Search Results - "Privér, Steven H."
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Innovative Molecular Design Strategies in Materials Science Following the Aurophilicity Concept
Published in Chemical reviews (12-08-2020)“…The past decade has seen a diverse range of breakthrough inventions that are derived from gold complexes, including the application of aurophilic interactions…”
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Unprecedented Near-Infrared (NIR) Emission in Diplatinum(III) (d7−d7) Complexes at Room Temperature
Published in Journal of the American Chemical Society (26-05-2010)“…The synthesis and single-crystal X-ray structures of the first family of efficient NIR emitters with tunable emission energy based on dihalodiplatinum(III)…”
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Formation of Heterobimetallic Complexes by Addition of d 10 -Metal Ions to [(Me 3 P) x M(2-C 6 F 4 PPh 2 ) 2 ] ( x = 1, 2; M = Ni and Pt): A Synthetic and Computational Study of Metallophilic Interactions
Published in Inorganic chemistry (12-06-2023)“…Treatment of the bis(chelate) complexes -[M(κ -2-C F PPh ) ] ( - ; M = Ni, Pt) and -[Pt(κ -2-C F PPh ) ] ( - ) with equimolar amounts or excess of PMe solution…”
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Formation of Heterobimetallic Complexes by Addition of d10-Metal Ions to [(Me3P) x M(2‑C6F4PPh2)2] (x = 1, 2; M = Ni and Pt): A Synthetic and Computational Study of Metallophilic Interactions
Published in Inorganic chemistry (12-06-2023)“…Treatment of the bis(chelate) complexes trans-[M(κ2-2-C6F4PPh2)2] (trans-1M; M = Ni, Pt) and cis-[Pt(κ2-2-C6F4PPh2)2] (cis-1Pt) with equimolar amounts or…”
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Anti-cancer gold(I) phosphine complexes: Cyclic trimers and tetramers containing the P-Au-P moiety
Published in Journal of inorganic biochemistry (01-10-2017)“…We report the application of cationic tri- and tetra-nuclear gold(I) phosphine complexes [Au3(μ-dppen)3]X3 and [Au4(μ-dppa)4]X4 (X=OTf, PF6)…”
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Synthesis of Gold(I) Complexes Containing Cinnamide: In Vitro Evaluation of Anticancer Activity in 2D and 3D Spheroidal Models of Melanoma and In Vivo Angiogenesis
Published in Inorganic chemistry (06-05-2019)“…A series of alkynylgold(I) phosphine complexes containing methoxy-substituted cinnamide moieties (3a–3c and 4a–4c) have been synthesized and characterized…”
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Antitumor and Antiangiogenic Properties of Gold(III) Complexes Containing Cycloaurated Triphenylphosphine Sulfide Ligands
Published in Inorganic chemistry (20-04-2020)“…A family of stable anticancer gold(III)-based therapeutic complexes containing cyclometalated triphenylphosphine sulfide ligands have been prepared. The…”
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Synthesis of gold(I) phosphine complexes containing the 2-BrC6F4PPh2 ligand: Evaluation of anticancer activity in 2D and 3D spheroidal models of HeLa cancer cells
Published in European journal of medicinal chemistry (10-02-2018)“…Newly synthesised mononuclear gold complexes containing the 2-BrC6F4PPh2 ligand have been fully characterised and their anticancer activity towards five human…”
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Gold(i) and gold(iii) phosphine complexes: synthesis, anticancer activities towards 2D and 3D cancer models, and apoptosis inducing properties
Published in Dalton transactions : an international journal of inorganic chemistry (21-11-2018)“…A series of gold(i), gold(iii) and cationic gold(i) complexes of tris(4-methoxyphenyl)phosphine and tris(2,6-dimethoxyphenyl)phosphine were synthesised and…”
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Potent and Selective Cytotoxic and Anti‐inflammatory Gold(III) Compounds Containing Cyclometalated Phosphine Sulfide Ligands
Published in Chemistry : a European journal (07-11-2019)“…Four cycloaurated phosphine sulfide complexes, [Au{κ2‐2‐C6H4P(S)Ph2}2][AuX2] [X=Cl (2), Br (3), I (4)] and [Au{κ2‐2‐C6H4P(S)Ph2}2]PF6 (5), have been prepared…”
