Search Results - "Pinkas, Jiri"
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Luminescent Zirconocene Complexes with Pendant Phosphine Chalcogenide Donor Groups
Published in Organometallics (26-06-2023)“…Neutral zirconocene complexes of the type [(η5-C5Me5){η5-C5H4CMe2P(E)Ph2}ZrCl2] (E = not present, O, S, or Se) with a cyclopentadienyl-attached phosphine…”
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The Role of Template Structure and Synergism between Inorganic and Organic Structure Directing Agents in the Synthesis of UTL Zeolite
Published in Chemistry of materials (08-06-2010)“…The extra-large-pore germanosilicates with UTL topology have been synthesized using a large variety of spiroazocompounds as structure-directing agents…”
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3
Luminescent Cationic Group 4 Metallocene Complexes Stabilized by Pendant N‑Donor Groups
Published in Inorganic chemistry (17-05-2021)“…Cationic group 4 metallocene complexes with pendant imine and pyridine donor groups were prepared as stable crystalline [B(C6F5)4]− salts either by…”
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4
Synthesis and characterization of WS2/SiO2 microfibers
Published in Journal of materials science (01-06-2021)“…Tungsten disulfide polycrystalline microfibers were successfully synthesized by a process involving electrospinning, calcination, and sulfidation steps. We…”
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The Power of Non-Hydrolytic Sol-Gel Chemistry: A Review
Published in Catalysts (25-05-2017)“…This review is devoted to non-hydrolytic sol-gel chemistry. During the last 25 years, non-hydrolytic sol-gel (NHSG) techniques were found to be attractive and…”
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Multifunctional catalysts based on palladium nanoparticles supported on functionalized halloysites: Applications in catalytic C-C coupling, selective oxidation and dehalogenation reactions
Published in Applied clay science (15-11-2021)“…A series of hybrid catalysts of the type, support-ligand-Pd (Sup-L-Pd), has been prepared and characterized and their activity in C-C coupling…”
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Sunlight photolysis of cyclopentadienyl–tethered titanium(iv) permethyltitanocene chlorides
Published in Journal of organometallic chemistry (15-11-2020)“…•The sunlight photolyses of permethyltitanocene(TiIV) monochlorides are studied.•The different types of photolytical processes afforded new complexes.•The…”
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Electron interactions with Bis(pentamethylcyclopentadienyl) titanium(IV) dichloride and difluoride
Published in The European physical journal. D, Atomic, molecular, and optical physics (01-06-2018)“…We present a combined experimental and theoretical study of the interaction of electrons with Bis(pentamethylcyclopentadienyl)titanium(IV) dichloride (Cp 2 *…”
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Molecular Hydrogen‐Induced Carbon Chain Rearrangement in Cyclopentadienyl‐Tethered Titanium(III) Permethyltitanocene Complexes
Published in European journal of inorganic chemistry (09-01-2020)“…Dihydrogen added at atmospheric pressure and ambient temperature to cyclopentadienyl‐tethered titanium(III) permethyltitanocene complexes induced the…”
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10
Low-valent ansa-dimethylsilylene-, dimethylmethylene-bis(cyclopentadienyl) titanium compounds and ansa-titanium–magnesium complexes
Published in Journal of organometallic chemistry (01-07-2019)“…Reduction of ansa-titanocene dichlorides [X(η5-C5H4)2TiCl2] (X = SiMe2 (1) and CMe2 (2)) in tetrahydrofuran (THF) by preactivated magnesium in the presence of…”
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11
Synthesis, structure and ethylene polymerisation activity of {η5:η1(N)-1-[(tert-butylamido)diphenylsilyl)]-2,3,4,5-tetramethylcyclopentadienyl}dichlorotitanium(IV
Published in Polyhedron (15-09-2020)“…The new complex {η5:η1(N)–1–[(tert-Butylamido)diphenylsilyl)]–2,3,4,5–tetramethylcyclopentadienyl}dichlorotitanium(IV) has been synthesized and characterized…”
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12
New Adamantane-like Silicophosphate Cage and Its Reactivity toward Tris(pentafluorophenyl)borane
Published in Inorganic chemistry (05-09-2017)“…The condensation reaction between Ph2Si(OC(O)CH3)2 and OP(OSiMe3)3 leads to elimination of CH3C(O)OSiMe3 and the formation of the new silicophosphate…”
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13
Group 4 Metal Complexes of Chelating Cyclopentadienyl-ketimide Ligands
Published in Organometallics (14-03-2016)“…A pendant nitrile group attached to the lithium cyclopentadienide moiety in (C5H4CMe2CMe2CN)Li was alkylated using organyl lithium reagents (RLi, R = Ph, t-Bu,…”
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14
Chromocene–Cyclopentadienyltitanium Trichloride Ion Pairs and Their Rearrangement to Titanocene Chloride–Cyclopentadienylchromium Dichlorides – Ethylene Polymerization Tests
Published in European journal of inorganic chemistry (22-06-2018)“…Reactions of chromocene [CrCp2] (Cp = η5‐C5H5) with cyclopentadienyltitanium trichlorides [Ti(η5‐C5H5–nMen)Cl3] (n = 0–5) and [Ti(C5Me4Et)TiCl3] in toluene…”
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15
B(C6F5)3 catalysis accelerates the hydrosilane chlorination by Ph3CCl
Published in Applied organometallic chemistry (01-08-2018)“…A chlorination of tertiary (5 examples), secondary (3 examples) and primary (PhSiH3) hydrosilanes by Ph3CCl with a catalytic amount of B(C6F5)3 is presented…”
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16
Synthesis of homogeneous silicophosphate xerogels by non-hydrolytic condensation reactions
Published in Microporous and mesoporous materials (01-10-2014)“…[Display omitted] •Silicophosphate xerogels prepared by a non-hydrolytic ester elimination.•Possess a high degree of Si−O−P condensation.•Feature a large…”
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17
Harmless glucose‐modified ruthenium complexes suppressing cell migration of highly invasive cancer cell lines
Published in Applied organometallic chemistry (01-01-2020)“…Glucose‐substituted ruthenium complexes [(η6‐benzyl‐glucose)RuCp*]+Cl−, where Cp* = η5‐C5Me5; benzyl‐glucose = peracetylated benzyl β‐d‐glucopyranoside (1),…”
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18
Electrochemical Study of Highly Substituted Titanocene Dihalides
Published in Electroanalysis (New York, N.Y.) (01-10-2019)“…Titanocene dihalides are promising alternative to Cisplatin in cancer chemotherapy which should reduce negative side effects and overcome increasing resistance…”
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Insertion of 1-t-butylpropyne into singly tucked-in permethyltitanocene. Synthesis, crystal structure of product and transition-state geometry
Published in Journal of molecular structure (05-09-2018)“…The singly tucked-in titanocene [(η5-C5Me5)TiIII{η5:η1-C5Me4(CH2)}] (1) reacted with one equivalent of 1-tert-butylpropyne to yield the propenyl-tethered…”
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20
Ethene Complexes of Bulky Titanocenes, Their Thermolysis, and Their Reactivity toward 2-Butyne
Published in Organometallics (13-08-2012)“…Ethene complexes of titanocenes [Ti(II)(η2-C2H4)(Cp′)2] for Cp′ = η5-C5Me5 (1), η5-C5Me4 t-Bu (2), η5-C5Me4SiMe3 (3), and η5-C5HMe4 (4) were prepared by…”
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