Search Results - "Piniella, Juan F."
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Preparation of (1 R,1′ R)-1,1′-(anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine): a chiral diamine with low basicity
Published in Tetrahedron (03-01-2009)“…A new chiral diamine with low basicity was synthesized in enantiopure form. (1 R,1′ R)-1,1′-(Anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine) was obtained…”
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C2-Symmetric enantiopure ethanotethered bis(α, β-butenolides) as templates for asymmetric synthesis. Application to the synthesis of (+)-grandisol
Published in Journal of organic chemistry (21-03-2003)“…Starting from D-mannitol, we have prepared several C(2)-symmetric ethanotethered bis(alpha,beta-butenolides) and studied their [2+2] photocycloaddition…”
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Synthesis and 1,3-dipolar cycloadditions of a new enantiopure cyclic nitrone
Published in Tetrahedron letters (13-01-2003)“…A new enantiopure cyclic nitrone has been efficiently synthesized from a d-glyceraldehyde derivative. Its 1,3-dipolar cycloaddition to different classes of…”
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Photochemical [2 + 2] Cycloaddition of Acetylene to Chiral 2(5H)-Furanones
Published in Journal of organic chemistry (21-02-2003)“…The [2 + 2] photocycloaddition of acetylene to chiral 2(5H)-furanones was investigated. The influence on the chemical yield and facial diastereoselectivity of…”
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Regio- and Stereoselective Hydroformylation of Glucal Derivatives with Rhodium Catalysts
Published in Organometallics (22-06-1998)“…The hydroformylation of the differently protected glucal derivatives 3,4,6-tri-O-acetyl-d-glucal, 3,4,6-tri-O-benzyl-d-glucal and 3,4,6-tri-O-methyl-d-glucal…”
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Asymmetric Induction in the Cycloaddition of a Masked p-Benzoquinone to Cyclic Nitrones
Published in Journal of organic chemistry (31-10-1997)“…1,3-Dipolar cycloadditions of cyclic nitrones to achiral and chiral p-benzoquinone monoketals have shown poor chemo- and stereoselectivity. To overcome these…”
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Diastereofacial Selectivity in the Cycloaddition of Nitrones to (E)-γ-Oxygenated α,β-Unsaturated Esters
Published in Journal of organic chemistry (29-11-1996)“…The 1,3-dipolar cycloadditions of nitrones 1 and 2 to a series of 1,2-disubstituted electron-deficient olefins bearing an allylic stereocenter, 4−8, are…”
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First Preparation of Optically Pure Ketals of p-Benzoquinone
Published in Journal of organic chemistry (01-06-1995)Get full text
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Diastereofacial Selectivity in the Cycloaddition of Nitrones to (E)-γ-Oxygenated α,β-Unsaturated Esters
Published in Journal of organic chemistry (20-03-1998)Get full text
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Dimethylthallium(III) complexes with sulfur-nitrogen and sulfur-oxygen ligands: the molecular structure of Me2TlL (L = 1-oxidopyridinium-2-thiolato)
Published in Organometallics (01-09-1988)Get full text
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Photocycloaddition of ( Z)-1,2-dichloroethylene to enantiopure 2(5 H)-furanones: an efficient strategy for the diastereoselective synthesis of cyclobutane and cyclobutene derivatives
Published in Tetrahedron letters (2003)“…A highly stereoselective and efficient synthetic approach to cyclobutane and cyclobutene derivatives has been developed consisting of a [2+2] photochemical…”
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Solid state and theoretical conformational analysis of enantiopure C2 symmetric bis(α,β-butenolides)
Published in Journal of molecular structure (12-03-2003)“…The solid state structure and theoretical conformational analysis of two enantiomerically pure bis(α,β-butenolides) with C 2 symmetry have been performed. The…”
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First synthesis of (+)-rengyolone and (+)- and (−)-menisdaurilide
Published in Tetrahedron: asymmetry (05-04-2002)“…The benzofuranone natural products (+)-rengyolone and (+)- and (−)-menisdaurilide have been synthesised for the first time from a common enantiopure…”
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Protected derivatives of ( R)-cysteine and ( R)-cysteinol
Published in Tetrahedron (06-03-1995)“…The synthesis of N, O, S protected forms of ( R)-cysteine and ( R)-cysteinol as bicyclic derivatives is described. The reactivity and the preparation of…”
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First example of a third generation nitrone cycloaddition
Published in Tetrahedron (24-02-1997)“…Compounds 5 and 6, derived from the cycloadditions of a nitrone to α,β-unsaturated lactones, were oxidized with m-chloroperbenzoic acid affording…”
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Boron complexes of L-cysteine
Published in Tetrahedron (22-10-1998)“…The synthesis of diphenyl[(R)- thiazolidine-4-carboxylato-O,N ] boron 4 , 9- borabicyclo[3.3.1]non-9-yl[(R)- thiazolidine-4-carboxylato-O,N ] boron 9 , 9-…”
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A New Reaction of Tetrabutylammonium Camphorsulfonate with P 4S 10. Synthesis and Crystal Structure of the First Chiral Tetrathiophosphate Derivative
Published in Tetrahedron letters (1997)“…Compound 5 has been synthesized in a good yield by reacting tetrabutylammonium camphorsulfonate with P 4S 10, and characterized by X ray diffraction. © 1997…”
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