Search Results - "Perotti, Jeremy M."

Expanding Dinitrogen Reduction Chemistry to Trivalent Lanthanides via the LnZ3/Alkali Metal Reduction System:  Evaluation of the Generality of Forming Ln2(μ-η 2 :η 2 -N2) Complexes via LnZ3/K by Evans, William J, Lee, David S, Rego, Daniel B, Perotti, Jeremy M, Kozimor, Stosh A, Moore, Ericka K, Ziller, Joseph W

“…The Ln[N(SiMe3)2]3/K dinitrogen reduction system, which mimicks the reactions of the highly reducing divalent ions Tm(II), Dy(II), and Nd(II), has been…”
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Evaluation of a Silylene Divalent Lanthanide Interaction in the Metallocene Complex (C5Me5)2Sm[SiN t BuCHCHN t Bu] by Evans, William J, Perotti, Jeremy M, Ziller, Joseph W, Moser, Daniel F, West, Robert

“…An R2Si: →Ln(II) complex 1, has been synthesized in 90% yield by reaction of (C5Me5)2Sm with 1,3-di-tert-butyl-2,3-dihydro-1H-1,3,2-diazasilol-2-ylidene in…”
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Synthetic Utility of [(C5Me5)2Ln][(μ-Ph)2BPh2] in Accessing [(C5Me5)2LnR] x Unsolvated Alkyl Lanthanide Metallocenes, Complexes with High C−H Activation Reactivity by Evans, William J, Perotti, Jeremy M, Ziller, Joseph W

“…The loosely ligated [BPh4]1- ion in [(C5Me5)2Ln][(μ-Ph)2BPh2] can be readily displaced by alkyllithium or potassium reagents to provide access to unsolvated…”
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Trialkylboron/Lanthanide Metallocene Hydride Chemistry:  Polydentate Bridging of (HBEt3)- to Lanthanum by Evans, William J, Perotti, Jeremy M, Ziller, Joseph W

“…The reaction of [(C5Me5)2LaH] x with BEt3 is reported, and the solid-state structures of the lanthanum product (C5Me5)2La[(μ-H)(μ-Et)2BEt], 1, and its THF…”
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Tethered Olefin Studies of Alkene versus Tetraphenylborate Coordination and Lanthanide Olefin Interactions in Metallocenes by Evans, William J, Perotti, Jeremy M, Brady, Jason C, Ziller, Joseph W

“…The tethered olefin cyclopentadienyl ligand, [(C5Me4)SiMe2(CH2CHCH2)]-, forms unsolvated metallocenes, [(C5Me4)SiMe2(CH2CHCH2)]2Ln (Ln = Sm, 1; Eu, 2; Yb,…”
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Formation of a Bridging Planar Trimethylenemethane Dianion from a Neopentyl Precursor via Sequential β-Alkyl Elimination and C−H Activation by Evans, William J, Perotti, Jeremy M, Ziller, Joseph W

“…The reaction of neopentyllithium, Me3CCH2Li, with [(C5Me5)2Sm][(μ-Ph)2BPh2], 1, was investigated as a route to the unsolvated alkyl, [(C5Me5)2Sm(CH2CMe3)] x ,…”
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Structural studies of lanthanide and yttrium metallocene oxides by Evans, William J, Davis, Benjamin L, Nyce, Gregory W, Perotti, Jeremy M, Ziller, Joseph W

“…Examination of the chemistry of sterically crowded (C 5Me 4R) 3Ln complexes has provided access to a series of [(C 5Me 4R) 2Ln] 2(μ-O) complexes: [(C 5Me 5)…”
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Synthesis and Comparative η1-Alkyl and Sterically Induced Reduction Reactivity of (C5Me5)3Ln Complexes of La, Ce, Pr, Nd, and Sm by Evans, William J, Perotti, Jeremy M, Kozimor, Stosh A, Champagne, Timothy M, Davis, Benjamin L, Nyce, Gregory W, Fujimoto, Cy H, Clark, Robert D, Johnston, Matthew A, Ziller, Joseph W

“…The synthesis of (C5Me5)3Ce and (C5Me5)3Pr from [(C5Me5)2Ln][(μ-Ph)2BPh2] and KC5Me5 completes the series of sterically crowded (C5Me5)3Ln complexes for the…”
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Expanding Dinitrogen Reduction Chemistry to Trivalent Lanthanides via the LnZ 3 /Alkali Metal Reduction System:  Evaluation of the Generality of Forming Ln 2 (μ - η 2 : η 2 -N 2 ) Complexes via LnZ 3 /K by Evans, William J., Lee, David S., Rego, Daniel B., Perotti, Jeremy M., Kozimor, Stosh A., Moore, Ericka K., Ziller, Joseph W.

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Evaluation of a Silylene Divalent Lanthanide Interaction in the Metallocene Complex (C 5 Me 5 ) 2 Sm[SiN t BuCHCHN t Bu] by Evans, William J., Perotti, Jeremy M., Ziller, Joseph W., Moser, Daniel F., West, Robert

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Synthesis and Comparative η 1 -Alkyl and Sterically Induced Reduction Reactivity of (C 5 Me 5 ) 3 Ln Complexes of La, Ce, Pr, Nd, and Sm by Evans, William J., Perotti, Jeremy M., Kozimor, Stosh A., Champagne, Timothy M., Davis, Benjamin L., Nyce, Gregory W., Fujimoto, Cy H., Clark, Robert D., Johnston, Matthew A., Ziller, Joseph W.

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Synthesis and structure of organosamarium metallocenes including the carbon-hydrogen and carbon-carbon bond cleavage reactivity of unsolvated tris(pentamethylcyclopentadienyl) samarium complexes by Perotti, Jeremy M

“…This dissertation describes advances in several areas of lanthanide metallocene chemistry including the reactivity of the sterically crowded…”
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Synthesis and structure of organosamarium metallocenes including the carbon-hydrogen and carbon-carbon bond cleavage reactivity of unsolvated tris(pentamethylcyclopentadienyl) samarium complexes by Perotti, Jeremy M

“…This dissertation describes advances in several areas of lanthanide metallocene chemistry including the reactivity of the sterically crowded…”
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