Search Results - "Rabung, Thomas"
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Mineral–Water Interface Reactions of Actinides
Published in Chemical reviews (13-02-2013)“…An examination of how light actinide ions react at the mineral-aqeuous solution interface is offered, focusing on sorption reaction and actinide surface…”
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Sorption of Eu(III) on quartz at high salt concentrations
Published in Colloids and surfaces. A, Physicochemical and engineering aspects (05-10-2019)“…[Display omitted] Sorption of Eu(III) onto quartz from highly saline solutions (up to 5 M NaCl) for pHc 2–9 ha s been studied by measuring sorption edges. The…”
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3
Thermodynamics of trivalent actinides and neodymium in NaCl, MgCl2, and CaCl2 solutions: Solubility, hydrolysis, and ternary Ca-M(III)-OH complexes
Published in Pure and applied chemistry (04-08-2009)“…Known data on the solubility of Am(OH) (s) and the hydrolysis of Am(III) and Cm(III), additional information from an extensive solubility study with Nd(OH) (s)…”
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Proton and Trivalent Metal Cation Binding by Dissolved Organic Matter in the Opalinus Clay and the Callovo-Oxfordian Formation
Published in Environmental science & technology (15-08-2008)“…We investigated the proton and trivalent metal binding of dissolved organic matter (DOM) in in situ pore water and anoxic rock extracts of two potential host…”
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Uptake of Cm(III) and Eu(III) by Calcium Silicate Hydrates: A Solution Chemistry and Time-Resolved Laser Fluorescence Spectroscopy Study
Published in Environmental science & technology (15-08-2003)“…The interaction of the two chemical homologues [Cm(III) and Eu(III)] with calcium silicate hydrates (CSH phases) at pH 13.3 has been investigated in batch-type…”
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Differences in properties and Cm(III) complexation behavior of isolated humic and fulvic acid derived from Opalinus clay and Callovo-Oxfordian argillite
Published in Applied geochemistry (01-06-2005)“…Fulvic acids from deep clay formations have been isolated by the International Humic Substances Society (IHSS) standard protocol and analyzed. Near edge X-ray…”
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7
Sorption of Eu(III) on a Natural Hematite: Application of a Surface Complexation Model
Published in Journal of colloid and interface science (01-12-1998)“…The solid/water interface reaction is investigated for the sorption of the Eu3+ion onto a well-characterized natural hematite at pH ≤6 in 0.1 mol/L NaClO4…”
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Sorption of Cm(III) and Eu(III) onto clay minerals under saline conditions: Batch adsorption, laser-fluorescence spectroscopy and modeling
Published in Geochimica et cosmochimica acta (15-02-2015)“…The present work reports experimental data for trivalent metal cation (Cm/Eu) sorption onto illite (Illite du Puy) and montmorillonite (Na-SWy-2) in NaCl…”
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Actinide geochemistry: From the molecular level to the real system
Published in Journal of contaminant hydrology (12-12-2008)“…Geochemical processes leading to either mobilization or retention of radionuclides in an aquifer system are significantly influenced by their interaction with…”
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Journal Article Conference Proceeding -
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Macroscopic and spectroscopic investigations on Eu(III) and Cm(III) sorption onto bayerite (β-Al(OH)3) and corundum (α-Al2O3)
Published in Journal of colloid and interface science (01-01-2016)“…[Display omitted] •Sorption studied by macroscopic (batch sorption) and microscopic (TRLFS) techniques.•Similar pH dependent sorption behaviour at trace metal…”
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Complexation of Nd(III)/Cm(III) with gluconate in alkaline NaCl and CaCl2 solutions: Solubility, TRLFS and DFT studies
Published in Applied geochemistry (01-03-2021)“…The effect of gluconate on the solubility and aqueous speciation of An(III) and Ln(III) was studied using a combination of Nd(III) solubility experiments,…”
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Tris‐{hydridotris(1‐pyrazolyl)borato}actinide Complexes: Synthesis, Spectroscopy, Crystal Structure, Bonding Properties and Magnetic Behaviour
Published in Chemistry : a European journal (01-09-2020)“…The isostructural compounds of the trivalent actinides uranium, neptunium, plutonium, americium, and curium with the hydridotris(1‐pyrazolyl)borato (Tp) ligand…”
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Comment on “Kinetics and thermodynamics of Eu(III) adsorption onto synthetic monoclinic pyrrhotite” by Y. Zhu et al., Journal of Molecular Liquids, 218 (2016), 565–570
Published in Journal of molecular liquids (01-12-2016)“…The paper of Zhu et al. [1] is of great interest, since it reported adsorption data of Eu(III) onto pyrrhotite, an uninvestigated solid surface to date. We are…”
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Interdisciplinary Round-Robin Test on Molecular Spectroscopy of the U(VI) Acetate System
Published in ACS omega (03-05-2019)“…A comprehensive molecular analysis of a simple aqueous complexing systemU(VI) acetateselected to be independently investigated by various spectroscopic…”
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Eu(III) coprecipitation with the trioctahedral clay mineral, hectorite
Published in Clays and clay minerals (01-02-2006)“…Various secondary phases formed during alteration/dissolution of HLW (high-level nuclear waste) borosilicate glass represent a significant retention potential…”
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Influence of water-extractable organic matter from Opalinus Clay on the sorption and speciation of Ni(II), Eu(III) and Th(IV)
Published in Applied geochemistry (01-02-2005)“…The influence of water-extractable organic matter from 6 Opalinus Clay (OPA) samples from Mont Terri and Benken (Switzerland) on the sorption of Ni(II),…”
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Kinetic Investigation of Eu(III)−Humate Interactions by Ion Exchange Resins
Published in Analytical chemistry (Washington) (01-07-2003)“…The kinetic stability of radionuclides bound to aqueous colloids is a determining factor in their migration from a radioactive waste repository. The cation…”
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Time-resolved observation of ZrO2-colloid agglomeration
Published in Colloids and surfaces. A, Physicochemical and engineering aspects (28-03-2003)Get full text
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Time-resolved observation of ZrO 2-colloid agglomeration
Published in Colloids and surfaces. A, Physicochemical and engineering aspects (2003)“…The agglomeration of ZrO 2-nanoparticles is investigated in situ by a combination of light scattering photon correlation spectroscopy (PCS) and laser-induced…”
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