Search Results - "Pinkowicz, Dawid"
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An intermetallic molecular nanomagnet with the lanthanide coordinated only by transition metals
Published in Nature communications (19-04-2022)“…Magnetic molecules known as molecular nanomagnets (MNMs) may be the key to ultra-high density data storage. Thus, novel strategies on how to design MNMs are…”
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1,2,5-Thiadiazole 1,1-dioxides and Their Radical Anions: Structure, Properties, Reactivity, and Potential Use in the Construction of Functional Molecular Materials
Published in Molecules (Basel, Switzerland) (11-08-2021)“…This work provides a summary of the preparation, structure, reactivity, physicochemical properties, and main uses of 1,2,5-thiadiazole 1,1-dioxides in…”
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Enforcing Multifunctionality: A Pressure-Induced Spin-Crossover Photomagnet
Published in Journal of the American Chemical Society (15-07-2015)“…Photomagnetic compounds are usually achieved by assembling preorganized individual molecules into rationally designed molecular architectures via the bottom-up…”
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Octacyanidorhenate(V) Ion as an Efficient Linker for Hysteretic Two‐Step Iron(II) Spin Crossover Switchable by Temperature, Light, and Pressure
Published in Angewandte Chemie International Edition (01-09-2020)“…A two‐step hysteretic FeII spin crossover (SCO) effect was achieved in programmed layered Cs{[Fe(3‐CNpy)2][Re(CN)8]}⋅H2O (1) (3‐CNpy=3‐cyanopyridine) assembly…”
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A Trigonal-Pyramidal Erbium(III) Single-Molecule Magnet
Published in Angewandte Chemie International Edition (11-05-2015)“…Given the recent advent of mononuclear single‐molecule magnets (SMMs), a rational approach based on lanthanides with axially elongated f‐electron charge cloud…”
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A Photomagnetic Sponge: High-Temperature Light-Induced Ferrimagnet Controlled by Water Sorption
Published in Journal of the American Chemical Society (21-11-2018)“…“Converting” light energy to magnetization is the attribute of molecule-based compounds called photomagnets and is inaccessible for conventional magnetic…”
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Octacyanidotungstate(IV) Coordination Chains Demonstrate a Light‐Induced Excited Spin State Trapping Behavior and Magnetic Exchange Photoswitching
Published in Angewandte Chemie International Edition (16-10-2017)“…A huge increase in the magnetization of two coordination chains based on tetravalent octacyanidometalates (WIV and MoIV) is observed on irradiation with 436 nm…”
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Site-Selective Photoswitching of Two Distinct Magnetic Chromophores in a Propeller-Like Molecule To Achieve Four Different Magnetic States
Published in Journal of the American Chemical Society (04-12-2019)“…Magnetic photoswitching is a highly important but relatively rare phenomenon for enabling optical writing/reading of the magnetic state of a molecule. In this…”
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Heterotrimetallic Cyanide-Bridged 3d-4d-5d Frameworks Based on a Photomagnetic Secondary Building Unit
Published in Inorganic chemistry (06-07-2020)“…The rational design of coordination frameworks combining more than two different metal ions using a self-assembly approach is challenging because it rarely…”
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The impact of ligands upon topology and functionality of octacyanidometallate-based assemblies
Published in Coordination chemistry reviews (01-09-2012)“…► Over 300 octacyanidometallate-based polymetallic assemblies are reviewed. ► Classification of ligands based on their structure and binding mode is proposed…”
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Room‐Temperature Bistability in a Ni–Fe Chain: Electron Transfer Controlled by Temperature, Pressure, Light, and Humidity
Published in Angewandte Chemie International Edition (01-02-2021)“…Bistable and stimuli‐responsive molecule‐based materials are promising candidates for the development of molecular switches and sensors for future…”
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Reversible Single-Crystal-to-Single-Crystal Transformation in Photomagnetic Cyanido-Bridged Cd4M2 Octahedral Molecules
Published in Inorganic chemistry (06-11-2017)“…Two new hexanuclear octahedral cyanido-bridged clusters, {[CdII(bpy)2]4[WIV(CN)8]2}·10H2O (Cd 4 W 2 ) and {[CdII(bpy)2]4[MoIV(CN)8]2}·10H2O (Cd 4 Mo 2 ), have…”
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Magnetic, Structural and Spectroscopic Properties of Iron(II)-Octacyanoniobate(IV) Crystalline Film Obtained by Ion-Exchange Synthesis
Published in Materials (07-07-2020)“…Over recent years, investigations of coordination polymer thin films have been initiated due to their unique properties, which are expected to be strongly…”
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Chiral Photomagnets Based on Copper(II) complexes of 1,2-Diaminocyclohexane and Octacyanidomolybdate(IV) Ions
Published in Inorganic chemistry (04-05-2020)“…Chiral photomagnets compose a class of multifunctional molecule-based materials with light-induced alteration of magnetization and chiral properties. The…”
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Photoinduced Mo−CN Bond Breakage in Octacyanomolybdate Leading to Spin Triplet Trapping
Published in Angewandte Chemie International Edition (17-02-2020)“…The photoinduced properties of the octacoordinated complex K4MoIV(CN)8⋅2 H2O were studied by theoretical calculations, crystallography, and optical and…”
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A Decade of Octacyanides in Polynuclear Molecular Materials
Published in European Journal of Inorganic Chemistry (01-01-2011)“…The aim and the scope of this review is to show the results of ten years of research following the first reports on magnetic and photomagnetic assemblies…”
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Record Antiferromagnetic Coupling for a 3d/4d Cyanide-Bridged Compound
Published in Journal of the American Chemical Society (16-07-2014)“…The pentanuclear compound [VII(tmphen)2]3[MoIII(CN)6]2 (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) exhibits a record antiferromagnetic exchange coupling…”
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Alternative Synthetic Route to Potassium Octacyanidoniobate(IV) and Its Molybdenum Congener
Published in European journal of inorganic chemistry (01-10-2016)“…Octacyanidometallates have been proven to be very useful molecular building blocks for the construction of various molecular materials with a strong emphasis…”
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The Heptacyanotungstate(IV) Anion: A New 5 d Transition-Metal Member of the Rare Heptacyanometallate Family of Anions
Published in Angewandte Chemie (International ed.) (12-09-2016)“…The heptacyanotungstate(IV) anion was isolated in the salt (n‐Bu4N)3[WIV(CN)7] (1) from the reduction of (n‐Bu4N)3[WV(CN)8] with concomitant loss of one…”
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The Underexplored Field of Lanthanide Complexes with Helicene Ligands: Towards Chiral Lanthanide Single Molecule Magnets
Published in Magnetochemistry (01-10-2021)“…The effective combination of chirality and magnetism in a single crystalline material can lead to fascinating cross-effects, such as magneto-chiral dichroism…”
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