Search Results - "Růžičková, Zdenka"
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Study of Donor–Acceptor Bonds on the N‐Coordinated Sn/Pb(II) Atoms in peri‐Substituted Naphthalenes: Evidence of Pb→B Interaction
Published in European journal of inorganic chemistry (15-10-2020)“…Peri‐substituted naphthalene derivatives, namely, N‐coordinated plumbylenes 1‐PPh2‐8‐PbL‐C10H6 (4) and 1‐BCy2‐8‐PbL‐C10H6 (5) (L = 2,6‐(Me2NCH2)2C6H3) were…”
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2
Prototropic μ‑H8,9 and μ‑H9,10 Tautomers Derived from the [nido-5,6‑C2B8H11]− Anion
Published in Inorganic chemistry (17-10-2016)“…Reported is an unusual tautomeric behavior within the [nido-5,6-C2B8H11]− (1a– ) cage that has no precedence in the whole area of carborane chemistry. Isolated…”
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3
Tetrazole Ring Substitution at Carbon and Boron Sites of the Cobalt Bis(dicarbollide) Ion Available via Dipolar Cycloadditions
Published in Inorganic chemistry (07-12-2020)“…Herein, we describe the synthesis of two families of compounds accessible from [3 + 2] cycloaddition reactions of known B8-substituted isonitrilium and new…”
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4
Sn,P-Peri-Substituted Naphthalene as a Ligand for Transition Metals
Published in Organometallics (22-08-2022)“…Peri-substituted naphthalene 1-PPh2-8-SnL-C10H6 (1) [L = 2,6-(Me2NCH2)2C6H3] was used as a ligand for the complexation of transition metals (TMs). The presence…”
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5
Phosphine‐substituted N‐coordinated Stannylene: Efficient Catalyst in Ketone Hydroboration
Published in European journal of inorganic chemistry (13-08-2024)“…P‐substituted stannylene (Ph2PCH2)(L)Sn containing N,C,N‐pincer ligand (L=[2,6‐(Me2NCH2)2C6H3]) was prepared. The complex was further oxidised to prepare…”
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6
Lithium, Magnesium, and Zinc Centers N,N′-Chelated by an Amine–Amide Hybrid Ligand
Published in Inorganic chemistry (27-06-2022)“…The synthesis and structure of lithium, magnesium, and zinc complexes N,N′-chelated by a hybrid amine–amido ligand ([2-(Me2NCH2)C6H4NR]−, abbreviated as L N…”
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7
Spontaneous Hydrosilylation of Substituted C=N Imines
Published in European journal of inorganic chemistry (31-07-2019)“…4‐Methoxy and 2,4‐di‐tBu substituted C,N‐chelating ligands 2‐[(2,6‐iPr2‐C6H3)N=CH]‐4‐MeO‐C6H3}– and {2‐[(2,6‐iPr2‐C6H3)N=CH]‐4,6‐tBu2‐C6H3}– and also…”
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8
N,C,N‑Coordinated Stannylenes as Ligands in Ag(I) and Au(I) Complexes
Published in Organometallics (22-03-2021)“…The intramolecularly N→Sn coordinated stannylene L(Cl)Sn (1), where L is {2,6-(Me2NCH2)2C6H3}−, has been used as a ligand for silver(I) and gold(I)…”
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9
Access to cationic polyhedral carboranes via dynamic cage surgery with N-heterocyclic carbenes
Published in Nature communications (17-08-2021)“…Polyhedral boranes and heteroboranes appear almost exclusively as neutral or anionic species, while the cationic ones are protonated at exoskeletal heteroatoms…”
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10
Carbon-Substituted Amines of the Cobalt Bis(dicarbollide) Ion: Stereochemistry and Acid–Base Properties
Published in Inorganic chemistry (28-10-2024)“…Organic amines are found to be abundant in natural living systems. They also constitute an inestimable family of building blocks available in drug design…”
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11
Lithium and Dilithium Guanidinates, a Starter Kit for Metal Complexes Containing Various Mono- and Dianionic Ligands
Published in Inorganic chemistry (03-08-2020)“…Comparative studies of the synthesis of lithium guanidinates via nucleophilic addition of lithium amides to carbodiimides were performed. Four combinations of…”
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12
Ambiguous Role of N → Sn Coordinated Stannylene: Lewis Base or Acid?
