Search Results - "RAGAINI, Fabio"
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Effective Synthesis of 4-Quinolones by Reductive Cyclization of 2'-Nitrochalcones Using Formic Acid as a CO Surrogate
Published in Molecules (Basel, Switzerland) (15-07-2023)“…4-Quinolones are the structural elements of many pharmaceutically active compounds. Although several approaches are known for their synthesis, the introduction…”
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2
Phenyl Formate as a CO Surrogate for the Reductive Cyclization of Organic Nitro Compounds to Yield Different N-Heterocycles: No Need for Autoclaves and Pressurized Carbon Monoxide
Published in Catalysts (01-02-2023)“…The reductive cyclization of different organic nitro compounds by carbon monoxide, catalyzed by transition metal complexes, is a very efficient and clean…”
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3
Synthesis and Catalysis of Redox‐Active Bis(imino)acenaphthene (BIAN) Iron Complexes
Published in ChemCatChem (23-08-2017)“…Reactions of various substituted bis(imino)acenaphthenes (R‐BIANs) with FeCl2(thf)1.5 afforded the tetrahedral complexes (R‐BIAN)FeCl2 (2) from bulky…”
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4
Synthesis of Indoles by Palladium-Catalyzed Reductive Cyclization of β-Nitrostyrenes with Phenyl Formate as a CO Surrogate
Published in Catalysts (01-01-2022)“…The reductive cyclization of suitably substituted organic nitro compounds by carbon monoxide is a very appealing technique for the synthesis of heterocycles…”
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5
Coordination chemistry of organic azides and amination reactions catalyzed by transition metal complexes
Published in Coordination chemistry reviews (01-06-2006)“…The interaction of organic azides with transition metal complexes will be discussed with particular attention to the coordination modes of these molecules. The…”
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6
Iron/N-doped graphene nano-structured catalysts for general cyclopropanation of olefins
Published in Chemical science (Cambridge) (28-06-2020)“…The first examples of heterogeneous Fe-catalysed cyclopropanation reactions are presented. Pyrolysis of in situ -generated iron/phenanthroline complexes in the…”
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7
Catalyst activity or stability: the dilemma in Pd-catalyzed polyketone synthesis
Published in Dalton transactions : an international journal of inorganic chemistry (28-10-2013)“…A series of Pd-complexes containing nonsymmetrical bis(aryl-imino)acenaphthene (Ar-BIAN) ligands, characterized by substituents on the meta positions of the…”
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8
Mechanistic Study of the Palladium–Phenanthroline Catalyzed Carbonylation of Nitroarenes and Amines: Palladium–Carbonyl Intermediates and Bifunctional Effects
Published in Chemistry : a European journal (10-08-2009)“…Palladium–phenanthroline complexes catalyze both the nitroarene carbonylation reaction and the amine oxidative carbonylation reaction to give, depending on the…”
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9
Asymmetric Cyclopropanation of Olefins Catalyzed by Chiral Cobalt(II)-Binaphthyl Porphyrins
Published in Organometallics (08-12-2008)“…Cobalt(II) complexes of chiral bis-binaphthyl porphyrins were prepared, and their catalytic activity in the asymmetric cyclopropanation of alkenes with ethyl…”
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10
Rearrangement of N‐Aryl‐2‐Vinylaziridines to Benzoazepines and Dihydropyrroles: A Synthetic and Theoretical Study
Published in Chemistry : a European journal (19-01-2009)“…Herein we report the one‐pot synthesis of several N‐heterocyclic compounds by rearrangement reactions of N‐aryl‐2‐vinylaziridines. The optimization of the…”
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11
Exclusive Papers of the Editorial Board Members and Topical Advisory Panel Members of Catalysts in Section “Catalysis in Organic and Polymer Chemistry”
Published in Catalysts (01-07-2024)“…Herein, I would like to provide an overview of this Special Issue, published in the Organic and Polymer Chemistry Section of Catalysis, comprising…”
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10th Anniversary of Catalysts: Molecular Catalysis
Published in Catalysts (01-12-2022)“…On the occasion of this Special Issue, I would like to present an editorial message on this good occasion [...]…”
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The [Ru(CO)(porphyrin)]-Catalyzed Synthesis of N-Aryl-2-vinylaziridines
Published in European Journal of Organic Chemistry (01-02-2007)“…[Ru(CO)(porphyrin)] complexes have been found to catalyze the direct aziridination of conjugated dienes by aryl azides with high chemoselectivity, to provide…”
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14
Heterogenization of ruthenium porphyrin complexes in polymeric membranes: Catalytic aziridination of styrenes
Published in Journal of molecular catalysis. A, Chemical (01-03-2008)“…In this paper we report the preparation of catalytic membranes having the complex Ru(4-(CF 3)TPP)CO ( 1) (TPP = dianion of tetraphenylporphyrin) embedded in…”
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15
An effective non-chromatographic method for the purification of phenanthrolines and related ligands
Published in Tetrahedron letters (02-07-2020)“…[Display omitted] •A non-chromatographic method is described for the purification of phenanthrolines.•The method only requires cheap and non-toxic reagents.•A…”
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16
Formic Acid as Carbon Monoxide Source in the Palladium-Catalyzed N‑Heterocyclization of o‑Nitrostyrenes to Indoles
Published in Journal of organic chemistry (21-04-2023)“…The reductive cyclization reaction of o-nitrostyrenes to generate indoles has been investigated for three decades using CO as a cheap reducing agent, but it…”
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17
Structural Determination of Ruthenium−Porphyrin Complexes Relevant to Catalytic Epoxidation of Olefins
Published in Inorganic chemistry (21-03-2005)“…A reproducible synthesis of a competent epoxidation catalyst, [RuVI(TPP)(O)2] (TPP = tetraphenylporphyrin dianion), starting from [RuII(TPP)(CO)L] (L = none or…”
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Catalytic reductive cyclization of 2-nitrobiphenyls using phenyl formate as CO surrogate: A robust synthesis of 9H-carbazoles
Published in Journal of catalysis (01-05-2022)“…[Display omitted] •Use of CO surrogates allows for phosphorus-free synthesis of carbazoles from o-nitrobiphenyls.•No need for high pressure equipment because…”
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19
Catalytic amination reactions mediated by Co(II) Schiff base complexes
Published in Journal of organometallic chemistry (15-04-2005)“…Co(acacen), 1, (acacen = 2,11-dihydroxy-4,9-dimethyl-5,8-diaza-2,4,8,10-dodecatetraene dianion) was found to be a highly efficient catalyst for the allylic…”
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20
Transition Metal Catalyzed Reductive Cyclization Reactions of Nitroarenes and Nitroalkenes
Published in ChemCatChem (19-09-2019)“…Nitroarenes are the entry point for the production of most nitrogen‐containing aromatic compounds. Thus, any transformation that leads directly from them to…”
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