Search Results - "Peterson, Vanessa K"
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Phase Evolution and Intermittent Disorder in Electrochemically Lithiated Graphite Determined Using in Operando Neutron Diffraction
Published in Chemistry of materials (24-03-2020)“…Since their commercialization in 1991, lithium-ion batteries (LIBs) have revolutionized our way of life, with LIB pioneers being awarded the 2019 Nobel Prize…”
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A niobium and tantalum co-doped perovskite cathode for solid oxide fuel cells operating below 500 °C
Published in Nature communications (03-01-2017)“…The slow activity of cathode materials is one of the most significant barriers to realizing the operation of solid oxide fuel cells below 500 °C. Here we…”
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Insight of a Phase Compatible Surface Coating for Long‐Durable Li‐Rich Layered Oxide Cathode
Published in Advanced energy materials (01-09-2019)“…Li‐rich layered oxides (LLOs) can deliver almost double the capacity of conventional electrode materials such as LiCoO2 and LiMn2O4; however, voltage fade and…”
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Chromium Ion Pair Luminescence: A Strategy in Broadband Near-Infrared Light-Emitting Diode Design
Published in Journal of the American Chemical Society (17-11-2021)“…Portable near-infrared (NIR) light sources are in high demand for applications in spectroscopy, night vision, bioimaging, and many others. Typical phosphor…”
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Crystallographic‐Site‐Specific Structural Engineering Enables Extraordinary Electrochemical Performance of High‐Voltage LiNi0.5Mn1.5O4 Spinel Cathodes for Lithium‐Ion Batteries
Published in Advanced materials (Weinheim) (01-11-2021)“…The development of reliable and safe high‐energy‐density lithium‐ion batteries is hindered by the structural instability of cathode materials during cycling,…”
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In Situ Neutron Diffraction Monitoring of Li7La3Zr2O12 Formation: Toward a Rational Synthesis of Garnet Solid Electrolytes
Published in Chemistry of materials (28-04-2015)“…The favorable combination of fast-ionic conductivity and high electrochemical stability of Li-stuffed garnet type Li7La3Zr2O12 (LLZ) makes this material a…”
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Lithium Migration in Li4Ti5O12 Studied Using in Situ Neutron Powder Diffraction
Published in Chemistry of materials (08-04-2014)“…We used in situ neutron powder diffraction (NPD) to study the migration of Li in Li4Ti5O12 anodes with different particle sizes during battery cycling. The…”
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Br-Doped Li4Ti5O12 and Composite TiO2 Anodes for Li-ion Batteries: Synchrotron X-Ray and in situ Neutron Diffraction Studies
Published in Advanced functional materials (21-10-2011)“…Synchrotron X‐ray diffraction data were used to determine the phase purity and re‐evaluate the crystal‐structure of Li4Ti5O12‐xBrx electrode materials (where…”
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Direct Evidence of Concurrent Solid-Solution and Two-Phase Reactions and the Nonequilibrium Structural Evolution of LiFePO4
Published in Journal of the American Chemical Society (09-05-2012)“…Lithium-ion batteries power many portable devices and in the future are likely to play a significant role in sustainable-energy systems for transportation and…”
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The Origin of Capacity Fade in the Li2MnO3·LiMO2 (M = Li, Ni, Co, Mn) Microsphere Positive Electrode: An Operando Neutron Diffraction and Transmission X‑ray Microscopy Study
Published in Journal of the American Chemical Society (20-07-2016)“…The mechanism of capacity fade of the Li2MnO3·LiMO2 (M = Li, Ni, Co, Mn) composite positive electrode within a full cell was investigated using a combination…”
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In Situ Powder Diffraction Studies of Electrode Materials in Rechargeable Batteries
Published in ChemSusChem (07-09-2015)“…The ability to directly track the charge carrier in a battery as it inserts/extracts from an electrode during charge/discharge provides unparalleled insight…”
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Elucidating Negative Thermal Expansion in MOF-5
Published in Journal of physical chemistry. C (07-10-2010)“…Multi-temperature X-ray diffraction studies show that twisting, rotation, and libration cause negative thermal expansion (NTE) of the nanoporous metal−organic…”
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Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks
Published in Nature communications (19-11-2018)“…Control of the thermomechanical properties of functional materials is of great fundamental and technological significance, with the achievement of zero or…”
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Structure, Atomistic Simulations, and Phase Transition of Stoichiometric Yeelimite
Published in Chemistry of materials (14-05-2013)“…Yeelimite, Ca4[Al6O12]SO4, is outstanding as an aluminate sodalite, being the framework of these type of materials flexible and dependent on ion sizes and…”
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Enhanced Rate-Capability and Cycling-Stability of 5 V SiO2- and Polyimide-Coated Cation Ordered LiNi0.5Mn1.5O4 Lithium-Ion Battery Positive Electrodes
Published in Journal of physical chemistry. C (23-02-2017)“…The ordered LiNi0.5Mn1.5O4 spinel exhibits great promise as a potential high-energy positive electrode for lithium-ion batteries due to its exceptionally high…”
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Interpenetration as a Mechanism for Negative Thermal Expansion in the Metal-Organic Framework Cu3(btb)2 (MOF-14)
Published in Angewandte Chemie International Edition (12-05-2014)“…Metal–organic framework materials (MOFs) have recently been shown in some cases to exhibit strong negative thermal expansion (NTE) behavior, while framework…”
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Structural changes in a commercial lithium-ion battery during electrochemical cycling: An in situ neutron diffraction study
Published in Journal of power sources (15-12-2010)“…The structural response to electrochemical cycling of the components within a commercial Li-ion battery (LiCoO 2 cathode, graphite anode) is shown through in…”
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Metal-Organic Frameworks with Exceptionally High Methane Uptake: Where and How is Methane Stored?
Published in Chemistry : a European journal (03-05-2010)“…Metal–organic frameworks (MOFs) are a novel family of physisorptive materials that have exhibited great promise for methane storage. So far, a detailed…”
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Negative Thermal Expansion in LnCo(CN)6 (Ln=La, Pr, Sm, Ho, Lu, Y): Mechanisms and Compositional Trends
Published in Angewandte Chemie International Edition (10-05-2013)“…RUM with a twist: The magnitude of negative thermal expansion (NTE) in the LnCo(CN)6 coordination frameworks increases with Ln ion radius rLn. The framework…”
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Extreme compressibility in LnFe(CN)6 coordination framework materials via molecular gears and torsion springs
Published in Nature chemistry (01-03-2016)“…The mechanical flexibility of coordination frameworks can lead to a range of highly anomalous structural behaviours. Here, we demonstrate the extreme…”
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