Published in Organometallics (25-02-2019)“…peri-Substituted naphthalene derivatives 1-BCy2-8-SnL-C10H6 (5), 1-PPh2-8-SnL-C10H6 (6), and 1,8-(SnL)2-C10H6 (7) (L = 2,6-(Me2NCH2)2C6H3) were prepared…”
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13
Triphenylamine-based fluorophores bearing peripheral diazine regioisomers. Synthesis, characterization, photophysics and two-photon absorption
Published in Dyes and pigments (01-05-2022)“…A series of six tripodal push-pull fluorophores with D-(π-A3) arrangement has been designed and synthesized. The structure of these fluorophores consists of a…”
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14
From Monomeric Tin(II) Hydride to Nonsymmetric Distannyne
Published in Organometallics (24-06-2019)“…The monomeric tin(II) hydride L2(H)Sn·W(CO)5 (2), where L2 is 2-Et2NCH2-4,6-tBu2-C6H2, was easily transformed to the nonsymmetrical distannyne…”
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15
Electrophilic Methylation of Decaborane(14): Selective Synthesis of Tetramethylated and Heptamethylated Decaboranes and Their Conjugated Bases
Published in Inorganic chemistry (03-08-2020)“…The paper reports specific syntheses of methylated decaborane(14), nido-B10H14 (1), derivatives. The reaction of 1 with an excess of neat MeI and AlCl3 yields…”
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Ruthenium Complexes with N‐Bound 2‐Pyridonato Ligand as O‐Donors: A New Synthetic Approach and the Effect on Reactivity
Published in ChemPlusChem (Weinheim, Germany) (01-04-2024)“…In this study, Ru complexes [(η6‐p‐cymene)RuX(2‐{(2,6‐iPr2‐C6H3)N=CH}‐C5H3N‐6‐(O))] (3: X=Cl; 4: X=I) were prepared with N‐bound 2‐pyridonato ligand by thermal…”
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17
Photophysical properties of acid-responsive triphenylamine derivatives bearing pyridine fragments: Towards white light emission
Published in Dyes and pigments (01-11-2017)“…The synthesis, thermal, electrochemical, and optical properties of a series of triphenylamine derivatives bearing pyridine fragments and their trifluoroacetate…”
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18
Focus on Chemistry of the 10-Dioxane- nido -7,8-dicarba-undecahydrido Undecaborate Zwitterion; Exceptionally Easy Abstraction of Hydrogen Bridge and Double-Action Pathways Observed in Ring Cleavage Reactions with OH - as Nucleophile
Published in Molecules (Basel, Switzerland) (13-02-2020)“…Ring cleavage of cyclic ether substituents attached to a boron cage via an oxonium oxygen atom are amongst the most versatile methods for conjoining boron…”
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19
Ferrocene donor linked to pyridine/pyridinium acceptor via a systematically enlarged π-linker
Published in RSC advances (03-12-2021)“…Nine chromophores with ferrocene donor and pyridine/pyridinium acceptors have been prepared and further investigated. The performed X-ray analysis showed…”
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20
Synthesis of closo-1,2‑H2C2B8Me8 and 1,2‑H2C2B8Me7X (X = I and OTf) Dicarbaboranes and Their Rearrangement Reactions
Published in Inorganic chemistry (18-02-2019)“…Methyl-camouflaged dicarbaboranes closo-1,2- and 1,10-H2C2B8Me8 have been prepared in high yields either from nido-5,6-H2C2B8H10 or closo-1,2-H2C2B8H8 via…”
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