Search Results - "Petr Koci"
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CO and hydrocarbon light-off inhibition by pre-adsorbed NOx on Pt/CeO2/Al2O3 and Pd/CeO2/Al2O3 diesel oxidation catalysts
Published in Chemical engineering science (14-12-2019)“…[Display omitted] •Inhibition by pre-adsorbed NOx affects CO and hydrocarbon light-off on diesel oxidation catalyst.•Due to the inhibition, the CO and C3H6…”
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Effective Model of NOx Adsorption and Desorption on PtPd/CeO2-ZrO2 Passive NOx Adsorber
Published in Catalysis letters (01-11-2020)“…An effective model for describing NO x adsorption and desorption on a PtPd/CeO 2 -ZrO 2 passive NO x adsorber is presented. The kinetic parameters are…”
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Hybrid fictitious domain-immersed boundary solver coupled with discrete element method for simulations of flows laden with arbitrarily-shaped particles
Published in Computers & fluids (15-08-2022)“…Particle-laden flows are commonly encountered in numerous engineering applications, e.g. fluidization, crystallization, granulation, drying, catalytic…”
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Effective modeling of coupled reaction and transport inside the catalytic filter wall
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (01-04-2023)“…A new extension of 1D mathematical model describing diffusion limitation in a catalytic filter wall is proposed. Transport limitations in the flowing gas…”
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Impact of diffusion limitations inside the wall of catalytic filters on conversion of gaseous pollutants at increased flow rates
Published in Chemical engineering science (12-10-2022)“…•Diffusion-limited conversion of gas in catalytic filters studied experimentally.•Several filters coated with Pt/Al2O3, using different catalyst distributions…”
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Balanced Fast-SpaciMS capillary configurations provide practically noninvasive channel-average measurements in catalytic monoliths
Published in Chemical engineering science (05-12-2023)“…Spatially resolved capillary-inlet mass spectrometry (SpaciMS) provides a detailed picture of the spatiotemporal evolution of reaction network in catalytic…”
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Global kinetic model of NO oxidation on Pd/γ-Al2O3 catalyst including PdOx formation and reduction by CO and C3H6
Published in Applied catalysis. B, Environmental (01-01-2020)“…[Display omitted] •PdOx formation affects NO oxidation rate on Pd/Al2O3 diesel oxidation catalyst (DOC).•NO2 yield gradually decreases with the growing PdOx…”
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Multiscale Modeling and Analysis of Pressure Drop Contributions in Catalytic Filters
Published in Industrial & engineering chemistry research (12-05-2021)“…Catalytic monolith filters with a honeycomb structure represent a key component of modern automotive exhaust gas aftertreatment systems. In this paper, we…”
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Impact of PtOx formation in diesel oxidation catalyst on NO2 yield during driving cycles
Published in Chemical engineering science (02-02-2017)“…Operation of a platinum-based diesel oxidation catalyst under lean conditions leads to the partial transformation of metallic Pt sites into platinum oxides…”
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Simulation of diesel exhaust aftertreatment system DOC—pipe—SCR: The effects of Pt loading, PtOx formation and pipe configuration on the deNOx performance
Published in Chemical engineering science (02-11-2018)“…•DOC-pipe-SCR diesel exhaust aftertreatment system was simulated.•SCR model was calibrated and validated using engine test data.•Parametric simulation study of…”
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Pore-scale filtration model for coated catalytic filters in automotive exhaust gas aftertreatment
Published in Chemical engineering science (23-11-2020)“…•Catalytic filters with in-wall, on-wall and combined washcoat distribution are compared.•Pore-scale filtration model is developed for 3D microstructures…”
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The impact of CO and C3H6 pulses on PtOx reduction and NO oxidation in a diesel oxidation catalyst
Published in Applied catalysis. B, Environmental (01-02-2016)“…[Display omitted] •Pt/Al2O3 catalyst deactivation due to PtOx and reactivation during NO oxidation.•Isothermal and temperature ramp experiments with inverse…”
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Washcoating of catalytic particulate filters studied by time-resolved X–ray tomography
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (01-04-2021)“…•New application of time-resolved XRT imaging to washcoating of catalytic filters.•Catalyst layer shrinking and cracking during drying depends on particle size…”
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Particle accumulation model in 3D reconstructed wall of a catalytic filter validated with time-resolved X-ray tomography
Published in Fuel (Guildford) (15-01-2024)“…A transient pore-scale model of particle deposit formation in 3D microstructure of a catalytic filter wall is introduced. It predicts location of particle…”
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3D reconstruction and pore-scale modeling of coated catalytic filters for automotive exhaust gas aftertreatment
Published in Catalysis today (15-01-2019)“…[Display omitted] •3D distribution of catalytic coating in porous filter wall imaged by XRT.•Three samples with different coating profile: on wall, in wall,…”
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Viscosity prediction for dense suspensions of non-spherical particles based on CFD-DEM simulations
Published in Powder technology (01-08-2024)“…Reliable estimation of the viscosity and rheology of dense suspensions formed from non-spherical particles is of high importance for studies of many natural…”
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Comparison of O2 and NO2 impact on PtOx and PdOx formation in diesel oxidation catalysts and their reduction by CO and C3H6 pulses
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (01-12-2019)“…•PtOx and PdOx formation deteriorates NO oxidation activity of Pt/Al2O3 and Pd/Al2O3 catalysts.•Impact of O2 and NO2 on PtOx and PdOx formation compared in…”
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Modeling of two-step CO oxidation light-off on Pt/γ-Al2O3 in the presence of C3H6 and NOx
Published in Applied catalysis. B, Environmental (05-10-2018)“…[Display omitted] •Dual CO light-off effect on Pt/Al2O3 catalyst in presence of propylene was studied.•CO conversion may decrease with temperature in a certain…”
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New operation strategy for driving the selectivity of NOx reduction to N2, NH3 or N2O during lean/rich cycling of a lean NOx trap catalyst
Published in Applied catalysis. B, Environmental (01-03-2016)“…[Display omitted] •Developed novel operating strategy for LNT catalyst regeneration.•Slightly lean transition phase inserted between rich and fully…”
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