Search Results - "Pushkarevsky, Nikolay A"
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Radical Anions, Radical‐Anion Salts, and Anionic Complexes of 2,1,3‐Benzochalcogenadiazoles
Published in Chemistry : a European journal (14-01-2019)“…By means of cyclic voltammetry (CV) and DFT calculations, it was found that the electron‐acceptor ability of 2,1,3‐benzochalcogenadiazoles 1–3 (chalcogen: S,…”
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2
Coordination of Halide and Chalcogenolate Anions to Heavier 1,2,5-Chalcogenadiazoles: Experiment and Theory
Published in Organometallics (25-08-2014)“…New products of coordination of anions X– (X = F, I, PhS) to the Te atom of 3,4-dicyano-1,2,5-telluradiazole (1) were synthesized in high yields and…”
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3
Yttrium and Lithium Complexes with Diamidophosphane Ligand Bearing 2,1,3-Benzothiazolyl Substituent: Polydentate Complexation and Reversible NH–PH Tautomery
Published in Inorganics (01-12-2022)“…Deprotonation of a bis(amino)phosphane H2L = PhP(HNBtd)2 bearing a heterocyclic Btd = 2,1,3-benzothiadiazol-4-yl substituents at nitrogen atoms by silylamides…”
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4
Synthesis and Properties of the Heterospin (S 1 = S 2 = 1/2) Radical-Ion Salt Bis(mesitylene)molybdenum(I) [1,2,5]Thiadiazolo[3,4‑c][1,2,5]thiadiazolidyl
Published in Inorganic chemistry (20-07-2015)“…Low-temperature interaction of [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazole (1) with MoMes2 (Mes = mesitylene/1,3,5-trimethylbenzene) in tetrahydrofuran…”
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5
Bis(toluene)chromium(I) [1,2,5]Thiadiazolo[3,4‑c][1,2,5]thiadiazolidyl and [1,2,5]Thiadiazolo[3,4‑b]pyrazinidyl: New Heterospin (S 1 = S 2 = 1/2) Radical-Ion Salts
Published in Inorganic chemistry (03-06-2013)“…Bis(toluene)chromium(0), Cr0(η6-C7H8)2 (3), readily reduced [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazole (1) and [1,2,5]thiadiazolo[3,4-b]pyrazine (2) in a…”
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Structural Diversity and Multielectron Reduction Reactivity of Samarium(II) Iodido-β-diketiminate Complexes Dependent on Tetrahydrofuran Content
Published in Inorganic chemistry (03-10-2022)“…The molecular structures of complexes [Sm(Nacnac)I(thf) n ] (Nacnac = HC(C(Me)Ndipp)2 –, dipp = 2,6-diisopropylphenyl, thf = tetrahydrofuran) depending…”
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7
Doping of Carbon Nanotubes with Encapsulated Phosphorus Chains
Published in Inorganic chemistry (27-06-2022)“…Single-walled carbon nanotubes (SWCNTs) are a perfect host for the formation of one-dimensional phosphorus structures and to obtain hybrid materials with a…”
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8
Structural Diversity of Calcium, Strontium, and Barium Complexes with Reduced Forms of the 3,6‐Di‐tert‐butyl‐o‐benzoquinone Ligand
Published in European journal of inorganic chemistry (31-10-2019)“…Molecular complexes of Ca, Sr, and Ba with the reduced forms of 3,6‐di‐tert‐butyl‐o‐benzoquinone as ligands (catecholate, 3,6‐Cat2–, or semiquinone 3,6‐SQ–‧)…”
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9
Nature of Bonding in Donor–Acceptor Interactions Exemplified by Complexes of N‐Heterocyclic Carbenes with 1,2,5‐Telluradiazoles
Published in Chemistry : a European journal (16-08-2017)“…Comprehensive structural, spectroscopic, and quantum chemical analyses of new donor–acceptor complexes between N‐heterocyclic carbenes and…”
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10
The approach to 4d/4f-polyphosphides
Published in Chemical science (Cambridge) (01-12-2015)“…The first 4d/4f polyphosphides were obtained by reaction of the divalent metallocenes [Cp* Ln(thf) ] (Ln = Sm, Yb) with [{CpMo(CO) } (μ,η -P )] or [Cp*Mo(CO)…”
