Search Results - "Parker, Christian R."
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Downstream Processability of Crystal Habit-Modified Active Pharmaceutical Ingredient
Published in Organic process research & development (21-04-2017)“…Efficient downstream processing of active pharmaceutical ingredients (APIs) can depend strongly on their particulate properties, such as size and shape…”
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Tracking molecular resonance forms of donor–acceptor push–pull molecules by single-molecule conductance experiments
Published in Nature communications (15-12-2015)“…The ability of molecules to change colour on account of changes in solvent polarity is known as solvatochromism and used spectroscopically to characterize…”
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3
A Comprehensive Study of Extended Tetrathiafulvalene Cruciform Molecules for Molecular Electronics: Synthesis and Electrical Transport Measurements
Published in Journal of the American Chemical Society (26-11-2014)“…Cruciform-like molecules with two orthogonally placed π-conjugated systems have in recent years attracted significant interest for their potential use as…”
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Interactions between tetrathiafulvalene units in dimeric structures - the influence of cyclic cores
Published in Beilstein journal of organic chemistry (02-06-2015)“…A selection of cyclic and acyclic acetylenic scaffolds bearing two tetrathiafulvalene (TTF) units was prepared by different metal-catalyzed coupling reactions…”
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5
On the bromination of the dihydroazulene/vinylheptafulvene photo-/thermoswitch
Published in Beilstein journal of organic chemistry (27-06-2012)“…The dihydroazulene (DHA)/vinylheptafulvene (VHF) system (with two cyano groups at C1) functions as a photo-/thermoswitch. Direct ionic bromination of DHA has…”
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6
Molecular Heterojunctions of Oligo(phenylene ethynylene)s with Linear to Cruciform Framework
Published in Advanced functional materials (01-03-2015)“…Electrical transport properties of molecular junctions are fundamentally affected by the energy alignment between molecular frontier orbitals (highest occupied…”
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The Gilded Edge in Acetylenic Scaffolding: Pd-Catalyzed Cross-Coupling Reactions of Phosphine–Gold(I) Oligoynyl Complexes
Published in Organic letters (18-07-2014)“…Stable bis(gold(I) alkynyl) complexes of tetraethynylethene (TEE) derivatives were readily prepared and employed in Sonogashira-like palladium-catalyzed…”
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Multistate Switches: Ruthenium Alkynyl-Dihydroazulene/Vinylheptafulvene Conjugates
Published in Chemistry : a European journal (23-05-2016)“…Multimode molecular switches incorporating distinct and independently addressable functional components have potential applications as advanced switches and…”
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Some Ruthenium Derivatives of Penta-1,4-diyn-3-one
Published in Organometallics (10-06-2013)“…The reaction between Ru(CCH)(dppe)Cp* (1) and oxalyl chloride affords ({Ru(dppe)Cp*}CC)2CO (2) in 72% yield. Methylation (MeOTf) of 2 occurs first on the…”
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Phosphite-mediated conversion of benzaldehydes into stilbenes via umpolung through a dioxaphospholane intermediate
Published in Tetrahedron letters (01-04-2015)“…[Display omitted] The phosphite-mediated coupling of two benzaldehydes into 2,2,2-triethoxy-1,3,2-dioxaphospholanes was investigated using 13C NMR spectroscopy…”
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11
The series of carbon-chain complexes {Ru(dppe)Cp∗}2{μ-(CC)x} (x=4–8, 11): Synthesis, structures, properties and some reactions
Published in Polyhedron (28-01-2015)“…Pd(0)/Cu(I)-catalysed reactions between iodo- or diiodo-alkynes and (phosphine)gold-substituted alkynyl-ruthenium complexes have given {Ru(dppe)Cp∗}2{ μ…”
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12
Reactions of 7,7,8,8-Tetracyanoquinodimethane with Poly-ynyl Ruthenium and Iron Complexes
Published in Organometallics (24-09-2012)“…The reaction of tetracyanoquinodimethane (TCNQ) with Ru(CCCCH)(dppe)Cp* (5) at the outer (from Ru) CC triple bond gives η1-(butadienyl)ethynyl…”
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Synthesis and Some Reactions of the Heterometallic C7 Complex {Cp(dppe)Ru}CCCCCCC{Co3(μ-dppm)(CO)7}
Published in Organometallics (28-07-2008)“…The heterometallic carbon-chain complex {Cp*(dppe)Ru}CCCCCCC{Co3(μ-dppm)(CO)7} (1) has been obtained by three routes that involve assembly of the C7 chain…”
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14
Facile Decarboxylation of Propiolic Acid on a Ruthenium Center and Related Chemistry
Published in Organometallics (13-08-2012)“…Spontaneous decarboxylation of RCCCO2H (R = H, Ph) occurs in reactions with RuCl(PP)Cp (PP = (PPh3)2, dppe) to give [Ru(CCHR)(PP)Cp]+. Computational studies…”
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Tuning crystal polymorphs of a π-extended tetrathiafulvalene-based cruciform molecule towards high-performance organic field-effect transistors
Published in Science China materials (2017)“…It is a common phenomenon for organic semiconductors to crystallize in two or more polymorphs, leading to various molecular packings and different charge…”
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Substitution of Tetracyanoethene by Ethynyl–Metal Complexes Gives Tricyanovinylethynyl (Tricyanobutenynyl) Derivatives: Syntheses, Protonation, and Addition of Metal–Ligand Fragments
Published in Organometallics (09-04-2012)“…A series of complexes containing the new tricyanovinylethynyl (3,4,4-tricyanobut-3-en-1-ynyl) ligand have been obtained by substitution of a CN group in…”
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Polarized Complexes Obtained by Regiospecific Substitution of a CN Group in Ru{CCC(CN)C(CN)2}(dppe)Cp (Cp = η-C5Me5)
Published in Organometallics (11-06-2012)“…The complex Ru{CCC(CN)C(CN)2}(dppe)Cp* (1), containing the new tricyanovinylethynyl (3,4,4-tricyanobut-3-en-1-ynyl) ligand, undergoes ready substitution of…”
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Bis(metallaethynyl) Ketones: Synthesis and Structure of {(Ph3P)AuCC}2CO and Attempted Transmetalation: Formation and Structure of [1,3-{Ru(dppe)Cp}2{c-COC(OMe)CHCCH}]PF6
Published in Organometallics (24-10-2011)“…The bis(metallaethynyl) ketone {(Ph3P)AuCC}2CO (1), obtained from (Me3SiCC)2CO, AuCl(PPh3), and NaOMe, forms an Au···Au-bonded dimer in the solid state…”
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19
Synthesis and Some Reactions of the Heterometallic C 7 Complex {Cp(dppe)Ru}C≡CC≡CC≡CC{Co 3 (μ-dppm)(CO) 7 }
Published in Organometallics (28-07-2008)Get full text
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Some reactions of azides with diynyl-bis(phosphine)ruthenium-cyclopentadienyl complexes
Published in Journal of organometallic chemistry (15-11-2015)“…Reactions of SiMe3(N3) with Ru(CCH)(PP)Cp’ [PP = (PPh3)2, Cp′ = Cp; PP = dppe, Cp′ = Cp*] afford Ru(N3)(PP)Cp′. Reactions of Ru(CCCCR)(dppe)Cp* with SiMe3(N3)…”
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