Search Results - "Powis, Ivan"
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Vibrationally induced inversion of photoelectron forward-backward asymmetry in chiral molecule photoionization by circularly polarized light
Published in Nature communications (05-07-2013)“…Electron–nuclei coupling accompanying excitation and relaxation processes is a fascinating phenomenon in molecular dynamics. A striking and unexpected example…”
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Imaging photoelectron circular dichroism of chiral molecules by femtosecond multiphoton coincidence detection
Published in The Journal of chemical physics (21-12-2013)“…Here, we provide a detailed account of novel experiments employing electron-ion coincidence imaging to discriminate chiral molecules. The full…”
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3
Influence of Vibrational Excitation and Nuclear Dynamics in Multiphoton Photoelectron Circular Dichroism of Fenchone
Published in The journal of physical chemistry letters (25-11-2021)“…We report photoelectron circular dichroism of S-(+)-fenchone enantiomers recorded with state–state vibrational level resolution using picosecond laser (2 + 1)…”
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VUV Photodynamics and Chiral Asymmetry in the Photoionization of Gas Phase Alanine Enantiomers
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (17-04-2014)“…The valence shell photoionization of the simplest proteinaceous chiral amino acid, alanine, is investigated over the vacuum ultraviolet region from its…”
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Enantioselective femtosecond laser photoionization spectrometry of limonene using photoelectron circular dichroism
Published in Physical chemistry chemical physics : PCCP (14-04-2015)“…Limonene is ionized by circularly polarized 420 nm femtosecond laser pulses. Ion mass and photoelectron energy spectra identify the dominant (2 + 1)…”
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Conformer-dependent vacuum ultraviolet photodynamics and chiral asymmetries in pure enantiomers of gas phase proline
Published in Communications chemistry (20-05-2021)“…Proline is a unique amino-acid, with a secondary amine fixed within a pyrrolidine ring providing specific structural properties to proline-rich biopolymers…”
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Photoelectron Spectroscopy and Circular Dichroism in Chiral Biomolecules: l-Alanine
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (10-02-2000)“…A theoretical treatment of the photoionization of the chiral amino acid l-alanine is presented. Particular attention is paid to a previously unobserved…”
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A Valence Photoelectron Imaging Investigation of Chiral Asymmetry in the Photoionization of Fenchone and Camphor
Published in Chemphyschem (22-02-2008)“…Photoelectron circular dichroism (PECD) is investigated in the valence ionization of selected fenchone enantiomers using a photoelectron imaging technique and…”
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Giant Chiral Asymmetry in the C 1s Core Level Photoemission from Randomly Oriented Fenchone Enantiomers
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (24-04-2008)“…Measurements made with a dilute, non-oriented, gas-phase sample of a selected fenchone enantiomer using circularly polarized synchrotron radiation demonstrate…”
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10
Initial-state and final-state vibrational effects in the treatment of molecular photoionization dynamics
Published in Physical review. A, Atomic, molecular, and optical physics (06-07-2011)“…The influence upon molecular photoionization dynamics of vibrational motion of the nuclei in both the initial (neutral) state and the final (molecular ion)…”
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Valence shell one-photon photoelectron circular dichroism in chiral systems
Published in Journal of electron spectroscopy and related phenomena (15-10-2015)“…•Photoelectron circular dichroism (PECD) is a very intense chiroptical effect.•PECD is able to probe molecular structures: conformations, substitution,…”
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12
Photoelectron circular dichroism: Chiral asymmetry in the angular distribution of electrons emitted by (+)-S-carvone
Published in Chirality (New York, N.Y.) (01-09-2008)“…The technique of photoelectron circular dichroism (PECD) is introduced and illustrated by the presentation of results obtained for the C 1s core ionization of…”
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13
Identifying and Understanding Strong Vibronic Interaction Effects Observed in the Asymmetry of Chiral Molecule Photoelectron Angular Distributions
Published in Chemphyschem (03-03-2017)“…Electron–ion coincidence imaging is used to study chiral asymmetry in the angular distribution of electrons emitted from randomly‐oriented enantiomers of two…”
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Vibrationally-resolved photoelectron spectroscopy and photoelectron circular dichroism of bicyclic monoterpene enantiomers
Published in Journal of molecular spectroscopy (01-11-2018)“…[Display omitted] •PhotoElectron Spectra & Circular Dichroism (PECD) with vibrational resolution.•A record 37% chiral asymmetry factor found for PECD of…”
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The Interplay Between Conformation and Absolute Configuration in Chiral Electron Dynamics of Small Diols
Published in Angewandte Chemie International Edition (05-09-2016)“…A competition between chiral characteristics alternatively attributable to either conformation or to absolute configuration is identified. Circular dichroism…”
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Enantiomer-specific analysis of multi-component mixtures by correlated electron imaging–ion mass spectrometry
Published in Nature communications (24-06-2015)“…Simultaneous, enantiomer-specific identification of chiral molecules in multi-component mixtures is extremely challenging. Many established techniques for…”
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Experimental and Theoretical Investigation of the 3sp(d) Rydberg States of Fenchone by Polarized Laser Resonance‐Enhanced‐Multiphoton‐Ionization and Fourier Transform VUV Absorption Spectroscopy
Published in Chemphyschem (03-11-2020)“…The VUV absorption spectrum of fenchone is re‐examined using synchrotron radiation Fourier transform spectrometry, revealing new vibrational structure…”
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The role of the intermediate state in angle-resolved photoelectron studies using (2 + 1) resonance-enhanced multiphoton ionization of the chiral terpenes, α-pinene and 3-carene
Published in Molecular physics (17-01-2021)“…Photoelectron angular distributions (PADs), ranging up to the maximum 6th order Legendre polynomial term set by the Yang theorem, have been recorded for the (2…”
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Wavelength dependent photoelectron circular dichroism of limonene studied by femtosecond multiphoton laser ionization and electron-ion coincidence imaging
Published in The Journal of chemical physics (28-09-2016)“…Enantiomers of the monoterpene limonene have been investigated by (2 + 1) resonance enhanced multiphoton ionization and photoelectron circular dichroism…”
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