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Electrochemical and Chemical Oxidation of [Pt2(μ-pyrophosphite)4]4− Revisited: Characterization of a Nitrosyl Derivative, [Pt2(μ-pyrophosphite)4(NO)]3
Published in Inorganic chemistry (16-03-2009)“…Electrochemical studies of the salts [cat]4[Pt2(μ-pop)4] (cat+ = Bu4N+ or PPN+ [Ph3PNPPh3]+; pop = pyrophosphite, [P2O5H2]2−) have been carried out in…”
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The use of [2-C6R4PPh2]− (R = H, F) and related carbanions as building blocks in coordination chemistry
Published in Coordination chemistry reviews (01-09-2018)“…•Metal to acceptor electron-donation in coordination chemistry has been established.•Novel modes of reactivity, such as cleavage of η2-B,C interactions by…”
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Organic ligand interaction with copper(II) ions in both aqueous and non-aqueous media: Overcoming solubility issues for sensing
Published in Sensors and actuators. B, Chemical (15-08-2022)“…A new bis(thienyl)imidazole-based fluorescent organic molecular sensor (TIBIT) was prepared and fully characterized by NMR spectroscopy, mass spectrometry and…”
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Synthesis, Characterization, and Electrochemical Relationships of Dinuclear Complexes of Platinum(II) and Platinum(III) Containing Ortho-Metalated Tertiary Arsine Ligands
Published in Inorganic chemistry (29-11-2004)“…Reaction of 2-Li-4-MeC6H3AsPh2 with [PtCl2(SEt2)2] gives two isomeric dinuclear platinum(II) complexes, one containing a half-lantern structure with two…”
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Synthesis of gold(I) phosphine complexes containing the 2-BrC 6 F 4 PPh 2 ligand: Evaluation of anticancer activity in 2D and 3D spheroidal models of HeLa cancer cells
Published in European journal of medicinal chemistry (10-02-2018)“…Newly synthesised mononuclear gold complexes containing the 2-BrC F PPh ligand have been fully characterised and their anticancer activity towards five human…”
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Tin(IV) Compounds with 2‑C6F4PPh2 Substituents and Their Reactivity toward Palladium(0): Formation of Tin–Palladium Complexes via Oxidative Addition
Published in Inorganic chemistry (01-05-2017)“…The tin(IV) compounds Me x Sn(2-C6F4PPh2)4–x (1, x = 1; 2, x = 2) and ClSn(2-C6F4PPh2)3 (3) were obtained from the reactions of 2-LiC6F4PPh2 with MeSnCl3…”
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Metallophilic Contacts in 2‑C6F4PPh2 Bridged Heterobinuclear Complexes: A Crystallographic and Computational Study
Published in Inorganic chemistry (20-07-2015)“…Treatment of the bis(chelate) complex trans-[Pd(κ2-2-C6F4PPh2)2] (7) with PMe3 gave trans-[Pd(κC-2-C6F4PPh2)2(PMe3)2] (13) as a mixture of syn- and…”
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Ortho-metallated transition metal complexes derived from tertiary phosphine and arsine ligands
Published in Coordination chemistry reviews (01-08-2006)“…This article reviews the synthesis, reactivity and structure of transition metal complexes containing ortho-metallated tertiary phosphines and arsines of the…”
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Linking Flavonoids to Gold - A New Family of Gold Compounds for Potential Therapeutic Applications
Published in European journal of inorganic chemistry (01-09-2015)“…The flavone ligands 8‐chloro‐2‐tetrahydrofuryl‐1,4‐benzopyrone and 8‐chloro‐2‐(2‐methyltetrahydrofuryl)‐1,4‐benzopyrone have been used to prepare the first…”
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Tin(IV) Compounds with 2-C 6 F 4 PPh 2 Substituents and Their Reactivity toward Palladium(0): Formation of Tin-Palladium Complexes via Oxidative Addition
Published in Inorganic chemistry (01-05-2017)“…The tin(IV) compounds Me Sn(2-C F PPh ) (1, x = 1; 2, x = 2) and ClSn(2-C F PPh ) (3) were obtained from the reactions of 2-LiC F PPh with MeSnCl (3:1), Me…”
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