Search Results - "Parker, Kyle D. J"

Synthesis, Structure, and Reactivity of Niobium and Tantalum Alkyne Complexes by Parker, Kyle D. J, Fryzuk, Michael D

“…This review focuses on niobium and tantalum organometallic complexes that feature a metal-bound alkyne (RCCR) unit. The contrasting…”
Get full text

Synthesis, Characterization, and Ligand Rearrangement of Tungsten Cyclopropyl Complexes by Parker, Kyle D. J, Vendier, Laure, Etienne, Michel

“…In an effort to study the β-H abstraction/1,3-addition mechanism for CH bond activation, the syntheses of tungsten organometallic complexes featuring a…”
Get full text

Allyl Complexes of Tungsten from the Rearrangement of Transient Cyclopropyl Precursors by Parker, Kyle D. J., Labat, Stéphane, Sotiropoulos, Jean‐Marc, Miqueu, Karinne, Pimienta, Véronique, Vendier, Laure, Etienne, Michel

“…This article explores the contrasting reactivity of cyclopropyl complexes of early transition metals. [Cp*W(NO)(CH2R)(c‐C3H5)] (R = SiMe3, Ph, t‐Bu) generated…”
Get full text

Carbon–Carbon Bond Forming Reactions with Tantalum Diamidophosphine Complexes That Incorporate Alkyne Ligands by Parker, Kyle D. J, Fryzuk, Michael D

“…The incorporation of o-phenylene-linked diamidophosphine ligands onto the readily available alkyne complexes Ta(alkyne)Cl3(DME) (where alkyne = hex-3-yne or…”
Get full text

Hydrogenolysis of Tantalum Hydrocarbyl Complexes: Intermediates on the Road to a Dinuclear Tantalum Tetrahydride Derivative by Parker, Kyle D. J, Nied, Dominik, Fryzuk, Michael D

“…The synthesis, characterization, and reactivity with H2 of a series of tantalum hydrocarbyl complexes are reported. The reaction of [NPN*]­TaMe3 (4, where NPN*…”
Get full text