Search Results - "Parker, Bernard F."
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Selective Nickel-Catalyzed Hydrodefluorination of Amides Using Sodium Borohydride
Published in Journal of organic chemistry (05-08-2022)“…Hydrodefluorination selective to the ortho position to amides is accomplished under mild conditions using sodium borohydride and a nickel catalyst. The facile…”
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2
Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater
Published in Nature communications (16-11-2017)“…Amidoxime-functionalized polymeric adsorbents are the current state-of-the-art materials for collecting uranium (U) from seawater. However, marine tests show…”
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3
Siderophore-inspired chelator hijacks uranium from aqueous medium
Published in Nature communications (18-02-2019)“…Over millennia, nature has evolved an ability to selectively recognize and sequester specific metal ions by employing a wide variety of supramolecular…”
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4
Reactivity of terminal imido complexes of group 4–6 metals: Stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules
Published in Coordination chemistry reviews (15-03-2020)“…•Summary of the synthesis, properties, and reactions of early metal imido complexes.•Cycloaddition reactions of model complexes and examples from recent…”
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α‑Diimine-Niobium Complex-Catalyzed Deoxychlorination of Benzyl Ethers with Silicon Tetrachloride
Published in Inorganic chemistry (07-10-2019)“…α-Diimine niobium complexes serve as catalysts for deoxygenation of benzyl ethers by silicon tetrachloride (SiCl4) to cleanly give two equivalents of the…”
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6
Thorium Metallacycle Facilitates Catalytic Alkyne Hydrophosphination
Published in Journal of the American Chemical Society (20-09-2017)“…The bis(NHC)borate-supported thorium-bis(mesitylphosphido) complex (1) undergoes reversible intramolecular C–H bond activation enabling the catalytic…”
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7
A Homoleptic Uranium(III) Tris(aryl) Complex
Published in Journal of the American Chemical Society (14-12-2016)“…The reaction of 3 equiv of Li–C6H3-2,6-(C6H4-4- t Bu)2 (Terph–Li) with UI3(1,4-dioxane)1.5 led to the formation of the homoleptic uranium(III) tris(aryl)…”
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8
Solution Thermodynamics and Kinetics of Metal Complexation with a Hydroxypyridinone Chelator Designed for Thorium-227 Targeted Alpha Therapy
Published in Inorganic chemistry (19-11-2018)“…The solution chemistry of a chelator developed for 227Th targeted alpha therapy was probed. The compound of interest is an octadentate ligand comprising four…”
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Thermodynamic, Structural, and Computational Investigation on the Complexation between UO22+ and Amine-Functionalized Diacetamide Ligands in Aqueous Solution
Published in Inorganic chemistry (19-02-2018)“…The stability constants (log β), enthalpies of complexation (ΔH), and entropies of complexation (ΔS) for the complexes of uranium(VI) with a series of…”
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10
Complexation of NpO2 + with Amine-Functionalized Diacetamide Ligands in Aqueous Solution: Thermodynamic, Structural, and Computational Studies
Published in Inorganic chemistry (18-06-2018)“…Complexation of Np(V) with three structurally related amine-functionalized diacetamide ligands, including 2,2′-azanediylbis(N,N′-dimethylacetamide) (ABDMA),…”
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11
A Peptoid-Based Combinatorial and Computational Approach to Developing Ligands for Uranyl Sequestration from Seawater
Published in Industrial & engineering chemistry research (20-04-2016)“…The selective binding of uranyl for extraction from seawater by using polymer sorbents holds promise as a sustainable source of uranium for nuclear energy. A…”
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12
Coordination of 2,2′-(Trifluoroazanediyl)bis(N,N′‑dimethylacetamide) with U(VI), Nd(III), and Np(V): A Thermodynamic and Structural Study
Published in Inorganic chemistry (02-12-2019)“…Thermodynamic properties of the complexation of 2,2′-(trifluoroazanediyl)bis(N,N′-dimethylacetamide) (CF3ABDMA) with U(VI), Nd(III), and Np(V) have been…”
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13
Complexation of NpO 2 + with Amine-Functionalized Diacetamide Ligands in Aqueous Solution: Thermodynamic, Structural, and Computational Studies
Published in Inorganic chemistry (18-06-2018)“…Complexation of Np(V) with three structurally related amine-functionalized diacetamide ligands, including 2,2'-azanediylbis( N, N'-dimethylacetamide) (ABDMA),…”
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14
VIVO and VIV Species Formed in Aqueous Solution by the Tridentate Glutaroimide–Dioxime Ligand – An Instrumental and Computational Characterization
Published in European journal of inorganic chemistry (08-05-2018)“…Complexation of VIV in aqueous solution with glutaroimide–dioxime (H3L), a ligand proposed for the possible sequestration of uranium from seawater, was studied…”
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Thermodynamic, Structural, and Computational Investigation on the Complexation between UO 2 2+ and Amine-Functionalized Diacetamide Ligands in Aqueous Solution
Published in Inorganic chemistry (19-02-2018)“…The stability constants (log β), enthalpies of complexation (ΔH), and entropies of complexation (ΔS) for the complexes of uranium(VI) with a series of…”
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16
V IV O and V IV Species Formed in Aqueous Solution by the Tridentate Glutaroimide–Dioxime Ligand – An Instrumental and Computational Characterization
Published in European journal of inorganic chemistry (08-05-2018)“…Complexation of V IV in aqueous solution with glutaroimide–dioxime (H 3 L), a ligand proposed for the possible sequestration of uranium from seawater, was…”
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17
Thermodynamic, Structural, and Computational Investigation on the Complexation between UO2 2+ and Amine-Functionalized Diacetamide Ligands in Aqueous Solution
Published in Inorganic chemistry (19-02-2018)“…The stability constants (log β), enthalpies of complexation (ΔH), and entropies of complexation (ΔS) for the complexes of uranium(VI) with a series of…”
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