and DFT Analysis by Banziger, Susannah D, Raghavan, Adharsh, Zeller, Matthias, Ren, Tong

“…Reported herein are the syntheses of mono- and bis-C2TPA (HC2TPA = 4-ethynyl-N,N-bis­(4-methoxyphenyl)­aniline) complexes of CoIII(cyclam) (cyclam =…”
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Orbital Engineering Mediated by Cation Conjugation in Luminescent Uranyl‐Organic Hybrid Materials by Raghavan, Adharsh, Cahill, Christopher L.

“…A series of compounds of the form [HAr]2[UO2X4] is reported here, wherein Ar is systematically varied between pyridine (1‐X), quinoline (2‐X), acridine (3‐X),…”
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