Search Results - "Peters, Kevin S"

A Theory−Experiment Conundrum for Proton Transfer by Peters, Kevin S

“…For the past 60 years, the framework for understanding the kinetic behavior of proton transfer has been transition state theory. Found throughout textbooks,…”
Get full text

Dynamic Processes Leading to Covalent Bond Formation for SN1 Reactions by Peters, Kevin S

“…The SN1 reaction mechanism is one of the most fundamental processes in organic chemistry. As such, it has been the subject of study for over 70 years with the…”
Get full text

Nature of dynamic processes associated with the S(N)1 reaction mechanism by Peters, Kevin S

Get full text

Nature of Dynamic Processes Associated with the SN1 Reaction Mechanism by Peters, Kevin S

“…This article discusses the nature of dynamic processes associated with the SN1 reaction mechanism. The article examines the issues concerning the mechanism…”
Get full text

Experimental Determination of the Antiaromaticity of Cyclobutadiene by Deniz, Ashok A., Peters, Kevin S., Snyder, Gary J.

“…Photoacoustic calorimetry was used to quantify the antiaromaticity of 1,3-cyclobutadiene (CBD) by measuring the heat release accompanying its formation via…”
Get full text

A DFT investigation into the structure and energetics for nonadiabatic proton transfer in the benzophenone/N,N-dimethylaniline contact radical ion pair by Peters, Kevin S.

“…For the past 60 years, the standard model for the interpretation of the mechanism for proton transfer has been based upon transition‐state theory, which posits…”
Get full text

Dynamic processes leading to covalent bond formation for S(N)1 reactions by Peters, Kevin S

“…The SN1 reaction mechanism is one of the most fundamental processes in organic chemistry. As such, it has been the subject of study for over 70 years with the…”
Get full text

Nonadiabatic Proton/Deuteron Transfer within the Benzophenone−Triethylamine Triplet Contact Radical Ion Pair:  Exploration of the Influence of Structure upon Reaction by Heeb, Libby R, Peters, Kevin S

“…The dynamics of proton transfer within a variety of substituted benzophenone−triethylamine triplet contact radical ion pairs are examined in the solvents…”
Get full text

Picosecond Kinetic Study of the Photoinduced Homolysis of Benzhydryl Acetates:  The Nature of the Conversion of Radical Pairs into Ion Pairs by Heeb, Libby R, Peters, Kevin S

“…The conversion of benzhydryl acetate geminate radical pairs to contact ion pairs following photoinduced homolysis in solution is studied using picosecond…”
Get full text

Further Evidence of an Inverted Region in Proton Transfer within the Benzophenone/Substituted Aniline Contact Radical Ion Pairs; Importance of Vibrational Reorganization Energy by Heeb, Libby R, Peters, Kevin S

“…The dynamics of proton transfer within the triplet contact radical ion pair of a variety of substituted benzophenones with N,N-diethylaniline,…”
Get full text

Characterization of Solvent and Deuterium Isotope Effects on Nonadiabatic Proton Transfer in the Benzophenone/N,N-Dimethylaniline Contact Radical Ion Pair by Peters, Kevin S, Kim, Ganghyeok

“…The dynamics of proton transfer within a variety of substituted benzophenones/N,N-dimethylaniline contact radical ion pairs are examined in a wide range of…”
Get full text

Time-Resolved Photoacoustic Calorimetry: Probing the Energetics and Dynamics of Fast Chemical and Biochemical Reactions by Peters, Kevin S., Snyder, Gary J.

“…Time-resolved photoacoustic calorimetry is a new experimental technique that measures the dynamics of enthalpy changes on the time scale of nanoseconds to…”
Get full text

Dynamic Nature of the Transition State for the SN1 Reaction Mechanism of Diphenylmethyl Acetates by Peters, Kevin S, Gasparrini, Sarah, Heeb, Libby R

“…Picosecond absorption spectroscopy is employed in the study of the reaction dynamics for the contact ion pairs produced upon the photolysis of a series of…”
Get full text

Picosecond Dynamics of Nonadiabatic Proton Transfer:  A Kinetic Study of Proton Transfer within the Contact Radical Ion Pair of Substituted Benzophenones/N,N-Dimethylaniline by Peters, Kevin S, Cashin, Amanda, Timbers, Peter

“…Picosecond absorption spectroscopy has been employed in the study of the dynamics of proton transfer within substituted benzophenones/N,N-dimethylaniline…”
Get full text

Role of the arginine-45 salt bridge in ligand dissociation from sperm whale carboxymyoglobin as probed by photoacoustic calorimetry by Westrick, Judy A, Peters, Kevin S, Ropp, J. Dezz, Sligar, Stephen G

“…The dynamics of the enthalpy and volume changes found in the photodissociation of CO from sperm whale carboxymyoglobin and two site-directed mutants in which…”
Get full text

Solvent effects on the picosecond dynamics of the photoreduction of benzophenone by aromatic amines by Simon, John D, Peters, Kevin S

Get full text

Nature of the Potential Energy Surfaces for the SN1 Reaction:  A Picosecond Kinetic Study of Homolysis and Heterolysis for Diphenylmethyl Chlorides by Lipson, Matthew, Deniz, Ashok A, Peters, Kevin S

“…The picosecond dynamics for the photoinduced homolysis and heterolysis of (4-methylphenyl)phenylmethyl chloride and bis(4-methylphenyl)methyl chloride in…”
Get full text

Picosecond dynamics of ion pairs: the effect of hydrogen bonding on ion-pair intermediates by Simon, John D, Peters, Kevin S

Get full text

A time-resolved photoacoustic calorimetry study of the dynamics of enthalpy and volume changes produced in the photodissociation of carbon monoxide from sperm whale carboxymyoglobin by Westrick, Judy A, Goodman, Joshua L, Peters, Kevin S

“…The dynamics of the enthalpy and volume changes produced in the photodissociation of carbon monoxide from sperm whale myoglobin is investigated by…”
Get full text

Solvent Effects for Nonadiabatic Proton Transfer in the Benzophenone/N,N-Dimethylaniline Contact Radical Ion Pair by Peters, Kevin S, Kim, Ganghyeok

“…Picosecond absorption spectroscopy is employed in determining the dynamics of proton transfer within a variety of substituted benzophenones/N,N-dimethylaniline…”
Get full text