Search Results - "Porhiel, Emmanuel"
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Synthesis and characterization of partially β-fluorinated 5,10,15,20-tetraphenylporphyrins and some derivatives
Published in Tetrahedron (12-08-2002)“…The synthesis of partially β-fluorinated meso-tetraphenylporphyrins using Lindsey conditions, has been examined, starting either from 3,4-difluoro-1 H-pyrrole…”
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Tetraethylammonium tetraselenotungstate: a new and efficient selenium transfer reagent for the chemoselective synthesis of functionalised diselenides
Published in Tetrahedron letters (10-03-2003)“…A variety of functionalised organodiselenides were prepared in excellent yields from the corresponding halides and activated alcohols on treatment with…”
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3
Utility of tetrathiomolybdate and tetraselenotungstate: efficient synthesis of cystine, selenocystine, and their higher homologues
Published in Tetrahedron letters (07-07-2003)“…Efficient synthesis of cystine, selenocystine, and their higher homologues like homo and bishomo amino acid derivatives from natural amino acid derivatives…”
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(β-Octafluoro-meso-tetraarylporphyrin)manganese Complexes: Synthesis, Characterization and Catalytic Behaviour in Monooxygenation Reactions
Published in European journal of inorganic chemistry (01-05-2000)“…The synthesis and characterization of manganese complexes of β‐octafluoro‐meso‐tetraarylporphyrins are reported. The presence of the electron‐withdrawing…”
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5
On the role of β-fluorine substitution on the extent of core deformation of porphyrin dications
Published in Tetrahedron letters (11-11-2002)“…Careful analysis of fully and partially β-fluorinated dicationic porphyrins have been performed suggesting an electronic influence of the β-fluorine atoms on…”
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6
Synthesis and applications of propargyl pentafluorophenyl carbonate for peptide synthesis
Published in Tetrahedron letters (25-03-2002)“…Propargyl pentafluorophenyl carbonate was synthesised in quantitative yield by the reaction of propargyl chloroformate and pentafluorophenol. All the…”
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Functionalised alkenylcarbene metal complexes (M=Ru, W, Cr) by activation of propargyl alcohol derivatives
Published in Journal of organometallic chemistry (20-04-2000)“…The reaction of arene ruthenium(II) complexes [Ru(η 6-C 6Me 4R 2)(PMe 3)Cl 2] ( 1, R=Me; 1′, R=H) with propargyl alcohol derivatives HCC(H)(OH)( p-C 6H 4X) (…”
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β-Octafluoro- meso-tetraarylporphyrin iron complexes as catalysts for monooxygenation reactions
Published in Tetrahedron letters (02-07-1998)“…The stability and catalytic activity of the β-octafluoro- meso-tetraarylporphyrin iron complexes for cyclooctene epoxidation, cyclohexane and benzene…”
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Tetraarylporphyrin synthesis by electrochemical oxidation of porphyrinogens
Published in Electrochimica acta (30-03-2001)“…The electrochemical synthesis of tetraarylporphyrins has been reinvestigated. Whereas the direct electrolysis of a mixture of benzaldehyde and pyrrole gave…”
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Synthesis of mixed bis(alkenylcarbene) ditungsten complexes by sequential activation of dialkynols
Published in Journal of organometallic chemistry (01-07-1997)“…The synthesis of new bis(alkenylcarbene) ditungsten complexes 2a–b, 5a and 6a has been achieved from W(CO) 5(THF), via activation of the dialkynol derivatives…”
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