Search Results - "Parrott, Andrew J"
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Biobased Epoxy Thermoset Polymers from Depolymerized Native Hardwood Lignin
Published in ACS macro letters (18-08-2020)“…Biobased epoxy thermoset polymers were prepared from lignin hydrogenolysis oils produced from native hardwood lignin. Native lignin in Eucalyptus nitens and…”
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Reaction Monitoring Using SABRE-Hyperpolarized Benchtop (1 T) NMR Spectroscopy
Published in Analytical chemistry (Washington) (21-05-2019)“…The conversion of [IrCl(COD)(IMes)] (COD = cis,cis-1,5-cyclooctadiene, IMes = 1,3-bis(2,4,6-trimethyl-phenyl)imidazole-2-ylidene) in the presence of an…”
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Self-Optimizing Continuous Reactions in Supercritical Carbon Dioxide
Published in Angewandte Chemie International Edition (11-04-2011)“…Hands‐free optimization: A combination of an automated flow reactor, online analysis, and a control algorithm leads to efficient optimization of reactions to a…”
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A simple hand‐held magnet array for efficient and reproducible SABRE hyperpolarisation using manual sample shaking
Published in Magnetic resonance in chemistry (01-07-2018)“…Signal amplification by reversible exchange (SABRE) is a hyperpolarisation technique that catalytically transfers nuclear polarisation from parahydrogen, the…”
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Temperature Correction of Spectra to Improve Solute Concentration Monitoring by In Situ Ultraviolet and Mid-Infrared Spectrometries toward Isothermal Local Model Performance
Published in Organic process research & development (18-11-2022)“…Changes in temperature can significantly affect spectroscopic-based methods for in situ monitoring of processes. As varying temperature is inherent to many…”
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Real-Time Feedback Control Using Online Attenuated Total Reflection Fourier Transform Infrared (ATR FT-IR) Spectroscopy for Continuous Flow Optimization and Process Knowledge
Published in Applied spectroscopy (01-10-2013)“…The use of automated continuous flow reactors is described, with real-time online Fourier transform infrared spectroscopy (FT-IR) analysis to enable rapid…”
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Quantitative In Situ Monitoring of Parahydrogen Fraction Using Raman Spectroscopy
Published in Applied spectroscopy (01-01-2019)“…Raman spectroscopy has been used to provide a rapid, noninvasive, and nondestructive quantification method for determining the parahydrogen fraction of…”
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Adaptive Process Optimization for Continuous Methylation of Alcohols in Supercritical Carbon Dioxide
Published in Organic process research & development (15-07-2011)“…A self-optimizing continuous flow reactor has been developed using the Super-Modified Simplex algorithm. This system, coupled with online gas chromatographic…”
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Continuous Acid-Catalyzed Methylations in Supercritical Carbon Dioxide: Comparison of Methanol, Dimethyl Ether and Dimethyl Carbonate as Methylating Agents
Published in Organic process research & development (19-03-2010)“…The development of high-yielding, “greener” chemistry-based routes for the continuous synthesis of methyl ethers are reported in this study. Ethers have been…”
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The Continuous Acid-Catalysed Etherification of Aliphatic Alcohols Using Stoichiometric Quantities of Dialkyl Carbonates
Published in Organic process research & development (19-11-2010)“…A range of methyl and ethyl ethers of aliphatic alcohols have been synthesized cleanly in high yield by reacting the corresponding alcohol with dimethyl…”
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Pocket-size near-IR spectrometers for rapid examination of contaminated textile fibres at the crime-scene
Published in Vibrational spectroscopy (01-11-2022)“…In a typical forensic investigation, fabric analysis plays a vital role in solving different crimes. Several types of textile fibre materials (cotton,…”
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Self‐Optimizing Continuous Reactions in Supercritical Carbon Dioxide
Published in Angewandte Chemie (11-04-2011)Get full text
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The Effect of Self-Optimisation Targets on the Methylation of Alcohols Using Dimethyl Carbonate in Supercritical CO2
Published in Journal of flow chemistry (2012)“…This paper describes the next stage in our development of self-optimising reactors. We demonstrate that the same reaction can be optimised for a series of…”
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Self-Optimizing Continuous Reactions in Supercritical Carbon Dioxide
Published in Angewandte Chemie (11-04-2011)“…Vollautomatisch: Mit einer Kombination aus automatisiertem Flussreaktor, Online‐Analyse und Steuerungsalgorithmus (siehe schematischen Aufbau) gelingt die…”
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