Search Results - "Parkin, Alison"
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Methodologies for “Wiring” Redox Proteins/Enzymes to Electrode Surfaces
Published in Chemistry : a European journal (22-08-2018)“…The immobilization of redox proteins or enzymes onto conductive surfaces has application in the analysis of biological processes, the fabrication of…”
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Investigating and Exploiting the Electrocatalytic Properties of Hydrogenases
Published in Chemical reviews (01-10-2007)“…The electrocatalytic properties of hydrogenases are investigated. The application of these properties to the development of fuel cells and other alternative…”
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Photocatalytic Deoxygenation of Sulfoxides Using Visible Light: Mechanistic Investigations and Synthetic Applications
Published in ACS catalysis (15-05-2020)“…The photocatalytic deoxygenation of sulfoxides to generate sulfides facilitated by either Ir[(dF(CF3)ppy)2(dtbbpy)]PF6 or fac-Ir(ppy)3 is reported…”
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Retuning the Catalytic Bias and Overpotential of a [NiFe]-Hydrogenase via a Single Amino Acid Exchange at the Electron Entry/Exit Site
Published in Journal of the American Chemical Society (09-08-2017)“…The redox chemistry of the electron entry/exit site in Escherichia coli hydrogenase-1 is shown to play a vital role in tuning biocatalysis. Inspired by nature,…”
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X-ray crystallographic and computational studies of the O₂-tolerant [NiFe]-hydrogenase 1 from Escherichia coli
Published in Proceedings of the National Academy of Sciences - PNAS (03-04-2012)“…The crystal structure of the membrane-bound O₂-tolerant [NiFe]-hydrogenase 1 from Escherichia coli (EcHyd-1) has been solved in three different states:…”
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The electrophotonic silicon biosensor
Published in Nature communications (14-09-2016)“…The emergence of personalized and stratified medicine requires label-free, low-cost diagnostic technology capable of monitoring multiple disease biomarkers in…”
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How Escherichia coli Is Equipped to Oxidize Hydrogen under Different Redox Conditions
Published in The Journal of biological chemistry (05-02-2010)“…The enterobacterium Escherichia coli synthesizes two H₂ uptake enzymes, Hyd-1 and Hyd-2. We show using precise electrochemical kinetic measurements that the…”
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Dynamic electrochemical investigations of hydrogen oxidation and production by enzymes and implications for future technology
Published in Chemical Society reviews (01-01-2009)“…This tutorial review describes studies of hydrogen production and oxidation by biological catalysts--metalloenzymes known as hydrogenases--attached to…”
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Electrochemical evidence that pyranopterin redox chemistry controls the catalysis of YedY, a mononuclear Mo enzyme
Published in Proceedings of the National Academy of Sciences - PNAS (24-11-2015)“…A long-standing contradiction in the field of mononuclear Mo enzyme research is that small-molecule chemistry on active-site mimic compounds predicts ligand…”
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Rapid and Efficient Electrocatalytic CO2/CO Interconversions by Carboxydothermus hydrogenoformans CO Dehydrogenase I on an Electrode
Published in Journal of the American Chemical Society (29-08-2007)“…The Ni-containing carbon monoxide dehydrogenase I from Carboxydothermus hydrogenoformans adsorbed on a pyrolytic graphite “edge” electrode catalyzes rapid…”
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Characteristics of Enzyme-Based Hydrogen Fuel Cells Using an Oxygen-Tolerant Hydrogenase as the Anodic Catalyst
Published in Journal of physical chemistry. C (15-07-2010)“…The special properties of O2-tolerant [NiFe]-hydrogenases make it possible, in principle, to operate all-enzyme hydrogen fuel cells. These devices show unusual…”
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How the structure of the large subunit controls function in an oxygen-tolerant [NiFe]-hydrogenase
Published in Biochemical journal (15-03-2014)“…Salmonella enterica is an opportunistic pathogen that produces a [NiFe]-hydrogenase under aerobic conditions. In the present study, genetic engineering…”
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Mannose-Presenting “Glyco-Colicins” Convert the Bacterial Cell Surface into a Multivalent Adsorption Site for Adherent Bacteria
Published in JACS Au (24-06-2024)“…Biofilm formation is integral to the pathogenesis of numerous adherent bacteria and contributes to antimicrobial resistance (AMR). The rising threat of AMR…”
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Structural dissection of two redox proteins from the shipworm symbiont Teredinibacter turnerae
Published in IUCrJ (01-03-2024)“…The discovery of lytic polysaccharide monooxygenases (LPMOs), a family of copper-dependent enzymes that play a major role in polysaccharide degradation, has…”
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The Antimicrobial Activity of a Carbon Monoxide Releasing Molecule (EBOR-CORM-1) Is Shaped by Intraspecific Variation within Pseudomonas aeruginosa Populations
Published in Frontiers in microbiology (08-02-2018)“…Carbon monoxide releasing molecules (CORMs) have been suggested as a new synthetic class of antimicrobials to treat bacterial infections. Here we utilized a…”
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Practical Guide to Large Amplitude Fourier-Transformed Alternating Current VoltammetryWhat, How, and Why
Published in ACS measurement science au (21-08-2024)“…Fourier-transformed alternating current voltammetry (FTacV) is a technique utilizing a combination of a periodic (frequently sinusoidal) oscillation…”
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A Voltammetric Perspective of Multi-Electron and Proton Transfer in Protein Redox Chemistry: Insights From Computational Analysis of Escherichia coli HypD Fourier Transformed Alternating Current Voltammetry
Published in Frontiers in chemistry (14-06-2021)“…This paper explores the impact of pH on the mechanism of reversible disulfide bond (CysS-SCys) reductive breaking and oxidative formation in Escherichia coli…”
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Water−Gas Shift Reaction Catalyzed by Redox Enzymes on Conducting Graphite Platelets
Published in Journal of the American Chemical Society (14-10-2009)“…The water−gas shift (WGS) reaction (CO + H2O ⇆ CO2 + H2) is of major industrial significance in the production of H2 from hydrocarbon sources. High…”
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Electrochemical Investigations of the Interconversions between Catalytic and Inhibited States of the [FeFe]-Hydrogenase from Desulfovibrio desulfuricans
Published in Journal of the American Chemical Society (27-12-2006)“…Studies of the catalytic properties of the [FeFe]-hydrogenase from Desulfovibrio desulfuricans by protein film voltammetry, under a H2 atmosphere, reveal and…”
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