Search Results - "Podyacheva, Evgeniya"
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Reduction of phosphine oxides to phosphines
Published in Tetrahedron letters (21-02-2019)“…[Display omitted] •Methods of reduction based on borane complexes afford to obtain derivatives protected from reoxidization.•Silanes are the most widespread…”
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Borrowing Hydrogen Amination Reactions: A Complex Analysis of Trends and Correlations of the Various Reaction Parameters
Published in ACS catalysis (17-06-2022)“…Borrowing hydrogen or the hydrogen autotransfer amination is a powerful approach to create single C–N bonds, starting from stable and readily available…”
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Tandem, Catalyst‐Free C‐C Synthesis of Nitriles from Aldehydes and Methyl Cyanoacetate with Sodium Hypophosphite
Published in European journal of organic chemistry (19-11-2024)“…Saturated carbon chain elongation is a common refrain in numerous synthetic pathways. While the formation of C‐C single bonds is of primary importance in…”
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4
Simplified Version of the Eschweiler–Clarke Reaction
Published in Journal of organic chemistry (01-03-2024)“…The traditional Eschweiler–Clarke reaction is a three-component process involving formaldehyde, amine, and formic acid. In this work, we showed that the…”
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Redox Condensations of o‑Nitrobenzaldehydes with Amines under Mild Conditions: Total Synthesis of the Vasicinone Family
Published in Journal of organic chemistry (17-07-2020)“…A total synthesis of the vasicinone family of natural products from bulk chemicals was developed. Reductive condensation of o-nitrobenzaldehydes with amines…”
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6
Planar Chiral Rhodium Complex Based on the Tetrahydrofluorenyl Core for Enantioselective Catalysis
Published in Organic letters (15-12-2023)“…A simple four-step route to a chiral tetrahydrofluorenyl rhodium catalyst from naturally occurring (−)-α-pinene was developed. Our approach does not use…”
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Syngas Instead of Hydrogen Gas as a Reducing AgentA Strategy To Improve the Selectivity and Efficiency of Organometallic Catalysts
Published in ACS catalysis (06-05-2022)“…Catalytic reduction reactions play a major role in modern chemistry and are often based on hydrogen gas as a reducing agent. However, the high reactivity of…”
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Sodium Hypophosphite as a Bulk and Environmentally Friendly Reducing Agent in the Reductive Amination
Published in Organic letters (28-10-2022)“…NaH2PO2 was found to promote reductive amination. Being nontoxic, stable, environmentally benign, and available in bulk amounts, this reducing agent showed a…”
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Fluorene Complexes of Group 9 Metals: Fluorene Effect and Application for Reductive Amination
Published in Organometallics (26-08-2019)“…The η6-fluorene cyclopentadienyl complexes [(η5-C5R5)M(η6-fluorene)](SbF6)2 (1: M = Co, R = Me; 2a: M = Rh, R = H; 2b: M = Ir, R = H) were synthesized by…”
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