Search Results - "Pothupitiya, Jinal U"
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Polyglycerol and Poly(ethylene glycol) exhibit different effects on pharmacokinetics and antibody generation when grafted to nanoparticle surfaces
Published in Biomaterials (01-08-2022)“…Poly(ethylene glycol) (PEG) is widely employed for passivating nanoparticle (NP) surfaces to prolong blood circulation and enhance localization of NPs to…”
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2
Triclocarban: Commercial Antibacterial and Highly Effective H‑Bond Donating Catalyst for Ring-Opening Polymerization
Published in ACS macro letters (18-04-2017)“…The antibacterial compound, triclocarban (TCC), is shown to be a highly effective H-bond donating catalyst for ring-opening polymerization (ROP) when applied…”
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Urea and Thiourea H‑Bond Donating Catalysts for Ring-Opening Polymerization: Mechanistic Insights via (Non)linear Free Energy Relationships
Published in Macromolecules (24-04-2018)“…Hammett-style free energy studies of (thio)urea/MTBD mediated ring-opening polymerization (ROP) of δ-valerolactone reveal the complicated interplay of…”
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H‑Bonding Organocatalysts for the Living, Solvent-Free Ring-Opening Polymerization of Lactones: Toward an All-Lactones, All-Conditions Approach
Published in Macromolecules (28-11-2017)“…The developing urea class of H-bond donors facilitates the solvent-free ROP of lactones at ambient and elevated temperatures, displaying enhanced rates and…”
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5
Bis- and Tris-Urea H‑Bond Donors for Ring-Opening Polymerization: Unprecedented Activity and Control from an Organocatalyst
Published in ACS macro letters (16-08-2016)“…A new class of H-bond donating ureas was developed for the ring-opening polymerization (ROP) of lactone monomers, and they exhibit dramatic rate acceleration…”
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Coupled equilibria in H-bond donating ring-opening polymerization: The effective catalyst-determined shift of a polymerization equilibrium
Published in European polymer journal (01-10-2017)“…[Display omitted] •ROP and catalyst/reagent binding equilibria are highly coupled.•Thiourea favors depolymerization to provide a lactone binding partner to…”
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Journal Article -
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Organocatalytic Ring-Opening Polymerization of Cyclic Lactones: Development of New Catalysts Guided by Mechanism
Published 01-01-2019“…The use of non-biodegradable polymeric materials has been a growing threat to the environment. Attention has been greatly focused by many scientists on…”
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Dissertation