Search Results - "Pradeep, Thalappil"
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Atomically Precise Clusters of Noble Metals: Emerging Link between Atoms and Nanoparticles
Published in Chemical reviews (28-06-2017)“…Atomically precise pieces of matter of nanometer dimensions composed of noble metals are new categories of materials with many unusual properties. Over 100…”
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Special Issue on “Nanoclusters”: A Glimpse into the Efforts to Redefine Matter at the Nanoscale
Published in Small (Weinheim an der Bergstrasse, Germany) (01-07-2021)Get full text
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Noble Metal Clusters: Applications in Energy, Environment, and Biology
Published in Particle & particle systems characterization (01-10-2014)“…Sub‐nanometer‐sized metal clusters, having dimensions between metal atoms and nanoparticles, have attracted tremendous attention in the recent past due to…”
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The emerging interface of mass spectrometry with materials
Published in NPG Asia materials (2019)“…Mass spectrometry (MS), a hundred-year-old subject, has been a technique of profound importance to molecular science. Its impact in solid-state materials…”
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Understanding the Evolution of Luminescent Gold Quantum Clusters in Protein Templates
Published in ACS nano (22-11-2011)“…We show that the time-dependent biomineralization of Au3+ by native lactoferrin (NLf) and bovine serum albumin (BSA) resulting in near-infrared (NIR)…”
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Cocrystals of Atomically Precise Noble Metal Nanoclusters
Published in Small (Weinheim an der Bergstrasse, Germany) (01-07-2021)“…Cocrystallization is a phenomenon involving the assembly of two or more different chemical entities in a lattice, occurring typically through supramolecular…”
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Self‐Assembly of Precision Noble Metal Nanoclusters: Hierarchical Structural Complexity, Colloidal Superstructures, and Applications
Published in Small (Weinheim an der Bergstrasse, Germany) (01-07-2021)“…Ligand protected noble metal nanoparticles are excellent building blocks for colloidal self‐assembly. Metal nanoparticle self‐assembly offers routes for a wide…”
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Quantum Clusters in Cavities: Trapped Au15 in Cyclodextrins
Published in Chemistry of materials (22-02-2011)“…We have prepared Au15 quantum clusters anchored to α-, β-, and γ-cyclodextrin (CD) cavities. The synthesis process involves the core etching of larger clusters…”
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Structure-conserving spontaneous transformations between nanoparticles
Published in Nature communications (10-11-2016)“…Ambient, structure- and topology-preserving chemical reactions between two archetypal nanoparticles, Ag 25 (SR) 18 and Au 25 (SR) 18 , are presented. Despite…”
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Assembling Atomically Precise Noble Metal Nanoclusters Using Supramolecular Interactions
Published in ACS Nanoscience Au (15-06-2022)“…Supramolecular chemistry (SC) of noble metal nanoclusters (NMNCs) is one of the fascinating areas of contemporary materials science. It is principally…”
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Phosphorylated cellulose nanofibers exhibit exceptional capacity for uranium capture
Published in Cellulose (London) (01-12-2020)“…We investigate the adsorption of hexavalent uranium, U(VI), on phosphorylated cellulose nanofibers (PHO-CNF) and compare the results with those for native and…”
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New Routes for Multicomponent Atomically Precise Metal Nanoclusters
Published in ACS omega (12-01-2021)“…Atomically precise metal nanoclusters (NCs), protected by a monolayer of ligands, are regarded as potential building blocks for advanced technologies. They are…”
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Accelerated microdroplet synthesis of benzimidazoles by nucleophilic addition to protonated carboxylic acids
Published in Chemical science (Cambridge) (14-07-2020)“…We report a metal-free novel route for the accelerated synthesis of benzimidazole and its derivatives in the ambient atmosphere. The synthetic procedure…”
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Spontaneous weathering of natural minerals in charged water microdroplets forms nanomaterials
Published in Science (American Association for the Advancement of Science) (31-05-2024)“…In this work, we show that particles of common minerals break down spontaneously to form nanoparticles in charged water microdroplets within milliseconds. We…”
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Atomically Precise Noble Metal Cluster-Assembled Superstructures in Water: Luminescence Enhancement and Sensing
Published in Journal of physical chemistry. C (08-10-2020)“…We present an example of host–guest complexes of atomically precise noble metal nanoparticles with cucurbit[7]uril (CB) in water, specifically concentrating…”
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Interparticle Reactions: An Emerging Direction in Nanomaterials Chemistry
Published in Accounts of chemical research (15-08-2017)“…Nanoparticles exhibit a rich variety in terms of structure, composition, and properties. However, reactions between them remain largely unexplored. In this…”
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Metal–Ligand Interface in the Chemical Reactions of Ligand-Protected Noble Metal Clusters
Published in Langmuir (03-09-2019)“…We discuss the role of the metal–ligand (M–L) interfaces in the chemistry of ligand-protected, atomically precise noble metal clusters, a new and expanding…”
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Spatial reorganization of analytes in charged aqueous microdroplets
Published in Chemical science (Cambridge) (23-11-2022)“…Imprinted charged aqueous droplets of micrometer dimensions containing spherical gold and silver nanoparticles, gold nanorods, proteins and simple molecules…”
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Bright, NIR‐Emitting Au23 from Au25: Characterization and Applications Including Biolabeling
Published in Chemistry : a European journal (05-10-2009)“…A novel interfacial route has been developed for the synthesis of a bright‐red‐emitting new subnanocluster, Au23, by the core etching of a widely explored and…”
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Intercluster Reactions between Au25(SR)18 and Ag44(SR)30
Published in Journal of the American Chemical Society (13-01-2016)“…We present the first example of intercluster reactions between atomically precise, monolayer protected noble metal clusters using Au25(SR)18 and Ag44(SR)30…”
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