Search Results - "Paulus, Renzo M"
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Self-Healing Materials via Reversible Crosslinking of Poly(ethylene oxide)-Block-Poly(furfuryl glycidyl ether) (PEO-b-PFGE) Block Copolymer Films
Published in Advanced functional materials (18-10-2013)“…The application of well‐defined poly(furfuryl glycidyl ether) (PFGE) homopolymers and poly(ethylene oxide)‐b‐poly(furfuryl glycidyl ether) (PEO‐b‐PFGE) block…”
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2
Acetyl Halide Initiator Screening for the Cationic Ring-Opening Polymerization of 2-Ethyl-2-Oxazoline
Published in Macromolecular chemistry and physics (22-04-2008)“…Kinetic investigations on the cationic ring‐opening polymerization of 2‐ethyl‐2‐oxazoline were conducted using acetyl chloride, acetyl bromide, and acetyl…”
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3
Tunable pH- and Temperature-Sensitive Copolymer Libraries by Reversible Addition−Fragmentation Chain Transfer Copolymerizations of Methacrylates
Published in Macromolecules (20-02-2007)“…Reversible addition−fragmentation chain transfer (RAFT) polymerizations have been performed on a Chemspeed Accelerator SLT100 automated synthesizer to…”
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4
Easy Access to Amphiphilic Heterografted Poly(2-oxazoline) Comb Copolymers
Published in Macromolecules (09-07-2013)“…A series of heterografted polymers with a polymethacrylate backbone and varying composition of oligomeric 2-oxazoline side chains was synthesized by…”
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5
Thermoresponsive Poly(2-oxazine)s
Published in Macromolecular rapid communications. (16-01-2012)“…The monomers 2‐methyl‐2‐oxazine (MeOZI), 2‐ethyl‐2‐oxazine (EtOZI), and 2‐n‐propyl‐2‐oxazine (nPropOZI) were synthesized and polymerized via the living…”
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6
Metal-Free Cycloaddition of Internal Alkynes and Multifunctional Azides Under Solvent-Free Conditions
Published in Macromolecular chemistry and physics (01-09-2014)“…The synthesis of three different electron‐deficient internal alkynes for the metal‐free 1,3‐dipolar azide–alkyne cycloaddition is shown. The alkynes are…”
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7
A systematic investigation of the effect of side chain branching on the glass transition temperature and mechanical properties of aliphatic (co-)poly(2-oxazoline)s
Published in Polymer (Guilford) (03-04-2013)“…The synthesis of a new branched 2-oxazoline monomer, namely 2-(3-ethylpentyl)-2-oxazoline is described. Microwave-assisted cationic ring-opening polymerization…”
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8
Scale-Up of Microwave-Assisted Polymerizations in Continuous-Flow Mode: Cationic Ring-Opening Polymerization of 2-Ethyl-2-oxazoline
Published in Macromolecular rapid communications. (19-02-2007)“…Microwave‐assisted polymerizations is a growing field of interest because the use of microwave irradiation instead of thermal heating was demonstrated to…”
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9
Synthesis of Poly(2-ethyl-2-oxazoline)-b-poly(styrene) Copolymers via a Dual Initiator Route Combining Cationic Ring-Opening Polymerization and Atom Transfer Radical Polymerization
Published in Macromolecules (22-07-2008)“…Block copolymers of 2-ethyl-2-oxazoline (EtOx) and styrene were synthesized by a combination of cationic ring-opening polymerization (CROP) and atom transfer…”
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10
Scale-up of Microwave-Assisted Polymerizations in Batch Mode: The Cationic Ring-Opening Polymerization of 2-Ethyl-2-oxazoline
Published in Macromolecular rapid communications. (22-09-2006)“…The use of microwave heating in polymer science is a rapidly growing field of research leading to faster and cleaner polymerization procedures. However, the…”
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Journal Article -
11
Synthesis and Structure−Property Relationships of Random and Block Copolymers: A Direct Comparison for Copoly(2-oxazoline)s
Published in Macromolecules (07-08-2007)“…The purpose of this study was to synthesize copolymers of different molecular architecture, i.e., monomer distribution over the polymer chain, and to compare…”
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12
Determination of the relative ligand-binding strengths in heteroleptic Ir(III) complexes by ESI-Q-TOF tandem mass spectrometry
Published in Journal of mass spectrometry. (01-01-2012)“…An electrospray ionization quadrupole time-of-flight mass spectrometer has been utilized to investigate the relative ligand-binding strengths in a series of…”
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13
Systematic parallel investigation of RAFT polymerizations for eight different (meth)acrylates: A basis for the designed synthesis of block and random copolymers
Published in Journal of polymer science. Part A, Polymer chemistry (01-09-2005)“…Poly(acrylate)s as well as poly(methacrylate)s were successfully synthesized via reversible addition‐fragmentation chain‐transfer (RAFT) polymerizations using…”
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14
Determination of the relative ligand-binding strengths in heteroleptic IrIII complexes by ESI-Q-TOF tandem mass spectrometry
Published in Journal of mass spectrometry. (01-01-2012)“…An electrospray ionization quadrupole time‐of‐flight mass spectrometer has been utilized to investigate the relative ligand‐binding strengths in a series of…”
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Journal Article -
15
Thermal Properties of Oligo(2-ethyl-2-oxazoline) Containing Comb and Graft Copolymers and their Aqueous Solutions
Published in Macromolecular symposia. (01-10-2011)“…The cationic ring opening polymerization of 2‐ethyl‐2‐oxazoline (EtOx) was applied for the synthesis of methacrylate end‐functionalized well‐defined…”
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16
Accelerated pressure synthesis and characterization of 2-oxazoline block copolymers
Published in Polymer (Guilford) (03-01-2006)“…The cationic ring-opening polymerization of 2-oxazolines in acetonitrile was investigated under pressure conditions utilizing methyl tosylate as initiator of…”
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17
High-throughput experimentation in synthetic polymer chemistry: From RAFT and anionic polymerizations to process development
Published in Applied surface science (31-01-2006)“…The application of combinatorial and high-throughput approaches in polymer research is described. An overview of the utilized synthesis robots is given,…”
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Journal Article Conference Proceeding -
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Optimization of the nitroxide-mediated radical polymerization conditions for styrene and tert-butyl acrylate in an automated parallel synthesizer
Published in Journal of polymer science. Part A, Polymer chemistry (01-11-2006)“…Automated parallel synthesizers provide fast and comparable screening of different polymerization parameters under similar conditions. In addition, these…”
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19
Concentration effects in the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide
Published in Journal of polymer science. Part A, Polymer chemistry (01-04-2005)“…The monomer concentration for the cationic ring‐opening polymerization of 2‐ethyl‐2‐oxazoline in N,N‐dimethylacetamide was optimized utilizing high‐throughput…”
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20
Protocol for Automated Kinetic Investigation/Optimization of the RAFT Polymerization of Various Monomers
Published in QSAR & combinatorial science (01-08-2008)“…A standard protocol for the parallel optimization of Reversible Addition–Fragmentation Chain Transfer (RAFT) polymerization conditions using an automated…”
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