Search Results - "ROSTEK, Charles J"
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Novel Syntheses of 2,3-Dihydro-1,5-benzothiazepin-4(5H)-ones and 2H-1,4-Benzothiazin-3(4H)-ones
Published in Journal of organic chemistry (05-10-2001)“…Nucleophilic additions of α-mercaptoalkanoate esters and β-mercaptoalkanoate acids to benzoquinone diimines, followed by cyclization with trifluoroacetic acid…”
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2
Structural assignment of regioisomeric 3-[2- or 5-anilino-2-(alkylamino)phenyl]propanoic acids, 2H-1,4-benzothiazin-3(4H)-ones and 2,3-dihydro-1,5-benzothiazepin-4(5H)-ones by 1D NOE and gHMBC NMR techniques
Published in Magnetic resonance in chemistry (01-07-2004)“…The 1H and 13C NMR spectra of compounds 1–11 and 16–22 in CDCl3 and DMSO‐d6 solutions allowed structural assignment to regioisomers 1/5 and 2/6 and their…”
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3
Synthesis and NMR spectroscopic studies of allylsulfanyl-N1-alkyl-N4-phenyl-1,4-phenylenediamines and their cyclization products, 2,3-dihydro-1-benzothiophenes and thiochromans
Published in Magnetic resonance in chemistry (01-12-2004)“…Regioselective addition of allylthiol at the C‐3 position adjacent to the nitrogen carrying the phenyl group of the 1,4‐phenylenediamine moiety of compounds…”
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4
Elucidation of the structures of 3-alkylthio-, 3-benzylthio-, 2-arylthio- and 2-heteroarylthio-N1-(1,3-dimethylbutyl)-N4-phenyl-1,4-phenylenediamines by one- and two-dimensional NMR spectroscopy
Published in Magnetic resonance in chemistry (01-05-2004)“…Nucleophilic addition of alkyl‐ and benzylthiols to benzoquinone diimine (1) gave the corresponding 3‐alkylthio‐ or 3‐benzylthio‐1,4‐phenylenediamines (2–5)…”
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5
Rubber chemicals derived from conjugate addition. II. Synthesis of a novel class of benzoquinone diimines
Published in Rubber chemistry and technology (01-11-2001)“…Various 2-alkylthio-5-amino- and 2,5-diamino-1,4-phenylenediamines were prepared by treatment of N-(1,3-dimethylbutyl)- N′-phenyl-1,4-quinonediimine with…”
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6
Rubber chemicals derived from conjugate addition. I. Syntheses of novel 2-thio-5-amino substituted benzoquinones
Published in Rubber chemistry and technology (01-11-2001)“…Alkylthio-substituted benzoquinones were prepared from benzoquinone and mercaptans in 50–94% yields via NaIO4 oxidation of the intermediate hydroquinones…”
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7
Structural assignment of regioisomeric 3‐[2‐ or 5‐anilino‐2‐(alkylamino)phenyl]propanoic acids, 2 H ‐1,4‐benzothiazin‐3(4 H )‐ones and 2,3‐dihydro‐1,5‐benzothiazepin‐4(5 H )‐ones by 1D NOE and gHMBC NMR techniques
Published in Magnetic resonance in chemistry (01-07-2004)“…The 1 H and 13 C NMR spectra of compounds 1 – 11 and 16 – 22 in CDCl 3 and DMSO‐ d 6 solutions allowed structural assignment to regioisomers 1/5 and 2/6 and…”
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8
Novel Syntheses of 2,3-Dihydro-1,5-benzothiazepin-4( 5H )-ones and 2 H -1,4-Benzothiazin-3(4 H )-ones
Published in Journal of organic chemistry (01-10-2001)Get full text
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9
Synthesis and NMR spectroscopic studies of allylsulfanyl‐ N 1 ‐alkyl‐ N 4 ‐phenyl‐1,4‐phenylenediamines and their cyclization products, 2,3‐dihydro‐1‐benzothiophenes and thiochromans
Published in Magnetic resonance in chemistry (01-12-2004)“…Regioselective addition of allylthiol at the C‐3 position adjacent to the nitrogen carrying the phenyl group of the 1,4‐phenylenediamine moiety of compounds 1…”
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10
Rubber chemicals derived from conjugate addition. I. Syntheses of novel 2-thio--amino substituted benzoquinones
Published in Rubber chemistry and technology (01-11-2001)“…The wave-lengths and intensities of the principal maxima for 3a-c were as follows: 201-210 nm (14800 < e < 15400), 243-252 nm (6680 <e < 8280), 307-378 nm…”
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11
Elucidation of the structures of 3‐alkylthio‐, 3‐benzylthio‐, 2‐arylthio‐ and 2‐heteroarylthio‐ N 1 ‐(1,3‐dimethylbutyl)‐ N 4 ‐phenyl‐1,4‐phenylenediamines by one‐ and two‐dimensional NMR spectroscopy
Published in Magnetic resonance in chemistry (01-05-2004)“…Nucleophilic addition of alkyl‐ and benzylthiols to benzoquinone diimine ( 1 ) gave the corresponding 3‐alkylthio‐ or 3‐benzylthio‐1,4‐phenylenediamines ( 2 –…”
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12
Novel Sulfur Vulcanization Accelerators Based on Mercapto-Pyridine, -Pyrazine, and -Pyrimidine
Published in Rubber chemistry and technology (01-05-1996)“…Sulfur vulcanization accelerators derived from 2-mercaptobenzothiazole (MBT) have been a staple for the rubber processing industry for over 65 years. Most…”
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