Search Results - "Portinha, Daniel"
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The aza-Michael reaction as an alternative strategy to generate advanced silicon-based (macro)molecules and materials
Published in Progress in polymer science (01-09-2017)“…Aza-Michael reaction is a simple and accessible addition reaction performed at moderate temperature, possibly without a catalyst and without releasing…”
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Synthesis of linear and crosslinked isosorbide-containing poly(β-thioether ester) via amine-catalyzed thiol-Michael addition
Published in European polymer journal (15-11-2024)“…[Display omitted] •New isosorbide-containing poly(β-thioether ester)s.•Amine-catalyzed thiol-Michael addition polymerization.•Polymers, oligomers with good…”
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Wettability adjustment of PVDF surfaces by combining radiation-induced grafting of (2,3,4,5,6)-pentafluorostyrene and subsequent chemoselective click-type reaction
Published in Polymer (Guilford) (27-05-2014)“…A novel strategy combining (2,3,4,5,6)-pentafluorostyrene (PFS) grafting and subsequent thiol/para-fluorine "click" type post-grafting modification is…”
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Thermoplastic silicone elastomers as materials exhibiting high mechanical properties and/or self-healing propensity
Published in Journal of adhesion science and technology (17-12-2021)“…Silicones are outstanding elastomers with e.g. great thermal properties and purity that make them important commercial materials. Current Research and…”
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Zwitterionic Silicone Materials Derived from Aza‐Michael Reaction of Amino‐Functional PDMS with Acrylic Acid
Published in Macromolecular rapid communications. (01-03-2021)“…Supramolecular zwitterionic silicones are synthesized by aza‐Michael reaction between acrylic acid and amine‐functional polydimethylsiloxanes. The in‐depth…”
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Toward replacement of styrene by bio-based methacrylates in unsaturated polyester resins
Published in European polymer journal (01-06-2015)“…[Display omitted] •Various potentially biobased methacrylates are evaluated as styrene replacement in UPRs.•Volatility, viscosity, miscibility are first…”
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Tuning features of H-bonded layer by layer assembly of poly(4-vinyl pyridine) and carboxylated poly-(2,3,4,5,6-pentafluorostyrene) synthesized through para-fluoro-thiol reaction
Published in European polymer journal (01-08-2019)“…[Display omitted] •Mercapto-propionic acid was grafted onto PPFS by para-fluoro-thiol reaction.•The extent of modification of PPFS was tuned by the reactional…”
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Controlled perfluorination of poly(2,3,4,5,6-pentafluorostyrene) (PPFS) and PPFS-functionalized fumed silica by thiol-para-fluoro coupling: Towards the design of self-cleaning (nano)composite films
Published in European polymer journal (01-05-2018)“…[Display omitted] •Perfluorinated thiol used to modify PPFS by controlled thiol-para-fluoro coupling.•Surface energy of resulting polymers tuned by degree of…”
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Direct Amination of Isohexides via Borrowing Hydrogen Methodology: Regio‐ and Stereoselective Issues
Published in European journal of organic chemistry (07-02-2020)“…The regio and diastereoselective direct mono or diamination of bio‐based isohexides (isosorbide and isomannide) has been developed through borrowing hydrogen…”
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Extra-Soft Self-Healable Supramolecular Silicone Elastomers from Bis-Amide-PDMS Multiblock Copolymers Prepared by Aza-Michael Reaction
Published in ACS applied polymer materials (10-02-2023)“…Silicone elastomers involving self-associating bis-amide groups were synthesized by aza-Michael addition between N,N′-methylenebis(acrylamide) and low…”
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Layer by Layer H‑Bonded Assembly of P4VP with Various Hydroxylated PPFS: Impact of the Donor Strength on Growth Mechanism and Surface Features
Published in Langmuir (09-09-2014)“…Hydrogen bond mediated films made by step by step deposition of poly(4-vinylpyridine) (P4VP) and hydroxylated poly(2,3,4,5,6-pentafluorostyrene) (PPFS)…”
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Instantaneous stereocomplex driven self-assembly of enantiomeric poly(vinyl alcohol)-graft-oligo(lactide) copolymers in DMSO and thin film formation thereof
Published in Polymer (Guilford) (19-11-2015)“…The ability of enantiomeric graft copolymers composed of partially acetylated poly(vinyl alcohol) (PVA) as backbone and oligo(l-lactide) (OLLA) or…”
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Nanomechanical and tribological characterization of the MPC phospholipid polymer photografted onto rough polyethylene implants
Published in Colloids and surfaces, B, Biointerfaces (01-08-2013)“…[Display omitted] ► p(MPC) brushes were photografted on rough surface of UHMWPE joint implants. ► p(MPC) thickness and mechanical properties are characterized…”
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Polyfluorinated mercaptoalcohol as a H-bond modifier of poly(2,3,4,5,6-pentafluorostyrene) (PPFS) enhancing miscibility of hydroxylated-PPFS with various acceptor polymers
Published in Polymer (Guilford) (08-07-2013)“…Novel strong hydrogen-bond donor hydroxylated-poly(2,3,4,5,6-pentafluorostyrene) (PPFSOH) copolymers were synthesized via a versatile and chemoselective…”
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Electron spin resonance quantitative monitoring of five different radicals in γ-irradiated polyvinylidene fluoride
Published in Radiation physics and chemistry (Oxford, England : 1993) (01-05-2013)“…The complex superimposition of electron spin resonance (ESR) signals of the five different radicals generated on PVDF upon γ-rays exposure is fully simulated…”
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Crosslinking of poly(vinylene fluoride) separators by gamma-irradiation for electrochemical high power charge applications
Published in Electrochimica acta (01-07-2015)“…•High dose of Gamma rays (Co60) causes chain scissionof PVdF based separators.•Irradiated membranes with different cross-linkig coagents [(Triallylisocyanurate…”
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Effect of dose and subsequent annealing on radicals distribution in y-irradiated PVDF as quantitatively monitored by ESR: Correlation between network features and radical type
Published in Radiation physics and chemistry (Oxford, England : 1993) (01-05-2013)“…A simulation model which takes into account the molecular structure, the localization and the chemical environment of radicals is used to quantitatively…”
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ESR investigation of radicals formed in γ-irradiated vinylidene fluoride based copolymer: P(VDF-co-HFP)
Published in Radiation physics and chemistry (Oxford, England : 1993) (01-05-2013)“…Samples of copolymer based on vinylidene fluoride and hexafluoropropene P(VDF-co-HFP) were exposed to γ-radiation performed under an inert atmosphere and the…”
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Effect of dose and subsequent annealing on radicals distribution in γ-irradiated PVDF as quantitatively monitored by ESR: Correlation between network features and radical type
Published in Radiation physics and chemistry (Oxford, England : 1993) (01-05-2013)“…A simulation model which takes into account the molecular structure, the localization and the chemical environment of radicals is used to quantitatively…”
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