Search Results - "Pillet, Sébastien"
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Elastic Frustration Triggering Photoinduced Hidden Hysteresis and Multistability in a Two-Dimensional Photoswitchable Hofmann-Like Spin-Crossover Metal–Organic Framework
Published in Inorganic chemistry (21-11-2016)“…We report a two-dimensional Hofmann-like spin-crossover (SCO) material, [Fe(trz-py)2{Pt(CN)4}]·3H2O, built from [FePt(CN)4] layers separated by…”
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Probing the Spin Dimensionality in Single‐Layer CrSBr Van Der Waals Heterostructures by Magneto‐Transport Measurements
Published in Advanced materials (Weinheim) (01-10-2022)“…2D magnetic materials offer unprecedented opportunities for fundamental and applied research in spintronics and magnonics. Beyond the pioneering studies on 2D…”
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Giant Ising-Type Magnetic Anisotropy in Trigonal Bipyramidal Ni(II) Complexes: Experiment and Theory
Published in Journal of the American Chemical Society (27-02-2013)“…This paper reports the experimental and theoretical investigations of two trigonal bipyramidal Ni(II) complexes, [Ni(Me6tren)Cl](ClO4) (1) and…”
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Very Long-Lived Photogenerated High-Spin Phase of a Multistable Spin-Crossover Molecular Material
Published in Journal of the American Chemical Society (10-10-2018)“…The spin-crossover compound [Fe(n-Bu-im)3(tren)](PF6)2 shows an unusual long relaxation time of 20 h after light-induced excited spin state trapping when…”
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Conducting Anilate-Based Mixed-Valence Fe(II)Fe(III) Coordination Polymer: Small-Polaron Hopping Model for Oxalate-Type Fe(II)Fe(III) 2D Networks
Published in Journal of the American Chemical Society (03-10-2018)“…The mixed-valence FeIIFeIII 2D coordination polymer formulated as [TAG][FeIIFeIII(ClCNAn)3]·(solvate) 1 (TAG = tris(amino)-guanidinium, ClCNAn2– =…”
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Weak Coordinating Character of Organosulfonates in Oriented Silica Films: An Efficient Approach for Immobilizing Cationic Metal-Transition Complexes
Published in Molecules (Basel, Switzerland) (01-09-2022)“…Iron (II) tris(2,2′-bipyridine) complexes, [Fe(bpy)3]2+, have been synthesized and immobilized in organosulfonate-functionalized nanostructured silica thin…”
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Photoinduced Mo−CN Bond Breakage in Octacyanomolybdate Leading to Spin Triplet Trapping
Published in Angewandte Chemie International Edition (17-02-2020)“…The photoinduced properties of the octacoordinated complex K4MoIV(CN)8⋅2 H2O were studied by theoretical calculations, crystallography, and optical and…”
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Hidden Hysteretic Behavior of a Paramagnetic Iron(II) Network Revealed by Light Irradiation
Published in European journal of inorganic chemistry (31-01-2018)“…The paramagnetic coordination polymer [Fe(3phOH‐trz){Pt(CN)4}]·2H2O [3phOH‐trz = 4‐(3‐hydroxyphenyl)‐1,2,4‐triazole] was obtained through the reaction of an…”
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Unprecedented Reverse Volume Expansion in Spin‐Transition Crystals
Published in Chemistry : a European journal (09-10-2020)“…The current craze for research around the spin crossover phenomenon can be justified to some extent by the mechanical properties due to the decrease of volume…”
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Direct Evidence of a Photoinduced Electron Transfer in Diluted “Molybdenum‐Copper” Molecular Compounds
Published in European journal of inorganic chemistry (31-01-2018)“…For the first time, direct evidence of a photoinduced intramolecular electron transfer has been found in the “molybdenum‐copper“ family of cyanide complexes…”
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Magnetostructural Relationship in the Spin-Crossover Complex t-{Fe(abpt)2[N(CN)2]2}: Polymorphism and Disorder Phenomenon
Published in Inorganic chemistry (01-12-2008)“…t-{Fe(abpt)2[N(CN)2]2} [abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole] is an intriguing spin-crossover system that crystallizes in two polymorphs…”
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Unidirectional Photoisomerization of Styrylpyridine for Switching the Magnetic Behavior of an Iron(II) Complex: A MLCT Pathway in Crystalline Solids
Published in Journal of physical chemistry. C (16-12-2010)“…The photoreactivity of two iron(II)−styrylpyridine frameworks Fe(stpy)4(NCSe)2 (stpy = 4-styrylpyridine) has been investigated for the very first time in a…”
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Photocrystallographic and spectroscopic studies of a model (N,N,O)-donor square-planar nickel(II) nitro complex: in search of high-conversion and stable photoswitchable materials
Published in IUCrJ (01-11-2020)“…A new, cheap, easy-to-synthesize and air-stable photoswitchable nickel(II) complex, QTNiNO , is reported. The metal centre in QTNiNO is coordinated by a nitro…”
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Spin Cross-Over (SCO) Anionic Fe(II) Complexes Based on the Tripodal Ligand Tris(2-pyridyl)ethoxymethane
Published in Magnetochemistry (01-06-2020)“…Reactions of Fe(II) with the tripodal chelating ligand 1,1,1-tris(2-pyridyl)ethoxymethane (py3C-OEt) and (NCE)− co-ligands (E = S, Se, BH3) give a series of…”
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Magnetic Bistability in Macrocycle-Based FeII Spin-Crossover Complexes: Counter Ion and Solvent Effects
Published in European journal of inorganic chemistry (01-12-2016)“…Two new iron(II) complexes of formula [Fe(L2)](tcm)2·2H2O (1) and [Fe(L2)][Ni(CN)4]·H2O (2) {L2 = 1,8‐bis(2′‐pyridylmethyl)‐1,4,8,11‐tetraazacyclotetradecane;…”
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Cyanocarbanion-Based Spin-Crossover Materials: Photocrystallographic and Photomagnetic Studies of a New Iron(II) Neutral Chain
Published in Inorganic chemistry (18-10-2010)“…A new iron(II) chain of formula [Fe(abpt)2(tcpd)] [1; (tcpd)2− = [C10N6]2− = (C[C(CN)2]3)2− = 2-dicyanomethylene-1,1,3,3-tetracyanopropanediide anion, abpt =…”
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Magnetic Bistability and Thermochromism in a Molecular CuII Chain
Published in Inorganic chemistry (16-02-2009)“…An original magnetic bistability and a thermochromic transition are observed in a new CuII molecular chain. Thermal structural studies reveal changes in the…”
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When combined X‐ray and polarized neutron diffraction data challenge high‐level calculations: spin‐resolved electron density of an organic radical
Published in Acta crystallographica Section B, Structural science, crystal engineering and materials (01-08-2017)“…Joint refinement of X‐ray and polarized neutron diffraction data has been carried out in order to determine charge and spin density distributions…”
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Experimental determination of spin-dependent electron density by joint refinement of X-ray and polarized neutron diffraction data
Published in Acta crystallographica. Section A, Foundations of crystallography (01-11-2012)“…New crystallographic tools were developed to access a more precise description of the spin‐dependent electron density of magnetic crystals. The method combines…”
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On the precision and accuracy of structural analysis of light-induced metastable states
Published in Journal of applied crystallography (01-12-2007)“…Bragg diffraction data were collected on single crystals of the spin‐crossover complex [Fe(phen)2(NCS)2] in its low‐spin and light‐induced metastable high‐spin…”
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