Search Results - "Piovan, Leandro"
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Immobilization of Pseudomonas cepacia lipase on layered double hydroxide of Zn/Al-Cl for kinetic resolution of rac-1-phenylethanol
Published in Enzyme and microbial technology (01-11-2019)“…[Display omitted] •Pseudomonas cepacia lipase was immobilized onto Zn/Al-Cl LDH with 96% immobilization efficiency.•Hydrolytic activity in organic medium was…”
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2
Immobilization and characterization of a new regioselective and enantioselective lipase obtained from a metagenomic library
Published in PloS one (23-02-2015)“…In previous work, a new lipase and its cognate foldase were identified and isolated from a metagenomic library constructed from soil samples contaminated with…”
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3
Improving the enantioselective bioreduction of aromatic ketones mediated by Aspergillus terreus and Rhizopus oryzae: the role of glycerol as a co-solvent
Published in Tetrahedron: asymmetry (16-07-2009)“…The improvement of the enzymatic performance of Aspergillus terreus and Rhizopus oryzae in enantioselective bioreductions by using glycerol as a co-solvent has…”
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4
Brazilian contributions to alcohol dehydrogenases-catalyzed reactions throughout the 21st century
Published in Results in Chemistry (01-01-2022)“…[Display omitted] •ADH-catalyzed reactions are widely employed to achieve optically active compounds.•Brazil was responsible for almost 3% of the production…”
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5
Enzymatic kinetic resolution of aliphatic sec-alcohols by LipG9, a metagenomic lipase
Published in Journal of molecular catalysis. B, Enzymatic (01-03-2016)“…[Display omitted] •Metagenomics is a useful technique for finding new biocatalysts.•LipG9 was successful employed in enzymatic kinetic resolution of aliphatic…”
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6
Characterization of an immobilized recombinant lipase from Rhizopus oryzae: Synthesis of ethyl-oleate
Published in Biocatalysis and agricultural biotechnology (01-07-2014)“…In recent years there has been a surge of interest in using lipases to catalyze the synthesis of biodiesel, as the biocatalytic route has several advantages…”
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Enzymatic kinetic resolution of tert-butyl 2-(1-hydroxyethyl)phenylcarbamate, a key intermediate to chiral organoselenanes and organotelluranes
Published in Molecules (Basel, Switzerland) (20-09-2011)“…The enzymatic kinetic resolution of tert-butyl 2-(1-hydroxyethyl) phenylcarbamate via lipase-catalyzed transesterification reaction was studied. We…”
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Demethylation of N,N-Dimethylbenzenamine and N,N,3-Trimethylbenzenamine by Whole Cells of Aspergillus terreus
Published in Food technology and biotechnology (01-10-2011)“…N,N-dimethylbenzenamine and N,N,3-trimethylbenzenamine were N-demethylated through enzymatic reactions mediated by whole cells of Aspergillus terreus strains…”
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9
Smart Materials for Biocatalysis Regulation through Thermoresponsive Polymers
Published in ChemCatChem (09-11-2024)“…Abstract Temperature‐responsive biocatalytic hybrid materials offer several advantages, such as improved stability, enhanced catalytic efficiency, and…”
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Ovicidal activity of diaryl dichalcogenides and ivermectin on Fasciola hepatica: A novel candidate for a blending-based therapeutic strategy
Published in Acta tropica (01-10-2024)“…•All tested compounds presented a concentration-dependent activity on egg hatch.•LQ62 and LQ68 had superior ovicidal activity compared to LQ07 and…”
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Polyfunctionalized organoselenides: New synthetic approach from selenium-containing cyanohydrins and anti-melanoma activity
Published in Bioorganic & medicinal chemistry letters (15-09-2024)“…[Display omitted] •Selenium-containing cyanohydrin acetates were crucial intermediates in synthesizing polyfunctionalized selenides.•Se-containing diesters and…”
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12
Stereoselective Bioreduction of Telluro‐Acetophenones to Optically Active Hydroxy Tellurides
Published in European journal of organic chemistry (08-03-2020)“…Organotellurium compounds exhibit a broad range of useful applications in organic synthesis, materials science and medicinal chemistry fields. Despite their…”
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13
Fermented solids that contain lipases produced by Rhizopus microsporus have an S-enantiopreference in the resolution of secondary alcohols
Published in Biochemical engineering journal (15-01-2021)“…•The fermented solid was used in the kinetic resolution of secondary alcohols.•The lipases in the fermented solid have anti-Kazlauskas enantiopreference.•The…”
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14
Straightforward microwave-assisted synthesis of organochalcogen amines by reductive amination
Published in Journal of organometallic chemistry (01-11-2018)“…Organoselenium and organotellurium amines have been shown to present a broad range of interesting properties for both synthetic and biological applications…”
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Cover Feature: Synthesis, Mechanism Elucidation and Biological Insights of Tellurium(IV)‐Containing Heterocycles (Chem. Eur. J. 58/2021)
Published in Chemistry : a European journal (19-10-2021)“…Explaining the oxidation–cyclization mechanism of heterocycles containing Te−O bonds. The structures of halogenated Te‐containing heterocycles have been…”
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Surface interactions of gold nanorods and polysaccharides: From clusters to individual nanoparticles
Published in Carbohydrate polymers (05-11-2016)“…[Display omitted] •Sulfated chitosan efficiently interact with the surface of CTAB coated AuNRs.•Sulfated chitosan produced well-dispersed individually wrapped…”
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Synthesis, Antioxidant Activity and Cytotoxicity of N-Functionalized Organotellurides
Published in Bioorganic & medicinal chemistry (15-01-2019)“…[Display omitted] The use of antioxidants is the most effective means to protect the organism against cellular damage caused by oxidative stress. In this…”
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High-Throughput Preparation of Optically Active Cyanohydrins Mediated by Lipases
Published in European journal of organic chemistry (01-12-2016)“…Cyanohydrins are versatile compounds with high applicability in organic synthesis; they are used as starting materials for the synthesis of other chemical…”
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Optimization of biodiesel synthesis by esterification using a fermented solid produced by Rhizopus microsporus on sugarcane bagasse
Published in Bioprocess and biosystems engineering (01-04-2018)“…A fermented solid containing lipases was produced by solid-state fermentation of Rhizopus microsporus on sugarcane bagasse enriched with urea, soybean oil, and…”
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Synthesis, Mechanism Elucidation and Biological Insights of Tellurium(IV)‐Containing Heterocycles
Published in Chemistry : a European journal (19-10-2021)“…Inspired by the synthetic and biological potential of organotellurium substances, a series of five‐ and six‐membered ring organotelluranes containing a Te−O…”
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