Search Results - "Peters, C."
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Catalytic Nitrogen-to-Ammonia Conversion by Osmium and Ruthenium Complexes
Published in Journal of the American Chemical Society (15-11-2017)“…Despite the critical role Ru and Os complexes have played in the development of transition metal dinitrogen chemistry, they have not been shown to mediate…”
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Catalytic N2‑to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes
Published in Chemical reviews (24-06-2020)“…Nitrogen fixation, the six-electron/six-proton reduction of N2, to give NH3, is one of the most challenging and important chemical transformations…”
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Intersection of biology and therapeutics: type 2 targeted therapeutics for adult asthma
Published in The Lancet (British edition) (01-02-2020)“…Asthma is a disease of reversible airflow obstruction characterised clinically by wheezing, shortness of breath, and coughing. Increases in airway type 2…”
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Catalytic conversion of nitrogen to ammonia by an iron model complex
Published in Nature (London) (05-09-2013)“…Catalysis of the reduction of nitrogen to ammonia under mild conditions by a tris(phosphine)borane-supported iron complex indicates that a single iron site may…”
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Loop-mediated isothermal amplification (LAMP): An advanced molecular point-of-care technique for the detection of Leishmania infection
Published in PLoS neglected tropical diseases (01-11-2019)“…Leishmaniasis, caused by protozoan parasites of the Leishmania genus, represents an important health problem in many regions of the world. Lack of effective…”
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Boryl–Metal Bonds Facilitate Cobalt/Nickel-Catalyzed Olefin Hydrogenation
Published in Journal of the American Chemical Society (01-10-2014)“…New approaches toward the generation of late first-row metal catalysts that efficiently facilitate two-electron reductive transformations (e.g., hydrogenation)…”
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Photoinduced, Copper-Catalyzed Decarboxylative C–N Coupling to Generate Protected Amines: An Alternative to the Curtius Rearrangement
Published in Journal of the American Chemical Society (06-09-2017)“…The Curtius rearrangement is a classic, powerful method for converting carboxylic acids into protected amines, but its widespread use is impeded by safety…”
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N2‐to‐NH3 Conversion by a triphos–Iron Catalyst and Enhanced Turnover under Photolysis
Published in Angewandte Chemie International Edition (06-06-2017)“…Bridging iron hydrides are proposed to form at the active site of MoFe‐nitrogenase during catalytic dinitrogen reduction to ammonia and may be key in the…”
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Hydricity of an Fe–H Species and Catalytic CO2 Hydrogenation
Published in Inorganic chemistry (01-06-2015)“…Despite renewed interest in carbon dioxide (CO2) reduction chemistry, examples of homogeneous iron catalysts that hydrogenate CO2 are limited compared to their…”
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Enhanced Ammonia Oxidation Catalysis by a Low-Spin Iron Complex Featuring Cis Coordination Sites
Published in Journal of the American Chemical Society (26-05-2021)“…The goal of using ammonia as a solar fuel motivates the development of selective ammonia oxidation (AO) catalysts for fuel cell applications. Herein, we…”
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DIAGNOSIS OF ENDOCRINE DISEASE: Congenital hypothyroidism: update and perspectives
Published in European journal of endocrinology (01-12-2018)“…Congenital hypothyroidism (CH) may be primary, due to a defect affecting the thyroid gland itself, or central, due to impaired thyroid-stimulating hormone…”
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A molecular mediator for reductive concerted proton-electron transfers via electrocatalysis
Published in Science (American Association for the Advancement of Science) (14-08-2020)“…Delivering protons with electrons Many chemical reactions involve concurrent transfer of a proton and an electron. In electrochemical synthesis, this mechanism…”
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Fe–N₂/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco)
Published in Proceedings of the National Academy of Sciences - PNAS (01-10-2013)“…We report here a series of four- and five-coordinate Fe model complexes that feature an axial tri(silyl)methyl ligand positioned trans to a substrate-binding…”
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Asymmetric copper-catalyzed C-N cross-couplings induced by visible light
Published in Science (American Association for the Advancement of Science) (12-02-2016)“…Despite a well-developed and growing body of work in copper catalysis, the potential of copper to serve as a photocatalyst remains underexplored. Here we…”
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In‐Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO2 Reduction to Ethylene
Published in Angewandte Chemie International Edition (18-11-2019)“…Bridging homogeneous molecular systems with heterogeneous catalysts is a promising approach for the development of new electrodes, combining the advantages of…”
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Cp Noninnocence Leads to a Remarkably Weak C–H Bond via Metallocene Protonation
Published in Journal of the American Chemical Society (20-03-2019)“…Metallocenes, including their permethylated variants, are extremely important in organometallic chemistry. In particular, many are synthetically useful either…”
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Visible-Light-Induced, Copper-Catalyzed Three-Component Coupling of Alkyl Halides, Olefins, and Trifluoromethylthiolate To Generate Trifluoromethyl Thioethers
Published in ACS catalysis (07-12-2018)“…Photoinduced, copper-catalyzed coupling reactions are emerging as a powerful method for generating Csp3–Y (Y = C or heteroatom) bonds from alkyl electrophiles…”
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Electrocatalytic Ammonia Oxidation Mediated by a Polypyridyl Iron Catalyst
Published in ACS catalysis (01-11-2019)“…Electrocatalytic ammonia oxidation (AO) mediated by iron(II) tris(2-pyridylmethyl)amine (TPA) bis-ammine triflate, [(TPA)Fe(NH3)2]OTf2, is reported…”
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The role of dermis resident macrophages and their interaction with neutrophils in the early establishment of Leishmania major infection transmitted by sand fly bite
Published in PLoS pathogens (02-11-2020)“…There is substantial experimental evidence to indicate that Leishmania infections that are transmitted naturally by the bites of infected sand flies differ in…”
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Photoinduced Ullmann C–N Coupling: Demonstrating the Viability of a Radical Pathway
Published in Science (American Association for the Advancement of Science) (02-11-2012)“…Carbon-nitrogen (C–N) bond-forming reactions of amines with aryl halides to generate arylamines (anilines), mediated by a stoichiometric copper reagent at…”
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