Search Results - "Pati, Sarah G"
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Increased Use of Quaternary Ammonium Compounds during the SARS-CoV‑2 Pandemic and Beyond: Consideration of Environmental Implications
Published in Environmental science & technology letters (08-09-2020)“…Quaternary ammonium compounds (QACs) are active ingredients in over 200 disinfectants currently recommended by the U.S. EPA for use to inactivate the…”
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Comprehensive screening of quaternary ammonium surfactants and ionic liquids in wastewater effluents and lake sediments
Published in Environmental science--processes & impacts (26-02-2020)“…Quaternary ammonium compounds (QACs) are widely applied as surfactants and biocides in cleaning and personal-care products. Because of incomplete removal…”
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Isotope Effects as New Proxies for Organic Pollutant Transformation
Published in Chimia (01-11-2014)“…Assessing the pathways and rates of organic pollutant transformation in the environment is a major challenge due to co-occurring transport and degradation…”
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Managing argon interference during measurements of 18O/16O ratios in O2 by continuous-flow isotope ratio mass spectrometry
Published in Analytical and bioanalytical chemistry (01-08-2022)“…Monitoring changes in stable oxygen isotope ratios in molecular oxygen allows for studying many fundamental processes in bio(geo)chemistry and environmental…”
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Photochemical Transformation of Four Ionic Liquid Cation Structures in Aqueous Solution
Published in Environmental science & technology (17-10-2017)“…Ionic liquids (ILs) are a new class of solvents expected to be used increasingly by the chemical industry in the coming years. Given their slow biodegradation…”
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Improving the accuracy of δ 18 O and δ 17 O values of O 2 measured by continuous-flow isotope-ratio mass spectrometry with a multipoint isotope-ratio calibration
Published in Rapid communications in mass spectrometry (15-01-2024)“…Stable isotope analysis of O is a valuable tool to identify O -consuming processes in the environment; however, reference materials for O isotope analysis are…”
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Improving the accuracy of δ18O and δ17O values of O2 measured by continuous‐flow isotope‐ratio mass spectrometry with a multipoint isotope‐ratio calibration
Published in Rapid communications in mass spectrometry (15-01-2024)“…Rationale Stable isotope analysis of O2 is a valuable tool to identify O2‐consuming processes in the environment; however, reference materials for O2 isotope…”
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Substrate-Specific Coupling of O2 Activation to Hydroxylations of Aromatic Compounds by Rieske Non-heme Iron Dioxygenases
Published in ACS catalysis (03-06-2022)“…Rieske dioxygenases catalyze the initial steps in the hydroxylation of aromatic compounds and are critical for the metabolism of xenobiotic substances. Because…”
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Substrate-Specific Coupling of O 2 Activation to Hydroxylations of Aromatic Compounds by Rieske Non-heme Iron Dioxygenases
Published in ACS catalysis (03-06-2022)“…Rieske dioxygenases catalyze the initial steps in the hydroxylation of aromatic compounds and are critical for the metabolism of xenobiotic substances. Because…”
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Substrate and Enzyme Specificity of the Kinetic Isotope Effects Associated with the Dioxygenation of Nitroaromatic Contaminants
Published in Environmental science & technology (05-07-2016)“…Compound-specific isotope analysis (CSIA) is a promising approach for tracking biotransformation of organic pollutants, but isotope fractionation associated…”
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Characterization of Substrate, Cosubstrate, and Product Isotope Effects Associated With Enzymatic Oxygenations of Organic Compounds Based on Compound-Specific Isotope Analysis
Published in Methods in enzymology (2017)“…Enzymatic oxygenations are among the most important biodegradation and detoxification reactions of organic pollutants. In the environment, however, such…”
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Exploring Trends of C and N Isotope Fractionation to Trace Transformation Reactions of Diclofenac in Natural and Engineered Systems
Published in Environmental science & technology (18-10-2016)“…Although diclofenac ranks among the most frequently detected pharmaceuticals in the urban water cycle, its environmental transformation reactions remain…”
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Isotope Effects of Enzymatic Dioxygenation of Nitrobenzene and 2‑Nitrotoluene by Nitrobenzene Dioxygenase
Published in Environmental science & technology (16-09-2014)“…Oxygenation of aromatic rings is a frequent initial step in the biodegradation of persistent contaminants, and the accompanying isotope fractionation is…”
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Carbon, Hydrogen, and Nitrogen Isotope Fractionation Associated with Oxidative Transformation of Substituted Aromatic N-Alkyl Amines
Published in Environmental science & technology (03-07-2012)“…We investigated the mechanisms and isotope effects associated with the N-dealkylation and N-atom oxidation of substituted N-methyl- and N,N-dimethylanilines to…”
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Carbon and Nitrogen Isotope Effects Associated with the Dioxygenation of Aniline and Diphenylamine
Published in Environmental science & technology (06-11-2012)“…Dioxygenation of aromatic rings is frequently the initial step of biodegradation of organic subsurface pollutants. This process can be tracked by…”
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Measurement of oxygen isotope ratios (18O/16O) of aqueous O2 in small samples by gas chromatography/isotope ratio mass spectrometry
Published in Rapid communications in mass spectrometry (30-03-2016)“…Rationale Oxygen isotope fractionation of molecular O2 is an important process for the study of aerobic metabolism, photosynthesis, and formation of reactive…”
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Perspectives of compound-specific isotope analysis of organic contaminants for assessing environmental fate and managing chemical pollution
Published in Nature water (17-01-2024)“…The management and mitigation of chemical pollution are key elements of sustainable development initiatives that aim to provide safe and clean water. While…”
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Managing argon interference during measurements of .sup.18O/.sup.16O ratios in O.sub.2 by continuous-flow isotope ratio mass spectrometry
Published in Analytical and bioanalytical chemistry (01-08-2022)“…Monitoring changes in stable oxygen isotope ratios in molecular oxygen allows for studying many fundamental processes in bio(geo)chemistry and environmental…”
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Characterization of O 2 uncoupling in biodegradation reactions of nitroaromatic contaminants catalyzed by rieske oxygenases
Published in Methods in enzymology (2024)“…Rieske oxygenases are known as catalysts that enable the cleavage of aromatic and aliphatic C-H bonds in structurally diverse biomolecules and recalcitrant…”
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Measurement of oxygen isotope ratios ( 18 O/ 16 O) of aqueous O 2 in small samples by gas chromatography/isotope ratio mass spectrometry
Published in Rapid communications in mass spectrometry (30-03-2016)“…Rationale Oxygen isotope fractionation of molecular O 2 is an important process for the study of aerobic metabolism, photosynthesis, and formation of reactive…”
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