Search Results - "Plumet, Joaquin"
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1,3‐Dipolar Cycloaddition Reactions of Nitrile Oxides under “Non‐Conventional” Conditions: Green Solvents, Irradiation, and Continuous Flow
Published in ChemPlusChem (Weinheim, Germany) (01-10-2020)“…The 1,3‐dipolar cycloaddition reactions (DCs) of nitrile oxides (NOs) to alkenes and alkynes are useful methods for the synthesis of 2‐isoxazolines and…”
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Ring Rearrangement Metathesis in 7-Oxabicyclo[2.2.1]heptene (7-Oxanorbornene) Derivatives. Some Applications in Natural Product Chemistry
Published in Natural product communications (01-05-2017)“…Metathesis reactions is firmly established as a valuable synthetic tool in organic chemistry, clearly comparable with the venerable Diels-Alder and Wittig…”
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Metathesis Reactions of Carbohydrates: Recent Highlights in Alkyne Metathesis
Published in European Journal of Organic Chemistry (01-04-2011)“…Metathesis processes play a prominent role in the development of useful synthetic transformations because of their mildness and tolerance of functional groups…”
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Metathesis Reactions of Carbohydrates: Recent Highlights in Cross-Metathesis
Published in European Journal of Organic Chemistry (01-11-2010)“…Metathetical processes play a prominent role in the development of useful transformations because of their mildness, tolerance of functional groups, and…”
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Tuning the Chemoselectivity of the Metathesis Reactions of N-Substituted 2-Azabicyclo[2.2.1]hept-5-en-3-one
Published in European Journal of Organic Chemistry (01-08-2008)“…By using the second‐generation Hoveyda–Grubbs precatalyst, the metathesis transformations of N‐substituted 2‐azabicyclo[2.2.1]hept‐5‐en‐3‐one derivatives have…”
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Synthesis of 2,8-disubstituted-4,7-dioxatricyclo[3.2.1.03,6]octane and 2,6-dioxabicyclo[3.2.0]heptane derivatives starting from furan
Published in ARKIVOC (22-10-2010)Get full text
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A Convenient Approach to Polycyclic Derivatives with a cis‐Fused 2,6‐Dioxabicyclo[4.3.0]nonane System by the Sequence Ring‐Opening/Intramolecular Ring‐Closing Enyne Metathesis/Diels–Alder Reaction
Published in European Journal of Organic Chemistry (01-02-2009)“…7‐Oxanorbornene derivatives functionalized with alkyneappendages undergo intramolecular enyne metathesis reactions to give cis‐fused…”
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Antiangiogenic versus cytotoxic activity in analogues of aeroplysinin-1
Published in Bioorganic & medicinal chemistry (01-08-2007)“…A series of analogues of the potentially angiogenic inhibitor aeroplysinin-1 1 were synthesized and their in vitro antiangiogenic and cytotoxic activities…”
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A Straightforward Synthesis of Pyran[2’,3’:4,5]furo[3,2-b]pyran from Furan
Published in Heterocycles (03-09-2008)Get full text
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Domino Metathesis of 2-Azanorbornenones: A New Strategy for the Enatioselective Synthesis of 1-Azabicyclic Compounds
Published in Journal of organic chemistry (22-02-2002)“…Domino metathesis of N-alkylated derivatives of (1S)-2-azanorborn-5-en-3-one allowed for the enantioselective synthesis of pyrrolizidine, quinolizidine,…”
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Synthesis and Conformational and Biological Aspects of Carbasugars
Published in Chemical reviews (01-05-2007)“…In carbasugars, a series of derivations occurr in which the ring oxygen of a monosaccharide has been replaced by a methylene group. The synthesis as well as…”
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Stereochemistry of the Tetrabutylammonium Cyanide-Catalyzed Cyanosylilation of Cyclic α,β-Epoxyketones - Dependence of the Diastereoselectivity on the Ring Size
Published in European Journal of Organic Chemistry (01-09-2006)“…The diastereoselective Bu4NCN‐catalyzed addition of TMSCN to cyclic α,β‐epoxyketones has been considered. Good diastereoselectivities were found, depending on…”
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The Intermolecular Pauson-Khand Reaction of Sugar-Derived Azaenynes: A Case of Total Diastereoselectivity
Published in Journal of carbohydrate chemistry (01-05-2006)“…Sugar azaenynes 1a and 1b, easily available from D-glucal and D-galactal, respectively, react with norbornene and norbornadiene under Pauson-Khand conditions…”
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Synthesis of Optically Pure 4-Hydroxymethyl-3-phenoxy-2-azetidinone from D-Glucal
Published in Heterocycles (01-12-2007)Get full text
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Diels−Alder Reactions of Masked o-Benzoquinones: New Experimental Findings and a Theoretical Study of the Inverse Electron Demand Case
Published in Journal of organic chemistry (02-04-2004)“…Diels−Alder reactions of the masked o-benzoquinone (MOB) 2 with vinylene carbonate (3), the bicyclic derivatives 4, 5, and 6, and the intramolecular version of…”
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Methyltriphenylphosphonium iodide catalyzes the addition of trimethylsilyl cyanide to aldehydes
Published in Tetrahedron letters (04-08-2003)“…Methyltriphenylphosphonium iodide catalyzes the formation of cyanohydrin trimethylsilyl ethers of aliphatic, aromatic and heterocyclic aldehydes. Graphic…”
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Synthesis of Enantiopure 3-Azabicyclo[3.3.0]octen-7-one Derivatives via Intramolecular Pauson−Khand Cycloaddition Reaction Using Tri-O-acetyl-d-glucal as Starting Material
Published in Journal of organic chemistry (17-05-2002)“…Some N-substituted-3-azabicyclo[3.3.0]octen-7-one derivatives have been synthesized in an enantiomerically pure form starting from tri-O-acetyl-d-glucal via…”
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Derivatives of 7-oxabicyclo[2.2.1]heptane in nature and as useful synthetic intermediates
Published in Tetrahedron (26-11-1999)“…Derivatives of 7-oxabicyclo[2.2.1]heptane are found in Nature, some of them and synthetic analogues show interesting biological activities. Methods for their…”
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Sequential Metathesis in Oxa- and Azanorbornene Derivatives
Published in European journal of organic chemistry (01-02-2003)“…Ring‐opening metathesis (ROM), when applied to the synthesis of bicyclic alkenes, is the basis of ring‐opening‐metathesis polymerisation (ROMP). This…”
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