Search Results - "Radhoff, Niklas"
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1,4-Aryl migration in ketene-derived enolates by a polar-radical-crossover cascade
Published in Nature communications (02-06-2022)“…The arylation of carboxylic acid derivatives via Smiles rearrangement has gained great interest in recent years. Both radical and ionic approaches, as well as…”
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2
Functionalization of α‐C(sp3)−H Bonds in Amides Using Radical Translocating Arylating Groups
Published in Angewandte Chemie International Edition (15-02-2021)“…α‐C−H arylation of N‐alkylamides using 2‐iodoarylsulfonyl radical translocating arylating (RTA) groups is reported. The method allows the construction of…”
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3
Oxindole synthesis via polar-radical crossover of ketene-derived amide enolates in a formal [3 + 2] cycloaddition
Published in Chemical science (Cambridge) (30-03-2022)“…Herein we introduce a simple, efficient and transition-metal free method for the preparation of valuable and sterically hindered 3,3-disubstituted oxindoles…”
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4
Oxindole synthesis via polar-radical crossover of ketene-derived amide enolates in a formal 3 + 2 cycloaddition
Published in Chemical science (Cambridge) (30-03-2022)“…Herein we introduce a simple, efficient and transition-metal free method for the preparation of valuable and sterically hindered 3,3-disubstituted oxindoles…”
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5
Lewis Acid Catalyzed Formal (3+2)‐Cycloaddition of Bicyclobutanes with Ketenes
Published in Angewandte Chemie International Edition (01-08-2023)“…Design, synthesis and application of benzene bioisosteres have attracted a lot of attention in the past 20 years. Recently, bicyclo[2.1.1]hexanes have emerged…”
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6
Lewis Acid Catalyzed Formal (3+2)‐Cycloaddition of Bicyclo[1.1.0]butanes with Ketenes
Published in Angewandte Chemie International Edition (21-08-2023)“…Design, synthesis and application of benzene bioisosteres have attracted a lot of attention in the past 20 years. Recently, bicyclo[2.1.1]hexanes have emerged…”
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7
Radikalische Funktionalisierung von α‐C(sp3)‐H‐Bindungen in Amiden durch Translokations‐induzierende arylierende Gruppen
Published in Angewandte Chemie (15-02-2021)“…Die radikalische α‐C‐H‐Arylierung in N‐Alkylamiden durch Translokations‐induzierende arylierende (RTA) Gruppen auf Basis von 2‐Iodarylsulfonylchloriden wird…”
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8
Lewis‐Säure‐katalysierte formale (3+2)‐Cycloaddition von Bicyclo[1.1.0]butanen mit Ketenen
Published in Angewandte Chemie (21-08-2023)“…Design, Synthese und Anwendung von Benzolbioisosteren haben in den letzten 20 Jahren viel Aufmerksamkeit erfahren. In jüngster Zeit haben sich…”
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9
Lewis‐Säure‐katalysierte formale (3+2)‐Cycloaddition von Bicyclobutanen mit Ketenen
Published in Angewandte Chemie (01-08-2023)“…Design, Synthese und Anwendung von Benzolbioisosteren haben in den letzten 20 Jahren viel Aufmerksamkeit erfahren. In jüngster Zeit haben sich…”
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10
Oxindole synthesis polar-radical crossover of ketene-derived amide enolates in a formal [3 + 2] cycloaddition
Published in Chemical science (Cambridge) (30-03-2022)“…Herein we introduce a simple, efficient and transition-metal free method for the preparation of valuable and sterically hindered 3,3-disubstituted oxindoles…”
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Journal Article -
11
Radikalische Funktionalisierung von α‐C(sp3)‐H‐Bindungen in Amiden durch Translokations‐induzierende arylierende Gruppen
Published in Angewandte Chemie (01-02-2021)“…Die radikalische α‐C‐H‐Arylierung in N‐Alkylamiden durch Translokations‐induzierende arylierende (RTA) Gruppen auf Basis von 2‐Iodarylsulfonylchloriden wird…”
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