Search Results - "Percival, Paul W"

Free Radical Reactivity of a Phosphaalkene Explored Through Studies of Radical Isotopologues by Chandrasena, Lalangi, Samedov, Kerim, McKenzie, Iain, Mozafari, Mina, West, Robert, Gates, Derek P., Percival, Paul W.

“…Muonium (Mu), an H atom analogue, is employed to probe the addition of free radicals to the P=C bond of a phosphaalkene. Specifically, two unprecedented…”
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Free Radical Chemistry of Phosphasilenes by Samedov, Kerim, Heider, Yannic, Cai, Yuanjing, Willmes, Philipp, Mühlhausen, Daniel, Huch, Volker, West, Robert, Scheschkewitz, David, Percival, Paul W.

“…Understanding the characteristics of radicals formed from silicon‐containing heavy analogues of alkenes is of great importance for their application in radical…”
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Silicon Meets Cyclotron: Muon Spin Resonance of Organosilicon Radicals by West, Robert, Samedov, Kerim, Percival, Paul W.

“…Muons, generated at a high‐powered cyclotron, can capture electrons to form muonium atoms. Muon spin resonance spectra can be recorded for organosilyl radicals…”
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Characterization of Free Radicals in Clathrate Hydrates of Furan, 2,3-Dihydrofuran, and 2,5-Dihydrofuran by Muon Spin Spectroscopy by Mozafari, Mina, Brodovitch, Jean-Claude, Chandrasena, Lalangi, Percival, Paul W

“…In addition to their importance as abundant hydrocarbon deposits in nature, clathrate hydrates are being studied as potential media for hydrogen and carbon…”
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Silyl Radical formed by Muonium Addition to a Silylene by Mitra, Amitabha, Brodovitch, Jean-Claude, Krempner, Clemens, Percival, Paul W, Vyas, Pooja, West, Robert

“…Muonraker: Irradiation of the stable silylene N,N′‐bis(2,6‐diisopropylphenyl)‐1,3‐diaza‐2‐silacyclopent‐4‐en‐2‐ylidene with muons produced a radical that was…”
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Free Radicals Formed by H Atom Addition to Allenes as Determined by Muon Spin Spectroscopy by Scollon, Myles, Percival, Paul W

“…Allyl and vinyl radicals are important intermediates in diverse areas of chemistry, ranging from combustion to synthesis. However, questions remain about the…”
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Free Radical Reactivity of a Phosphaalkene Explored Through Studies of Radical Isotopologues by Chandrasena, Lalangi, Samedov, Kerim, McKenzie, Iain, Mozafari, Mina, West, Robert, Gates, Derek P., Percival, Paul W.

“…Muonium (Mu), an H atom analogue, is employed to probe the addition of free radicals to the P=C bond of a phosphaalkene. Specifically, two unprecedented…”
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Reaction of Stable N‐Heterocyclic Silylenes and Germylenes with Muonium by McCollum, Brett M., Brodovitch, Jean‐Claude, Clyburne, Jason A. C., Mitra, Amitabha, Percival, Paul W., Tomasik, Adam, West, Robert

“…Very a‐Mu‐sing! Reaction of a germylene with muonium (Mu) yields a germyl radical, in direct analogy to Mu attack at the ylideneic center of the corresponding…”
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The Reaction of Muonium with Hydrogen Peroxide in Aqueous Solution by Percival, Paul W., Brodovitch, Jean‐Claude

“…Rate constants for the reactions of muonium (Mu) (the ultralight isotope of the hydrogen atom) with H2O2 in H2O and D2O2 in D2O have been determined at various…”
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Probing Radical Addition to 1‐Phosphabutadienes by Employing Muonium as a “Light Isotope” of Hydrogen by Walsgrove, Henry T. G., Percival, Paul W., Gates, Derek P.

