Search Results - "Pasta, Piero"
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Comparison of cyclohexanone monooxygenase as an isolated enzyme and whole cell biocatalyst for the enantioselective oxidation of 1,3-dithiane
Published in Journal of molecular catalysis. B, Enzymatic (01-12-2004)“…Both whole cells of recombinant Escherichia coli TOP10, overexpressing cyclohexanone monooxygenase (CHMO) and isolated cyclohexanone monooxygenase, were used…”
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Recent biotechnological developments in the use of peroxidases
Published in Trends in Biotechnology (01-04-1999)“…Peroxidases are ubiquitous oxidoreductases that use hydrogen peroxide or alkyl peroxides as oxidants. Advances have recently been made in using them to…”
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Book Review Journal Article -
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First asymmetric epoxidation catalysed by cyclohexanone monooxygenase
Published in Tetrahedron letters (04-03-2002)Get full text
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Oxidation of secondary amines by molecular oxygen and cyclohexanone monooxygenase
Published in Tetrahedron (01-01-2004)“…Cyclohexanone monooxygenase from Acinetobacter calcoaceticus catalyzed the oxidation of tertiary and secondary amines to N-oxides and nitrones, respectively…”
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Oxidation of amines catalyzed by cyclohexanone monooxygenase
Published in Tetrahedron letters (20-01-2003)“…Cyclohexanone monooxygenase catalyzed the oxidation of tertiary, secondary and hydroxylamines to N-oxides, hydroxylamines and nitrones respectively…”
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Microbiological transformations 36: Preparative scale synthesis of chiral thioacetal and thioketal sulfoxides using whole-cell biotransformations
Published in Tetrahedron (14-07-1997)“…This work describes the preparative scale enantioselective oxidation of some prochiral dithioacetals and dithioketals to their corresponding chiral…”
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Chloroperoxidase-catalyzed enantioselective oxidation of methyl phenyl sulfide with dihydroxyfumaric acid/oxygen or ascorbic acid/oxygen as oxidants
Published in Biotechnology and bioengineering (20-02-1999)“…The chloroperoxidase catalyzed oxidation of methyl phenyl sulfide to (R)‐methyl phenyl sulfoxide was investigated, both in batch and membrane reactors, using…”
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A predictive active site model for the cyclohexanone monooxygenase catalyzed oxidation of sulfides to chiral sulfoxides
Published in Tetrahedron: asymmetry (01-06-1995)“…An active site model to explain and predict the stereoselectivity of the sultoxidation of organic sulfides to optically active sulfoxides catalyzed by…”
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Enantioselective synthesis of tert-butyl tert-butanethiosulfinate catalyzed by cyclohexanone monooxygenase
Published in Chirality (New York, N.Y.) (2001)“…Cyclohexanone monooxygenase from Acinetobacter calcoaceticus catalyzes the asymmetric oxidation of tert‐butyl disulfide to enantiomerically pure (R)‐tert‐butyl…”
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Enantio and diastereoselectivity of cyclohexanone monooxygenase catalyzed oxidation of 1,3-dithioacetals
Published in Tetrahedron: asymmetry (01-02-1996)“…The asymmetric oxidation of 2-substituted dithianes, dithiolanes and oxathiolanes catalyzed by cyclohexanone monooxygenase (CMO) has been examined. The…”
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Enantioselective synthesis oftert-butyltert-butanethiosulfinate catalyzed by cyclohexanone monooxygenase
Published in Chirality (New York, N.Y.) (2001)Get full text
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Active site model of cyclohexanone monooxygenase. 3. The case of benzyl sulfides bearing polar groups
Published in Tetrahedron: asymmetry (01-12-1996)“…The stereopreference of cyclohexanone monooxygenase for a series of benzyl methyl sulfides bearing in the p-position groups with different σ p values has been…”
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Sulphoxidation reaction catalysed by myeloperoxidase from human leucocytes
Published in Biochemical journal (01-10-1998)“…The oxidation of alkyl aryl sulphides by myeloperoxidase (MPO) at the expense of hydrogen peroxide was investigated under steady-state conditions. The sulphide…”
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Synthetic applications of NAD(P)(H)-dependent enzymes
Published in Annals of the New York Academy of Sciences (01-10-1996)Get more information
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Synthesis of chiral benzyl alkyl sulfoxides by cyclohexanone monooxygenase from Acinetobacter NCIB 9871
Published in Tetrahedron: asymmetry (01-04-1995)“…Benzyl alkyl sulfides with alkyl groups from methyl to hexyl, para-alkylbenzyl groups from methyl to butyl, 2-phenylethyl methyl sulfide and 3-phenylpropyl…”
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Enantioselective oxidations catalyzed by diketocamphane monooxygenase from Pseudomonas Putida with macromolecular NAD in a membrane reactor
Published in Biotechnology letters (01-10-1996)“…Several sulfides and bicyclo[3.2.0]hept-2-en-6-one were enantioselectively oxidized to the corresponding sulfoxides and oxa lactones by a crude preparation of…”
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Fourier-transform infrared conformational study of bovine insulin in surfactant solutions
Published in International journal of peptide and protein research (01-08-1996)“…To obtain conformational data on the monomeric form of insulin, which is believed to be the physiologically active form of the hormone, insulin in sodium…”
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Effects of chloride on the kinetics and stereochemistry of chloroperoxidase catalyzed oxidation of sulfides
Published in Biochimica et biophysica acta (14-12-1994)“…At pH 3, chloride dramatically influenced both the Km of chloroperoxidase (CPO) for methyl p-tolyl sulfide, which decreased, and its activity, which increased…”
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