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11
Steric Influence and Intermolecular Interactions of Formamidinate Ligands in Lanthanide (Sm, Yb) Arylchalcogenolate Complexes
Published in European journal of inorganic chemistry (07-08-2018)“…The complexes [Ln(DippForm)2(QAr)(THF)] [DippForm = N,N′‐(2,6‐diisopropylphenyl)formamidinate; Ln = Sm, Yb; QAr = SPh, SePh, TePh, SeC6F5, Se(p‐C6F4OMe)] were…”
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12
[{(η5-C5Me5)2Sm}4P8]: A Molecular Polyphosphide of the Rare-Earth Elements
Published in Journal of the American Chemical Society (29-04-2009)“…[{(η5-C5Me5)2Sm}4P8], a molecular polyphosphide of the rare-earth elements having a realgar core structure, was synthesized by a one-electron redox reaction of…”
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13
First charge-transfer complexes between tetrathiafulvalene and 1,2,5-chalcogenadiazole derivatives: Design, synthesis, crystal structures, electronic and electrical properties
Published in Synthetic metals (31-12-2012)“…[Display omitted] ► The first CT complexes of TTF with 1,2,5-chalcogenadiazoles are designed. ► These complexes were synthesized and characterized by…”
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14
Wheel-Shaped Lanthanide Iron Sulfide Clusters
Published in Chemistry : a European journal (27-12-2010)“…Octanuclear lanthanide–iron clusters: The first lanthanide–carbonyl–sulfide–iron clusters were obtained by redox reactions of [(η5‐C5Me5)2Ln(thf)2] (Ln=Sm, Yb)…”
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15
Transformation of a Phosphorus-Bound Cp Moiety in the Coordination Sphere of Manganese Carbonyl Complexes
Published in Organometallics (11-02-2013)“…The reaction of Cp*PCl2 with K[Mn(CO)5] yields two novel anionic products, [Mn2(CO)8(μ-PC11H14O)]− (1 – ) and [Mn2(CO)8(μ-PHCp*)]− (2 – ), instead of the…”
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16
Metal- and Ligand-Supported Reduction of the {Fe2S2} Cluster as a Path to Formation of Molecular Group 13 Element Complexes {Fe2S2M} (M = Al, Ga)
Published in Organometallics (09-06-2014)“…The first examples of molecular cluster complexes with the Fe2S2(CO)6 moiety covalently bound to the group 13 elements Al and Ga have been synthesized and…”
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17
Heterospin π-Heterocyclic Radical-Anion Salt: Synthesis, Structure, and Magnetic Properties of Decamethylchromocenium [1,2,5]Thiadiazolo[3,4-c][1,2,5]thiadiazolidyl
Published in Inorganic chemistry (16-08-2010)“…Decamethylchromocene, CrII(η5-C5(CH3)5)2 (2), readily reduced [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazole (1) in a tetrahydrofuran solvent at ambient…”
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18
Reactions of K2[Fe3Q(CO)9] (Q = Se, Te) with AsI3: Synthesis and Structures of the First {Fe3TeAs} Clusters with Capping µ3-AsI and Bridging µ6,κ3:κ3-As2 Ligands
Published in Journal of cluster science (2015)“…Reactions of cluster salts K 2 [Fe 3 Q(CO) 9 ] (Q = Se, Te) with AsI 3 in CH 2 Cl 2 proceed differently depending on the chalcogen atom and the reaction…”
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19
Mixed-Metal Lanthanide-Iron Triple-Decker Complexes with a cyclo-P5 Building Block
Published in Angewandte Chemie International Edition (26-09-2011)“…Triple‐decker complexes with mixed d/f‐block metals that have a purely inorganic middle deck were unknown. A mixed‐metal iron–samarium complex is presented…”
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20
X-(Diiodoarsanyl)benzoic acid (X = 3 and 4)
Published in Acta crystallographica. Section C, Crystal structure communications (01-11-2012)“…The title compounds, 4‐(diiodoarsanyl)benzoic acid, (I), and 3‐(diiodoarsanyl)benzoic acid, (II), both [As(C7H5O2)I2], which possess a –COOH coordinating…”
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