Search Results - "Poe, Todd N."

Altering the spectroscopy, electronic structure, and bonding of organometallic curium(III) upon coordination of 4,4′−bipyridine by Long, Brian N., Beltrán-Leíva, María J., Sperling, Joseph M., Poe, Todd N., Celis-Barros, Cristian, Albrecht-Schönzart, Thomas E.

“…Structural and electronic characterization of (Cp′ 3 Cm) 2 ( μ −4,4′−bpy) (Cp′ = trimethylsilylcyclopentadienyl, 4,4′−bpy = 4,4′−bipyridine) is reported and…”
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Understanding the Stabilization and Tunability of Divalent Europium 2.2.2B Cryptates by Poe, Todd N, Beltrán-Leiva, Maria J, Celis-Barros, Cristian, Nelson, William L, Sperling, Joseph M, Baumbach, Ryan E, Ramanantoanina, Harry, Speldrich, Manfred, Albrecht-Schönzart, Thomas E

“…Lanthanides such as europium with more accessible divalent states are useful for studying redox stability afforded by macrocyclic organic ligands. Substituted…”
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Cyclopentadienyl coordination induces unexpected ionic Am−N bonding in an americium bipyridyl complex by Long, Brian N., Beltrán-Leiva, María J., Celis-Barros, Cristian, Sperling, Joseph M., Poe, Todd N., Baumbach, Ryan E., Windorff, Cory J., Albrecht-Schönzart, Thomas E.

“…Variations in bonding between trivalent lanthanides and actinides is critical for reprocessing spent nuclear fuel. The ability to tune bonding and the…”
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Creation of an unexpected plane of enhanced covalency in cerium(III) and berkelium(III) terpyridyl complexes by Gaiser, Alyssa N., Celis-Barros, Cristian, White, Frankie D., Beltran-Leiva, Maria J., Sperling, Joseph M., Salpage, Sahan R., Poe, Todd N., Gomez Martinez, Daniela, Jian, Tian, Wolford, Nikki J., Jones, Nathaniel J., Ritz, Amanda J., Lazenby, Robert A., Gibson, John K., Baumbach, Ryan E., Páez-Hernández, Dayán, Neidig, Michael L., Albrecht-Schönzart, Thomas E.

“…Controlling the properties of heavy element complexes, such as those containing berkelium, is challenging because relativistic effects, spin-orbit and…”
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Atypical Spectroscopic Behavior in Divalent Lanthanide Dibenzyldiaza-18-crown‑6 Complexes (Ln = Sm, Eu, Yb) by Poe, Todd N, Gaiser, Alyssa N, Albrecht-Schönzart, Thomas E

“…Direct synthesis of LnI2 with 1,10-dibenzyl-1,10-diaza-18-crown-6 in organic media under air-free conditions yields several new Ln2+ diaza-crown complexes,…”
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Structural and Spectroscopic Analysis of Ln(II) 18-crown‑6 and Benzo-18-crown‑6 Complexes (Ln = Sm, Eu, Yb) by Poe, Todd N, Molinari, Sarah, Justiniano, Samantha, McLeod, Grace M, Albrecht-Schönzart, Thomas E

“…Three Ln2+ 18-crown-6 complexes of the formula Ln­(18-crown-6)­I2 (Ln = Sm, Eu, Yb) were isolated from the explicit synthesis of the corresponding LnI2 salts…”
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Trivalent f‑Element Squarates, Squarate-Oxalates, and Cationic Materials, and the Determination of the Nine-Coordinate Ionic Radius of Cf(III) by Brenner, Natasha, Sperling, Joseph M, Poe, Todd N, Celis-Barros, Cristian, Brittain, Kristi, Villa, Eric M, Albrecht-Schmitt, Thomas E, Polinski, Matthew J

“…The synthesis, structure, and solid-state UV–vis–NIR spectroscopy of four new f-element squarates, M2(C4O4)3(H2O)4 (M = Eu, Am, Cf) and…”
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Influence of Outer-Sphere Anions on the Photoluminescence from Samarium(II) Crown Complexes by Poe, Todd N, Molinari, Sarah, Beltran-Leiva, Maria J, Celis-Barros, Cristian, Ramanantoanina, Harry, Albrecht-Schönzart, Thomas E

“…Three samarium­(II) crown ether complexes, [Sm­(15-crown-5)2]­I2 (1), [Sm­(15-crown-5)2]­I2·CH3CN (2), and [Sm­(benzo-15-crown-5)2]­I2 (3), have been prepared…”
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Isolation of a californium(II) crown–ether complex by Poe, Todd N., Ramanantoanina, Harry, Sperling, Joseph M., Wineinger, Hannah B., Rotermund, Brian M., Brannon, Jacob, Bai, Zhuanling, Scheibe, Benjamin, Beck, Nicholas, Long, Brian N., Justiniano, Samantha, Albrecht-Schönzart, Thomas E., Celis-Barros, Cristian

“…The actinides, from californium to nobelium (Z = 98–102), are known to have an accessible +2 oxidation state. Understanding the origin of this chemical…”
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Two Neptunium(III) Mellitate Coordination Polymers: Completing the Series Np–Cf of Trans-Uranic An(III) Mellitates by Beck, Nicholas B., Bai, Zhuanling, Brannon, Jacob P., Martinez, Daniela Gomez, Grödler, Dennis, Long, Brian N., Poe, Todd N., Rotermund, Brian M., Albrecht-Schönzart, Thomas E., Sperling, Joseph M.

