Search Results - "Petoud, Stéphane"
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Near-infrared emitting probes for biological imaging: Organic fluorophores, quantum dots, fluorescent proteins, lanthanide(III) complexes and nanomaterials
Published in Journal of luminescence (01-09-2017)“…Fluorescence optical imaging is a highly sensitive and powerful tool with diverse in vitro and in vivo applications for preclinical and clinical studies. This…”
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On-Demand Degradation of Metal–Organic Framework Based on Photocleavable Dianthracene-Based Ligand
Published in Journal of the American Chemical Society (29-08-2018)“…We have designed a rigid photocleavable dianthracene-based ligand that reacts with ytterbium as coordination metal ion for the creation of a class of…”
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Zinc-Adeninate Metal−Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations
Published in Journal of the American Chemical Society (09-02-2011)“…Luminescent metal−organic frameworks (MOFs), Ln 3+ @bio-MOF-1, were synthesized via postsynthetic cation exchange of bio-MOF-1 with Tb3+, Sm3+, Eu3+, or Yb3+,…”
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Near-Infrared Optical Imaging of Necrotic Cells by Photostable Lanthanide-Based Metallacrowns
Published in Journal of the American Chemical Society (28-06-2017)“…Sensitive detection of cell necrosis is crucial for the determination of cell viability. Because of its high resolution at the cellular level and sensitivity,…”
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Ship-in-a-Bottle Preparation of Long Wavelength Molecular Antennae in Lanthanide Metal–Organic Frameworks for Biological Imaging
Published in Journal of the American Chemical Society (13-05-2020)“…While metal–organic frameworks (MOFs) have been identified as promising materials for sensitizing near-infrared emitting lanthanide ions (Ln3+) for biological…”
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Highly Emitting Near-Infrared Lanthanide “Encapsulated Sandwich” Metallacrown Complexes with Excitation Shifted Toward Lower Energy
Published in Journal of the American Chemical Society (29-01-2014)“…Near-infrared (NIR) luminescent lanthanide complexes hold great promise for practical applications, as their optical properties have several complementary…”
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Near-Infrared Luminescent Lanthanide MOF Barcodes
Published in Journal of the American Chemical Society (23-12-2009)“…We demonstrate the conceptual advantage of using metal−organic frameworks (MOFs) for the creation of a polymetallic material that contains several different…”
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Turn-On Luminescence Sensing and Real-Time Detection of Traces of Water in Organic Solvents by a Flexible Metal-Organic Framework
Published in Angewandte Chemie International Edition (26-01-2015)“…The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries…”
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Dy3+ White Light Emission Can Be Finely Controlled by Tuning the First Coordination Sphere of Ga3+/Dy3+ Metallacrown Complexes
Published in Journal of the American Chemical Society (23-09-2020)“…Single lanthanide(III) ion white light emission is in high demand since it provides the advantage of requiring only one chromophore for the control of the…”
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Lanthanide near infrared imaging in living cells with Yb³⁺ nano metal organic frameworks
Published in Proceedings of the National Academy of Sciences - PNAS (22-10-2013)“…We have created unique near-infrared (NIR)–emitting nanoscale metal-organic frameworks (nano-MOFs) incorporating a high density of Yb ³⁺ lanthanide cations and…”
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Functionalized Triptycene-Derived Tripodal Ligands: Privileged Formation of Tetranuclear Cage Assemblies with Larger Ln(III)
Published in Inorganic chemistry (06-03-2017)“…In this Article, we report the self-assembly of lanthanide complexes formed with two new tripodal ligands, L2 and L3, where binding strands are connected to a…”
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Visible, Near-Infrared, and Dual-Range Luminescence Spanning the 4f Series Sensitized by a Gallium(III)/Lanthanide(III) Metallacrown Structure
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (17-12-2020)“…Lanthanide(III) ions (Ln3+) in coordination compounds exhibit unique luminescence properties with narrow and characteristic f-f transitions throughout the…”
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Architectural Chirality in a Metal–Organic Framework Superstructure
Published in Crystal growth & design (02-11-2022)“…While complexity is observed everywhere in living organisms, it remains an outstanding challenge to establish controlled synthetic approaches allowing one to…”
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Taming Lanthanide-Centered Upconversion at the Molecular Level
Published in Inorganic chemistry (17-10-2016)“…Considered at the beginning of the 21th century as being incompatible with the presence of closely bound high-energy oscillators, lanthanide-centered…”
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Optimizing Millisecond Time Scale Near-Infrared Emission in Polynuclear Chrome(III)–Lanthanide(III) Complexes
Published in Journal of the American Chemical Society (01-08-2012)“…This work illustrates a simple approach for optimizing long-lived near-infrared lanthanide-centered luminescence using trivalent chromium chromophores as…”
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A Dual-Mode Near-Infrared Optical and Photoacoustic Imaging Agent Based on a Low Energy Absorbing Ytterbium Complex
Published in Journal of the American Chemical Society (15-05-2024)“…Near-infrared (NIR) luminescence and photoacoustic (PA) imaging have attracted increasing attention for the real-time monitoring of biological samples due to…”
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Tunable Optical Molecular Thermometers Based on Metallacrowns
Published in Journal of the American Chemical Society (12-10-2022)“…The effect of ligands’ energy levels on thermal dependence of lanthanide emission was examined to create new molecular nanothermometers. A series of Ln2Ga8L8…”
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Polynuclear Sm III Polyamidoamine‐Based Dendrimer: A Single Probe for Combined Visible and Near‐Infrared Live‐Cell Imaging
Published in Angewandte Chemie International Edition (10-03-2014)“…Abstract We report herein the synthesis of a luminescent polynuclear dendritic structure (Sm III ‐G3P‐2,3Nap) in which eight Sm III ions are sensitized by…”
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Tuning white light emission using single-component tetrachroic Dy3+ metallacrowns: the role of chromophoric building blocks
Published in Chemical science (Cambridge) (29-05-2024)“…White light production is of major importance for ambient lighting and technological displays. White light can be obtained by several types of materials and…”
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Near-Infrared Lanthanide-Based Emission from Fused Bis[Ln(III)/Zn(II) 14-metallacrown-5] Coordination Compounds
Published in Inorganic chemistry (18-04-2022)“…A set of (Ln[14-MCZn(II)N(quinHA)-5])2Ln2Zn2(quinHA)2(ph)2(Hph)4(OH)8(H2O)4 metallacrowns (Ln-1, Ln = Tb, Gd, or Yb; H2quinHA = quinaldic hydroxamic acid,…”
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