Search Results - "Pihl, Josh A"
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Catalytic Exhaust Gas Recirculation-Loop Reforming for High Efficiency in a Stoichiometric Spark-Ignited Engine through Thermochemical Recuperation and Dilution Limit Extension, Part 1: Catalyst Performance
Published in Energy & fuels (15-02-2018)“…The use of fuel reformate from catalytic processes is known to have beneficial effects on the spark-ignited combustion process through enhanced dilution…”
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2
Catalytic Steam and Partial Oxidation Reforming of Liquid Fuels for Application in Improving the Efficiency of Internal Combustion Engines
Published in Energy & fuels (15-02-2018)“…This study investigated the potential for catalytically reforming liquid fuels in a simulated exhaust gas recirculation (EGR) mixture loop for the purpose of…”
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Passive-ammonia selective catalytic reduction (SCR): Understanding NH3 formation over close-coupled three way catalysts (TWC)
Published in Catalysis today (01-08-2014)“…•Evaluated 4 TWC formulations for the production of NH3 for passive SCR.•All produced NH3 over range of rich conditions; Pd-only had highest NH3…”
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4
NOx storage and reduction in model lean NOx trap catalysts studied by in situ DRIFTS
Published in Applied catalysis. B, Environmental (07-09-2009)“…NOx storage and reduction on a model Pt/BaO/Al2O3 catalyst was studied by means of in situ DRIFTS measurements. To examine the effect of ceria addition,…”
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NH3 formation over a lean NOX trap (LNT) system: Effects of lean/rich cycle timing and temperature
Published in Applied catalysis. B, Environmental (05-04-2014)“…•Below 300°C NOX release and reduction are slow and kinetically limiting.•Above 450°C NOX storage becomes the limiting factor.•Selectivities to NH3 and N2O are…”
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Study of the Theoretical Potential of Thermochemical Exhaust Heat Recuperation for Internal Combustion Engines
Published in Energy & fuels (18-03-2010)“…A detailed thermodynamic analysis of thermochemical recuperation (TCR) applied to an idealized internal combustion engine with single-stage work extraction is…”
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Spatiotemporal distribution of NOx storage and impact on NH3 and N2O selectivities during lean/rich cycling of a Ba-based lean NOx trap catalyst
Published in Catalysis today (30-04-2012)“…[Display omitted] ► Distribution of stored NOx evolves continously over space and time. ► Coupled with local chemistry, the distribution of stored NOx impacts…”
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Sulfur and temperature effects on the spatial distribution of reactions inside a lean NOx trap and resulting changes in global performance
Published in Catalysis today (15-07-2008)“…We experimentally studied the influence of temperature and sulfur loading on the axial distribution of reactions inside a commercial lean NOx trap (LNT)…”
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Conference Proceeding Journal Article -
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Investigation of NO adsorption and desorption phenomena on a Pd/ZSM-5 passive NOx adsorber
Published in Applied catalysis. B, Environmental (05-12-2021)“…[Display omitted] •Pd2+ ions exchanged into ZSM-5 exist in a hydrated state at low temperatures.•Hydration of the Pd2+ ions inhibits the rate of NO uptake.•CO…”
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Journal Article -
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Intra-catalyst CH4 oxidation pathways on a Pd/Al2O3/CeZrOx-based commercial catalyst and implications on NOx conversion profiles for a natural gas vehicle exhaust under lambda modulation
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-09-2023)“…[Display omitted] •Intra-catalyst species measurement was performed on NG-TWC under λ-modulation.•Impact of λ-modulation parameters on reaction pathways was…”
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In-situ DRIFTS measurements for the mechanistic study of NO oxidation over a commercial Cu-CHA catalyst
Published in Applied catalysis. B, Environmental (01-05-2015)“…•NO oxidation mechanism on Cu-CHA is investigated by in situ DRIFT spectroscopy.•NOx feed to pre-oxidized/pre-reduced samples reveals redox nature of the…”
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12
Condition-Dependent Pd Speciation and NO Adsorption in Pd/Zeolites
Published in ACS catalysis (06-11-2020)“…Metal ions exchanged on zeolites represent a unique bridge between heterogeneous solid materials and homogeneous inorganic chemistry. The complexing of…”
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Journal Article -
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Pre-oxidized and nitrided stainless steel alloy foil for proton exchange membrane fuel cell bipolar plates. Part 2: Single-cell fuel cell evaluation of stamped plates
Published in Journal of power sources (01-09-2010)“…Thermal (gas) nitridation of stainless steel alloys can yield low interfacial contact resistance (ICR), electrically conductive and corrosion-resistant nitride…”
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Journal Article -
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Impact of Selected High-Performance Fuel Blends on Three-Way Catalyst Light Off under Synthetic Spark-Ignition Engine-Exhaust Conditions
Published in Energy & fuels (15-10-2020)“…The U.S. Department of Energy funded Co-Optimization of Fuels and Engines initiative aims to simultaneously develop advanced engines along with…”
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Journal Article -
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Reactivity of novel high-performance fuels on commercial three-way catalysts for control of emissions from spark-ignition engines
Published in Applied energy (01-12-2019)“…[Display omitted] •Three-way catalyst light-off temperatures vary significantly with fuel composition.•Most oxygenated fuels light off at lower temperatures…”
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Catalytic Exhaust Gas Recirculation-Loop Reforming for High Efficiency in a Stoichiometric Spark-Ignited Engine through Thermochemical Recuperation and Dilution Limit Extension, Part 2: Engine Performance
Published in Energy & fuels (15-02-2018)“…This is the second part of a two-part investigation of on-board catalytic fuel reforming to increase the brake efficiency of a multicylinder, stoichiometric…”
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Integration of an Oxidation Catalyst with Pd/Zeolite-Based Passive NOx Adsorbers: Impacts on Degradation Resistance and Desorption Characteristics
Published in Industrial & engineering chemistry research (12-05-2021)“…Fully ion-exchanged Pd/SSZ-13 model passive NOx adsorbers (PNA) exhibit significant NOx storage capability, achieving NOx-to-Pd ratios of 1, and NOx desorption…”
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Lean NOx reduction over Ag/alumina catalysts via ethanol-SCR using ethanol/gasoline blends
Published in Applied catalysis. B, Environmental (01-03-2017)“…[Display omitted] •High NOx conversion for EtOH and EtOH/gasoline blends as reductant.•High NH3 formation over pure Ag samples related to formation of…”
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Journal Article -
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Passive SCR for lean gasoline NOX control: Engine-based strategies to minimize fuel penalty associated with catalytic NH3 generation
Published in Catalysis today (01-06-2016)“…[Display omitted] •Air-fuel equivalence ratio impacts both NH3 selectivity and fuel penalty.•Fuel penalty reduced with increased engine-out NOX via spark…”
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Production, fuel properties and combustion testing of an iso-olefins blendstock for modern vehicles
Published in Fuel (Guildford) (15-02-2022)“…•A dimethyl-hexenes rich olefins mixture (DMHROM) for gasoline engines.•A pathway for DMHROM production from ethanol was developed and scaled up.•DMHROM…”
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