“…Two neptunium­(III) mellitates, 237Np2(mell)­(H2O)9·1.5H2O (Np-1α) and 237Np2(mell)­(H2O)8·2H2O (Np-1β), have been synthesized from 237NpCl4(dme)2 by reduction…”
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[Ag2M(Te2O5)2]SO4 (M = CeIV or ThIV): A New Purely Inorganic d/f-Heterometallic Cationic Material by Poe, Todd N, White, Frankie D, Proust, Vanessa, Villa, Eric M, Polinski, Matthew J

“…Two new isotypic d/f-heterometallic purely inorganic cationic materials, [Ag2M­(Te2O5)2]­SO4 (M = CeIV or ThIV), were synthesized using the metal oxides (MO2…”
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Stabilization of Pu(IV) in PuBr4(OPCy3)2 and Comparisons with Structurally Similar ThX4(OPR3)2 (R = Cy, Ph) Molecules by Windorff, Cory J., Goodwin, Conrad A. P., Sperling, Joseph M., Albrecht-Schönzart, Thomas E., Bai, Zhuanling, Evans, William J., Huffman, Zachary K., Jeannin, Renaud, Long, Brian N., Mills, David P., Poe, Todd N., Ziller, Joseph W.

“…The pursuit of a trivalent plutonium halide phosphine oxide compound, e.g., “PuBr3(OPR)3,” instead led to the isolation of the tetravalent…”
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A Single Small-Scale Plutonium Redox Reaction System Yields Three Crystallographically-Characterizable Organoplutonium Complexes by Windorff, Cory J, Sperling, Joseph M, Albrecht-Schönzart, Thomas E, Bai, Zhuanling, Evans, William J, Gaiser, Alyssa N, Gaunt, Andrew J, Goodwin, Conrad A. P, Hobart, David E, Huffman, Zachary K, Huh, Daniel N, Klamm, Bonnie E, Poe, Todd N, Warzecha, Evan

“…An approach to obtaining substantial amounts of data from a hazardous starting material that can only be obtained and handled in small quantities is…”
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Pressure-Induced Spectroscopic Changes in a Californium 1D Material Are Twice as Large as Found in the Holmium Analog by Sperling, Joseph M, Warzecha, Evan, Windorff, Cory J, Klamm, Bonnie E, Gaiser, Alyssa N, Whitefoot, Megan A, White, Frankie D, Poe, Todd N, Albrecht-Schönzart, Thomas E

“…In this study, the synthesis, characterization, and pressure response of a 1D californium mellitate (mellitate = 1,2,3,4,5,6-benzenehexacarboxylate)…”
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Electrochemical Studies of Selected Lanthanide and Californium Cryptates by Marsh, Matthew L, White, Frankie D, Meeker, David S, McKinley, Carla D, Dan, David, Van Alstine, Cayla, Poe, Todd N, Gray, Danielle L, Hobart, David E, Albrecht-Schmitt, Thomas E

“…Efforts to quantitatively reduce CfIII → CfII in solution as well as studies of its cyclic voltammetry have been hindered by its scarcity, significant…”
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[Ag 2 M(Te 2 O 5 ) 2 ]SO 4 (M = Ce IV or Th IV ): A New Purely Inorganic d/f-Heterometallic Cationic Material by Poe, Todd N, White, Frankie D, Proust, Vanessa, Villa, Eric M, Polinski, Matthew J

“…Two new isotypic d/f-heterometallic purely inorganic cationic materials, [Ag M(Te O ) ]SO (M = Ce or Th ), were synthesized using the metal oxides (MO and TeO…”
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Atypical Spectroscopic Behavior in Divalent Lanthanide Dibenzyldiaza-18-crown-6 Complexes (Ln = Sm, Eu, Yb) by Poe, Todd N., Gaiser, Alyssa N., Albrecht-Schönzart, Thomas E.

“…Not provided…”
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Influence of Outer-Sphere Anions on the Photoluminescence from Samarium(II) Crown Complexes by Poe, Todd N., Molinari, Sarah, Beltran-Leiva, Maria J., Celis-Barros, Cristian, Ramanantoanina, Harry, Albrecht-Schönzart, Thomas E.

“…Not provided…”
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Stabilization of Pu(IV) in PuBr 4 (OPCy 3 ) 2 and Comparisons with Structurally Similar ThX 4 (OPR 3 ) 2 (R = Cy, Ph) Molecules by Windorff, Cory J., Goodwin, Conrad A. P., Sperling, Joseph M., Albrecht-Schönzart, Thomas E., Bai, Zhuanling, Evans, William J., Huffman, Zachary K., Jeannin, Renaud, Long, Brian N., Mills, David P., Poe, Todd N., Ziller, Joseph W.

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Coordination Chemistry and Spectroscopic Properties of Eu(II), Sm(II), and Yb(II) with 12-Crown‑4 by Wineinger, Hannah B., Scheibe, Benjamin, Brannon, Jacob P., Poe, Todd N., Rotermund, Brian M., Sperling, Joseph M., Albrecht-Schönzart, Thomas E.

“…The coordinative properties of 12-crown-4 (12c4) with Sm2+, Eu2+, and Yb2+ have been examined using nonaqueous and inert atmosphere conditions and led to the…”
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