“…Understanding free radical addition to multiple bonds is important to elucidating the mechanistic details of addition polymerization reactions, albeit the…”
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Probing the Reactivity of a Stable Silene Using Muonium by McCollum, Brett M, Abe, Takashi, Brodovitch, Jean-Claude, Clyburne, Jason A.C, Iwamoto, Takeaki, Kira, Mitsuo, Percival, Paul W, West, Robert

“…Taking the silenic route: Addition of a hydrogen atom analogue, muonium (Mu), to stable silene 1 gives rise to two distinct radical species, 1‐CMu and 1‐SiMu,…”
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Investigation of H atom and free radical behaviour in clathrate hydrates of organic molecules by Mozafari, Mina, Chandrasena, Lalangi, McKenzie, Iain, Samedov, Kerim, Percival, Paul W.

“…Clathrate hydrates are icy materials composed of a lattice of water molecules containing well-defined cavities which can accommodate small guest molecules…”
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Prediction of Rate Constants for Reactions of the Hydroxyl Radical in Water at High Temperatures and Pressures by Ghandi, Khashayar, Percival, Paul W

“…There is a need for accurate data on the rate constants of many reactions involved in the radiolysis of water at high temperature and pressure, to model…”
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Characterization of free radicals in clathrate hydrates of pyrrole, thiophene, and isoxazole by muon spin spectroscopy by Mozafari, Mina, Chandrasena, Lalangi, McKenzie, Iain, Samedov, Kerim, Percival, Paul W

“…Gas hydrates have long been of interest to the petrochemical industry, but there has been growing interest in potential applications for carbon dioxide…”
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Organic Free Radicals in Superheated Water Studied by Muon Spin Spectroscopy by Percival, Paul W, Brodovitch, Jean-Claude, Ghandi, Khashayar, McCollum, Brett M, McKenzie, Iain

“…There is a pressing need to identify and monitor reaction intermediates in water at high temperatures and pressures, but conventional techniques have limited…”
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Organic Free Radicals in Clathrate Hydrates Investigated by Muon Spin Spectroscopy by Percival, Paul W, Mozafari, Mina, Brodovitch, Jean-Claude, Chandrasena, Lalangi

“…Very little is known about the behavior of free H atoms and small organic radicals inside clathrate hydrate structures despite the relevance of such species to…”
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H atom kinetics in superheated water studied by muon spin spectroscopy by Percival, Paul W., Brodovitch, Jean-Claude, Ghandi, Khashayar, McCollum, Brett M., McKenzie, Iain

“…It is possible to study H atom chemistry in aqueous systems over a wide range of conditions, from standard to supercritical, using the exotic atom muonium (Mu)…”
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Free Radical Reactivity of Mono- and Dichlorosilylene with Muonium by Percival, Paul W., Brodovitch, Jean-Claude, Mozafari, Mina, Mitra, Amitabha, West, Robert, Ghadwal, Rajendra S., Azhakar, Ramachandran, Roesky, Herbert W.

“…The H atom analogue muonium (Mu) has been used to explore the free radical reactivity of two novel chlorosilylenes. Spectroscopic and computational…”
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Enolization of Acetone in Superheated Water Detected via Radical Formation by Ghandi, Khashayar, Addison-Jones, Brenda, Brodovitch, Jean-Claude, McCollum, Brett M, McKenzie, Iain, Percival, Paul W

“…Muoniated free radicals have been detected in muon-irradiated aqueous solutions of acetone at high temperatures and pressures. At temperatures below 250 °C,…”
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Free Radicals of N‑Donor-Stabilized Silicon(II) Compounds Probed by Muon Spin Spectroscopy by Samedov, Kerim, West, Robert, Percival, Paul W, Brodovitch, Jean-Claude, Chandrasena, Lalangi, Mozafari, Mina, Tacke, Reinhold, Junold, Konstantin, Kobelt, Claudia, Samuel, Prinson P, Azhakar, Ramachandran, Mondal, Kartik Chandra, Roesky, Herbert W, Driess, Matthias, Wang, Wenyuan

“…Transverse-field muon spin rotation (TF-μSR) spectra have been obtained for muoniated free radicals formed by positive muon irradiation of a series of…”
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