Search Results - "Polach, Sharon A"
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Activation of Alkyl Halides via a Silver-Catalyzed Carbene Insertion Process
Published in Journal of the American Chemical Society (06-08-2003)“…The silver complex [HB(3,5-(CF3)2Pz)3]Ag(THF) featuring a highly fluorinated tris(pyrazolyl)borate ligand catalyzes the formation of aliphatic carbon−halogen…”
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Copper(I) Ethylene Adducts and Aziridination Catalysts Based on Fluorinated Tris(pyrazolyl)borates [HB(3-(CF3),5-(R)Pz)3]- (where R = CF3, C6H5, H; Pz = pyrazolyl)
Published in Organometallics (01-04-2002)“…The ethylene adducts of copper(I) tris(pyrazolyl)borates, [HB(3,5-(CF3)2Pz)3]Cu(C2H4), [HB(3-(CF3),5-(C6H5)Pz)3]Cu(C2H4), and [HB(3-(CF3)Pz)3]Cu(C2H4), have…”
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Coinage metal complexes of 3,5-bis(trifluoromethyl)pyrazolate ligand: Synthesis and characterization of {[3,5-(CF 3) 2Pz]Cu} 3 and {[3,5-(CF 3) 2Pz]Ag} 3
Published in Journal of fluorine chemistry (24-04-2000)“…Copper(I) and silver(I) adducts of [3,5-(CF 3) 2Pz] − have been prepared in good yield by reacting the corresponding metal(I) oxide with pyrazole [3,5-(CF 3)…”
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Copper and Silver Complexes Containing Organic Azide Ligands: Syntheses, Structures, and Theoretical Investigation of [HB(3,5-(CF3)2Pz)3]CuNNN(1-Ad) and [HB(3,5-(CF3)2Pz)3]AgN(1-Ad)NN (Where Pz = Pyrazolyl and 1-Ad = 1-Adamantyl)
Published in Inorganic chemistry (21-08-2000)“…Treatment of [HB(3,5-(CF3)2Pz)3]Na(THF) with CF3SO3Cu followed by 1-azidoadamantane affords [HB(3,5-(CF3)2Pz)3]CuNNN(1-Ad) in 65% yield. The solid state…”
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Coinage metal complexes of 3,5-bis(trifluoromethyl)pyrazolate ligand
Published in Journal of fluorine chemistry (01-04-2000)Get full text
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