Search Results - "Paz, Filipe A.Almeida"
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Metal–Organic Frameworks assembled from tetraphosphonic ligands and lanthanides
Published in Coordination chemistry reviews (15-01-2018)“…[Display omitted] •Use of tetraphosphonic acid linkers in the construction of Lanthanide–Organic Frameworks.•Structural diversity of Lanthanide–Organic…”
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Photoluminescent Thermometer Based on a Phase-Transition Lanthanide Silicate with Unusual Structural Disorder
Published in Journal of the American Chemical Society (04-03-2015)“…The hydrothermal synthesis of the novel Na[LnSiO4] (Ln = Gd, Eu, Tb) disordered orthorhombic system is reported. At 100 K, and above, these materials are best…”
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Visible-Light Excited Luminescent Thermometer Based on Single Lanthanide Organic Frameworks
Published in Advanced functional materials (20-12-2016)“…Isostructural lanthanide organic frameworks (Me2NH2)3[Ln3(FDC)4(NO3)4]·4H2O (Ln = Eu (1), Gd (2), Tb (3), H2FDC = 9‐fluorenone‐2,7‐dicarboxylic acid),…”
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Excimer Formation in a Terbium Metal–Organic Framework Assists Luminescence Thermometry
Published in Chemistry of materials (14-11-2017)“…Photoluminescent isotypical phosphonate-based metal–organic frameworks, [Ln(H5btp)]·2H2O [where Ln3+ = Tb3+ (1) or Gd3+ (2) and H8btp =…”
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Multifunctionality in an Ion-Exchanged Porous Metal–Organic Framework
Published in Journal of the American Chemical Society (27-01-2021)“…Porous robust materials are typically the primary selection of several industrial processes. Many of these compounds are, however, not robust enough to be used…”
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Perylene-Based Coordination Polymers: Synthesis, Fluorescent J‑Aggregates, and Electrochemical Properties
Published in Inorganic chemistry (22-05-2023)“…The incorporation of electroactive organic building blocks into coordination polymers (CPs) and metal–organic frameworks (MOFs) offers a promising approach for…”
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Porphyrin-Based Metal-Organic Frameworks as Heterogeneous Catalysts in Oxidation Reactions
Published in Molecules (Basel, Switzerland) (12-10-2016)“…Porphyrin-based Metal-Organic Frameworks (Por-MOFs) constitute a special branch of the wide MOF family that has proven its own value and high potential in…”
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Exploring the Luminescence, Redox, and Magnetic Properties in a Multivariate Metal–Organic Radical Framework
Published in Chemistry of materials (13-02-2024)“…Persistent neutral organic radicals are excellent building blocks for the design of functional molecular materials due to their unique electronic, magnetic,…”
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Bifunctional Porphyrin-Based Nano-Metal–Organic Frameworks: Catalytic and Chemosensing Studies
Published in Inorganic chemistry (02-04-2018)“…The use of 5,10,15,20-tetrakis(p-phenylphosphonic acid)porphyrin (H 10 TPPA) as a linker in the preparation of porphyrin-based metal–organic frameworks…”
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Phosphonate Appended Porphyrins as Versatile Chemosensors for Selective Detection of Trinitrotoluene
Published in Analytical chemistry (Washington) (21-04-2015)“…Fluorescent molecular probes based on phosphonate-functionalized porphyrin derivatives have been designed for selective detection of nitroaromatics. It is…”
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Monovacant polyoxometalates incorporated into MIL-101(Cr): novel heterogeneous catalysts for liquid phase oxidation
Published in Applied catalysis. A, General (26-02-2013)“…[Display omitted] ► Novel composite materials, PW11@MIL-101 and SiW11@MIL-101, were isolated. ► Materials were characterized and investigated as heterogeneous…”
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Coordination Compounds As Multi-Delivery Systems for Osteoporosis
Published in ACS applied materials & interfaces (04-08-2021)“…Osteoporosis therapies leveraging bisphosphonates and mineral components (e.g., magnesium, calcium, and strontium) have been raising attention because of their…”
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Robust Multifunctional Yttrium-Based Metal–Organic Frameworks with Breathing Effect
Published in Inorganic chemistry (06-02-2017)“…Phosphonate- and yttrium-based metal–organic frameworks (MOFs), formulated as [Y(H5btp)]·5.5H2O (1), [Y(H5btp)]·2.5H2O (2), (H3O)[Y2(H5btp)(H4btp)]·H2O…”
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Metal oxide-triazole hybrids as heterogeneous or reaction-induced self-separating catalysts
Published in Journal of catalysis (01-08-2016)“…[Display omitted] •Synthesis of the W analogue (2) of the hybrid solid [MoO3(1,2,4-triazole)0.5] (1).•Use of 2 as a heterogeneous catalyst for cyclooctene…”
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Cyclodextrins in Antiviral Therapeutics and Vaccines
Published in Pharmaceutics (01-03-2021)“…The present review describes the various roles of cyclodextrins (CDs) in vaccines against viruses and in antiviral therapeutics. The first section describes…”
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Hemi-synthesis, in-vitro and in-silico bioactivities of new chiral-Schiff bases and benzodiazepine derivatives from Ammodaucus leucotrichus(S)-perillaldehyde
Published in Journal of molecular structure (05-10-2021)“…•Benzodiazepines and chiral Schiff bases were hemi-synthetized from the natural (S)-(-)-perillaldehyde of A. leucotrichus.•Structures were chemically…”
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Novel heterogeneous catalysts based on lanthanopolyoxometalates supported on MIL-101(Cr)
Published in Catalysis today (01-12-2013)“…•Lanthanide-based polyoxotungstates were incorporated into the porous MIL-101.•Novel composite materials, Eu(PW11)2@MIL and Sm(PW11)2@MIL, were prepared.•The…”
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Luminescent and Magnetic Cyano-Bridged Coordination Polymers Containing 4d−4f Ions: Toward Multifunctional Materials
Published in Inorganic chemistry (06-07-2009)“…A new family of cyano-bridged coordination polymers Ln(H2O)5[M(CN)8] (Ln = Eu, Tb, Sm, Gd; M = Mo, W) were obtained and characterized by X-ray diffraction,…”
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One-Pot Synthesis of Benzopyran-4-ones with Cancer Preventive and Therapeutic Potential
Published in European journal of organic chemistry (01-02-2016)“…A one‐pot synthesis of novel benzopyran‐4‐ones is described. In a tandem reaction, organobase‐catalysed Michael addition of R1COCH2COR2 on…”
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Versatile Coordination Polymer Catalyst for Acid Reactions Involving Biobased Heterocyclic Chemicals
Published in Catalysts (01-02-2021)“…The chemical valorization/repurposing of biomass-derived chemicals contributes to a biobased economy. Furfural (Fur) is a recognized platform chemical produced…”
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