Search Results - "Peacock, Robert D."
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Circularly Polarized Luminescence from Helically Chiral N,N,O,O-Boron-Chelated Dipyrromethenes
Published in Chemistry : a European journal (04-01-2016)“…Helically chiral N,N,O,O‐boron chelated dipyrromethenes showed solution‐phase circularly polarized luminescence (CPL) in the red region of the visible spectrum…”
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Chiroptical Probing of Lanthanide-Directed Self-Assembly Formation Using btp Ligands Formed in One-Pot Diazo-Transfer/Deprotection Click Reaction from Chiral Amines
Published in Chemistry : a European journal (11-01-2016)“…A series of enantiomeric 2,6‐bis(1,2,3‐triazol‐4‐yl)pyridines (btp)‐containing ligands was synthesized by a one‐pot two‐step copper‐catalyzed amine/alkyne…”
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Circularly Polarized Lanthanide Luminescence from Langmuir-Blodgett Films Formed from Optically Active and Amphiphilic EuIII-Based Self-Assembly Complexes
Published in Angewandte Chemie International Edition (16-01-2012)“…Europium union: The development of chiral amphiphilic self‐assembled complexes by europium(III)‐directed synthesis is described. These systems form stable…”
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Probing the Effects of Ligand Isomerism in Chiral Luminescent Lanthanide Supramolecular Self-Assemblies: A Europium "Trinity Sliotar" Study
Published in Chemistry : a European journal (25-11-2013)“…“Trinity Sliotar” family: Chiral ligands containing pyridyl and naphthalene moieties were synthesized and characterized. These ligands were successfully used…”
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Quantifying the formation of chiral luminescent lanthanide assemblies in an aqueous medium through chiroptical spectroscopy and generation of luminescent hydrogels
Published in Faraday discussions (01-01-2015)“…Herein we present the synthesis and the photophysical evaluation of water-soluble chiral ligands (2·(R,R) and 2·(S,S)) and their application in the formation…”
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Metal-Directed Synthesis of Enantiomerially Pure Dimetallic Lanthanide Luminescent Triple-Stranded Helicates
Published in Journal of the American Chemical Society (22-07-2009)“…The synthesis and photophysical evaluation of two enatiomerially pure dimetallic lanthanide luminescent triple-stranded helicates is described. The two…”
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Europium Directed Synthesis of Enantiomerically Pure Dimetallic Luminescent "Squeezed" Triple-Stranded Helicates; Solution Studies
Published in Chemistry, an Asian journal (01-03-2010)“…Triple‐stranded helix: The formation of two novel chiral enantiomerially pure dimetallic (EuIII) triple stranded helicates (L3Eu2) was monitored in solution by…”
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The application of chiroptical spectroscopy (circular dichroism) in quantifying binding events in lanthanide directed synthesis of chiral luminescent self-assembly structures
Published in Chemical science (Cambridge) (01-01-2015)“…The binding of asymmetrical and optically pure tridentate ligands ( = and ) containing one carboxylic group and 2-naphthyl as an antenna to lanthanide ions ( =…”
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Self-Assembly of Chiral Luminescent Lanthanide Coordination Bundles
Published in Journal of the American Chemical Society (12-09-2007)“…The synthesis and characterization of several highly ordered lanthanide complexes formed by the use of f-metal directed supramolecular synthesis is described…”
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Reversible Redox Reactions in an Extended Polyoxometalate Framework Solid
Published in Angewandte Chemie (International ed.) (25-08-2008)“…Back and forth: A concerted reversible redox reaction occurs in a pure metal oxide extended polyoxometalate framework when the accessible pockets are filled…”
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A chiral probe for the acute phase proteins alpha-1-acid glycoprotein and alpha-1-antitrypsin based on europium luminescence
Published in Dalton transactions : an international journal of inorganic chemistry (14-11-2012)“…Reversible and selective binding of a dynamically racemic europium(III) complex to α(1)-acid glycoprotein and α(1)-antitrypsin is characterised by a…”
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Cobalt(II) Citrate Cubane Single-Molecule Magnet
Published in Inorganic chemistry (18-08-2008)“…An investigation of the magnetic properties of the cobalt(II) citrate cubane [C(NH2)3]8{Co4(cit)4}·4H2O reveals that the cluster is a new cobalt(II)…”
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Ligand Chirality Transfer from Solution State to the Crystalline Self‐Assemblies in Circularly Polarized Luminescence (CPL) Active Lanthanide Systems
Published in Advanced science (01-05-2024)“…The synthesis of a family of chiral and enantiomerically pure pyridyl‐diamide (pda) ligands that upon complexation with europium [Eu(CF3SO3)3] result in chiral…”
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Structural, Luminescence, and NMR Studies of the Reversible Binding of Acetate, Lactate, Citrate, and Selected Amino Acids to Chiral Diaqua Ytterbium, Gadolinium, and Europium Complexes
Published in Journal of the American Chemical Society (30-10-2002)“…The nature of the ternary complexes formed in aqueous media at ambient pH on reversible binding of acetate, lactate, citrate, and selected amino acids and…”
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The Selectivity of Reversible Oxy-Anion Binding in Aqueous Solution at a Chiral Europium and Terbium Center: Signaling of Carbonate Chelation by Changes in the Form and Circular Polarization of Luminescence Emission
Published in Journal of the American Chemical Society (11-10-2000)“…Reversible anion binding in aqueous media at chiral EuIII and TbIII centers has been characterized by 1H NMR and by changes in the emission intensity and…”
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Formation of Enantiomerically Pure Luminescent Triple-Stranded Dimetallic Europium Helicates and Their Corresponding Hierarchical Self-Assembly Formation in Protic Polar Solutions
Published in Inorganic chemistry (02-03-2020)“…Ditopic helicate ligands 1 and 2 were synthesized for the formation of dinuclear EuIII luminescent chiral helical assemblies (Eu2·L3) in competitive organic…”
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Enantioselective regulation of a metal complex in reversible binding to serum albumin: dynamic helicity inversion signalled by circularly polarised luminescence
Published in Chemical communications (Cambridge, England) (01-01-2008)“…The helicity of the (SSS)-Delta enantiomer of a terbium and europium(III) complex is inverted on reversible binding to 'drug site II' of serum albumin,…”
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Core Electron Transitions as a Probe for Molecular Chirality: Natural Circular Dichroism at the Carbon K-edge of Methyloxirane
Published in Journal of the American Chemical Society (14-04-2004)“…We have measured for the first time the X-ray natural circular dichroism (XNCD) of a chiral molecule in an isotropic medium. In this condition the only…”
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Lanthanide Directed Self-Assembly of Highly Luminescent Supramolecular “Peptide” Bundles from α‑Amino Acid Functionalized 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Ligands
Published in Inorganic chemistry (16-02-2015)“…Ligands containing the [2,6-bis(1,2,3-triazol-4-yl)pyridine] (btp) motif have recently shown promise in coordination chemistry. The motif is synthesized via…”
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