The emission spectroscopy of some elements in high-temperature flames

The emission of atoms of a large number of elements in laminar high-temperature acetylene-N 2 O, H 2 -N 2 O, H 2 -O 2 , acetylene-air, and H 2 -air flames was studied; of these the most suitable are flame mixtures containing N 2 O. Methods were developed for determining Ca, Sr, Ba, for Cu, Cr, Mn an...

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Bibliographic Details
Published in:Collection of Czechoslovak chemical communications Vol. 44; no. 1; pp. 69 - 79
Main Authors: Pištěková, Marie, Jambor, Jaroslav, Otruba, Vítězslav, Sommer, Lumír
Format: Journal Article
Language:English
Published: 1979
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Summary:The emission of atoms of a large number of elements in laminar high-temperature acetylene-N 2 O, H 2 -N 2 O, H 2 -O 2 , acetylene-air, and H 2 -air flames was studied; of these the most suitable are flame mixtures containing N 2 O. Methods were developed for determining Ca, Sr, Ba, for Cu, Cr, Mn and Ni in steels and for Cu, Fe, Mn and Ni in aluminium alloys using an acetylene-N 2 O flame. A small chemical interference for the matrix elements was found provided that a monochromator with good resolution and with a small amount of scattered light was employed. These conditions are fulfilled by most modern atomic absorption instruments with which comparable results are obtained.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
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ISSN:0010-0765
1212-6950
DOI:10.1135/cccc19790069