Search Results - "Peterson, Joshua P"
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Solvent Effects on the Stability and Delocalization of Aryl Dicyanomethyl Radicals: The Captodative Effect Revisited
Published in Journal of the American Chemical Society (14-08-2019)“…The captodative effect postulates that radicals substituted with both electron donating and accepting groups enjoy a special enhanced stabilization, a model…”
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Spin Delocalization, Polarization, and London Dispersion Forces Govern the Formation of Diradical Pimers
Published in Journal of the American Chemical Society (18-03-2020)“…Some free radicals are stable enough to be isolated, but most are either unstable transient species or exist as metastable species in equilibrium with a…”
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Effect of Structure on the Spin–Spin Interactions of Tethered Dicyanomethyl Diradicals
Published in Journal of the American Chemical Society (31-10-2018)“…Stable organic radicals with switchable spin states have attracted attention for a variety of applications, but a fundamental understanding of how radical…”
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Effect of Substituents on the Bond Strength of Air-Stable Dicyanomethyl Radical Thermochromes
Published in Journal of organic chemistry (16-06-2017)“…A series of substituted aryl dicyanomethyl radicals were synthesized, and the bonding thermodynamic parameters for self-dimerization were determined from van’t…”
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Effect of Structure on the Spin Switching and Magnetic Bistability of Solid-State Aryl Dicyanomethyl Monoradicals and Diradicals
Published in ACS omega (20-08-2019)“…Stable organic radicals with switchable spin states have applications in medicine, biology, and material science. An emerging class of such spin-switchable…”
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Solvent-Responsive Radical Dimers
Published in Organic letters (07-08-2020)“…An air- and thermally stable aryl dicyanomethyl radical is reported that switches between two dimeric formsa σ dimer and a π dimerby changing the solvent…”
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Variations on the “Blue-Bottle” Demonstration Using Food Items That Contain FD&C Blue #1
Published in Journal of chemical education (13-10-2015)“…Erioglaucine dye (FD&C Blue #1) can be used instead of methylene blue in the classic “blue-bottle” demonstration. Food items containing FD&C Blue #1 and…”
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Spectroscopy of Sound Transmission in Solid Samples
Published in Journal of chemical education (14-10-2014)“…These laboratory experiments are designed to familiarize students with concepts of spectroscopy by using sound waves. Topics covered in these experiments…”
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