Search Results - "ROOT, Thatcher W"
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Chemical and Electrochemical O2 Reduction on Earth-Abundant M‑N‑C Catalysts and Implications for Mediated Electrolysis
Published in Journal of the American Chemical Society (19-01-2022)“…M-N-C catalysts, incorporating non-precious-metal ions (e.g. M = Fe, Co) within a nitrogen-doped carbon support, have been the focus of broad interest for…”
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Discovery of Multicomponent Heterogeneous Catalysts via Admixture Screening: PdBiTe Catalysts for Aerobic Oxidative Esterification of Primary Alcohols
Published in Journal of the American Chemical Society (01-02-2017)“…In the present study, we demonstrate the utility of “admixture screening” for the discovery of new multicomponent heterogeneous Pd catalyst compositions that…”
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Experimental Limiting Oxygen Concentrations for Nine Organic Solvents at Temperatures and Pressures Relevant to Aerobic Oxidations in the Pharmaceutical Industry
Published in Organic process research & development (20-11-2015)“…Applications of aerobic oxidation methods in pharmaceutical manufacturing are limited in part because mixtures of oxygen gas and organic solvents often create…”
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Production of Biofuels from Cellulose and Corn Stover Using Alkylphenol Solvents
Published in ChemSusChem (22-08-2011)“…Alkylphenol solvents allow a more effective production of biofuels from corn stover by enabling selective extraction and hydrogenation of levulinic acid to…”
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Process Development of CuI/ABNO/NMI-Catalyzed Aerobic Alcohol Oxidation
Published in Organic process research & development (20-11-2015)“…An improved Cu/nitroxyl catalyst system for aerobic alcohol oxidation has been developed for the oxidation of functionalized primary and secondary alcohols to…”
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Continuous Flow Aerobic Alcohol Oxidation Reactions Using a Heterogeneous Ru(OH) x /Al2O3 Catalyst
Published in Organic process research & development (21-11-2014)“…Ru(OH) x /Al2O3 is among the more versatile catalysts for aerobic alcohol oxidation and dehydrogenation of nitrogen heterocycles. Here, we describe the…”
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Rheology measurements of a biomass slurry: an inter-laboratory study
Published in Rheologica acta (01-12-2009)“…The conversion of biomass, specifically lignocellulosic biomass, into fuels and chemicals has recently gained national attention as an alternative to the use…”
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High-CO2 Requirement as a Mechanism for the Containment of Genetically Modified Cyanobacteria
Published in ACS synthetic biology (16-02-2018)“…As researchers engineer cyanobacteria for biotechnological applications, we must consider potential environmental release of these organisms. Previous…”
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Heterogeneous M-N-C Catalysts for Aerobic Oxidation Reactions: Lessons from Oxygen Reduction Electrocatalysts
Published in Chemical reviews (10-05-2023)“…Nonprecious metal heterogeneous catalysts composed of first-row transition metals incorporated into nitrogen-doped carbon matrices (M-N-Cs) have been studied…”
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Platinum-Based Heterogeneous Catalysts for Nitrile Synthesis via Aerobic Oxidative Coupling of Alcohols and Ammonia
Published in ACS omega (30-06-2018)“…Transition-metal-catalyzed aerobic oxidative coupling of alcohols and ammonia represents an attractive atom-economical synthetic route to prepare nitriles…”
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Optimization‐based process synthesis under seasonal and daily variability: Application to concentrating solar power
Published in AIChE journal (01-07-2019)“…We propose an optimization‐based framework for process synthesis under variability in two frequencies. Low‐frequency variability is represented through…”
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Kinetic studies of carbonylation of methanol to dimethyl carbonate over Cu +X zeolite catalyst
Published in Journal of catalysis (01-07-2003)“…Direct synthesis of dimethyl carbonate offers prospects for a “green chemistry” replacement of phosgene use for polymer production and other processes. The…”
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The decomposition of dimethyl carbonate over copper zeolite catalysts
Published in Applied catalysis. A, General (08-03-2005)“…Direct synthesis of dimethyl carbonate offers prospects for a “green chemistry” replacement to eliminate use of phosgene for polymer production and other…”
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Aerobic Oxidation of Diverse Primary Alcohols to Carboxylic Acids with a Heterogeneous Pd–Bi–Te/C (PBT/C) Catalyst
Published in Organic process research & development (15-09-2017)“…Heterogeneous catalytic aerobic oxidation methods represent a near-ideal approach for the conversion of primary alcohols to carboxylic acids. Here, we report…”
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15
Vapor-phase silylation of MCM-41 and Ti-MCM-41
Published in Microporous and mesoporous materials (18-11-2003)“…MCM-41 mesoporous molecular sieves have been silylated with trimethylchlorosilane (TMCS) and trimethylethoxysilane (TMES) under anhydrous, vapor-phase reaction…”
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Heterogeneous Fe-N-C Catalyst for Aerobic Dehydrogenation of Hydrazones to Diazo Compounds Used for Carbene Transfer
Published in Journal of the American Chemical Society (22-05-2024)“…Organic diazo compounds are versatile reagents in chemical synthesis and would benefit from improved synthetic accessibility, especially for larger scale…”
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PTFE-Membrane Flow Reactor for Aerobic Oxidation Reactions and Its Application to Alcohol Oxidation
Published in Organic process research & development (17-07-2015)“…A “tube-in-shell” membrane flow reactor has been developed for aerobic oxidation reactions that permits continuous delivery of O2 to a liquid-phase reaction…”
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Comparison of Quinone‐Based Catholytes for Aqueous Redox Flow Batteries and Demonstration of Long‐Term Stability with Tetrasubstituted Quinones
Published in Advanced energy materials (01-05-2020)“…Quinones are appealing targets as organic charge carriers for aqueous redox flow batteries (RFBs), but their utility continues to be constrained by limited…”
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Quinone-mediated hydrogen anode for non-aqueous reductive electrosynthesis
Published in Nature (London) (02-11-2023)“…Electrochemical synthesis can provide more sustainable routes to industrial chemicals 1 – 3 . Electrosynthetic oxidations may often be performed…”
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Molecular Catalyst Synthesis Strategies to Prepare Atomically Dispersed Fe-N‑C Heterogeneous Catalysts
Published in Journal of the American Chemical Society (19-10-2022)“…We report a strategy to integrate atomically dispersed iron within a heterogeneous nitrogen-doped carbon (N-C) support, inspired by routes for metalation of…”
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