Search Results - "Parida, Keshaba N"

λ3‐ and λ5‐Iodanes: Substituent Effects and Pseudorotation/Hypervalent Twisting by Parida, Keshaba N., Moorthy, J. Narasimha

“…Hypervalent iodine (III and V) compounds exhibit positional isomerization through pseudorotation or twisting; the latter have been invoked for the stability as…”
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Enolonium Species—Umpoled Enolates by Arava, Shlomy, Kumar, Jayprakash N., Maksymenko, Shimon, Iron, Mark A., Parida, Keshaba N., Fristrup, Peter, Szpilman, Alex M.

“…Enolonium species/iodo(III)enolates of carbonyl compounds have been suggested to be intermediates in a wide variety of hypervalent iodine induced chemical…”
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Cross-coupling of dissimilar ketone enolates via enolonium species to afford non-symmetrical 1,4-diketones by Parida, Keshaba N, Pathe, Gulab K, Maksymenko, Shimon, Szpilman, Alex M

“…Due to their closely matched reactivity, the coupling of two dissimilar ketone enolates to form a 1,4-diketone remains a challenge in organic synthesis. We…”
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Oxidation of Thiols with IBX or DMP: One-Pot Access to Thiosulfonates or 2‑Iodobenzoates and Applications in Functional Group Transformations by Chandra, Ajeet, Yadav, Navin, Payra, Soumen, Parida, Keshaba N.

“…o-Iodoxybenzoic acid (IBX) and Dess–Martin periodinane (DMP) are employed for thiol to thiosulfonate conversion at rt. DMP is better than IBX in terms of…”
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λ 3 - and λ 5 -Iodanes: Substituent Effects and Pseudorotation/Hypervalent Twisting by Parida, Keshaba N, Moorthy, J Narasimha

“…Hypervalent iodine (III and V) compounds exhibit positional isomerization through pseudorotation or twisting; the latter have been invoked for the stability as…”
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Unsupervised Segmentation-Based Machine Learning as an Advanced Analysis Tool for Single Molecule Break Junction Data by Bamberger, Nathan D, Ivie, Jeffrey A, Parida, Keshaba N, McGrath, Dominic V, Monti, Oliver L. A

“…Improved understanding of charge-transport in single molecules is essential for harnessing the potential of molecules, e.g., as circuit components at the…”
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Transition-Metal-Free Intermolecular α‑Arylation of Ketones via Enolonium Species by Maksymenko, Shimon, Parida, Keshaba N, Pathe, Gulab K, More, Atul A, Lipisa, Yuriy B, Szpilman, Alex M

“…Herein it is shown, for the first time, that enolonium species are powerful electrophiles capable of reacting with aromatic compounds in an intermolecular…”
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Chemistry of the Au–Thiol Interface through the Lens of Single-Molecule Flicker Noise Measurements by Rashid, Umar, Bro-Jørgensen, William, Harilal, KB, Sreelakshmi, PA, Mondal, Reetu Rani, Chittari Pisharam, Varun, Parida, Keshaba N., Geetharani, K., Hamill, Joseph M., Kaliginedi, Veerabhadrarao

“…Chemistry of the Au–S interface at the nanoscale is one of the most complex systems to study, as the nature and strength of the Au–S bond change under…”
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Enolonium Species—Umpoled Enolates by Arava, Shlomy, Kumar, Jayprakash N., Maksymenko, Shimon, Iron, Mark A., Parida, Keshaba N., Fristrup, Peter, Szpilman, Alex M.

“…Enolonium species/iodo(III)enolates of carbonyl compounds have been suggested to be intermediates in a wide variety of hypervalent iodine induced chemical…”
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Correlated Energy-Level Alignment Effects Determine Substituent-Tuned Single-Molecule Conductance by Ivie, Jeffrey A, Bamberger, Nathan D, Parida, Keshaba N, Shepard, Stuart, Dyer, Dylan, Saraiva-Souza, Aldilene, Himmelhuber, Roland, McGrath, Dominic V, Smeu, Manuel, Monti, Oliver L.A

“…The rational design of single-molecule electrical components requires a deep and predictive understanding of structure–function relationships. Here, we explore…”
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α‑N‑Heteroarylation and α‑Azidation of Ketones via Enolonium Species by More, Atul A, Pathe, Gulab K, Parida, Keshaba N, Maksymenko, Shimon, Lipisa, Yuriy B, Szpilman, Alex M

“…Enolonium species, resulting from the umpolung of ketone enolates by Koser’s hypervalent iodine reagents activated by boron trifluoride, react with a variety…”
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Correction to “Unsupervised Segmentation-Based Machine Learning as an Advanced Analysis Tool for Single Molecule Break Junction Data” by Bamberger, Nathan D, Ivie, Jeffrey A, Parida, Keshaba N, McGrath, Dominic V, Monti, Oliver L. A

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Dioxirane‐Based Stereoselective and Oxidative Transformations by Neogi, Ishita, Parida, Keshaba N.

“…The synthesis of chiral organic molecules is a purity‐driven research that has become an essential part of our lives due to their applications in…”
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Construction and topological studies of a three dimensional (3D) coordination polymer showing selective adsorption of aromatic hazardous dyes by Ahmed, Adeeba, Ali, Arif, Ahmed, Mohsina, Parida, Keshaba N., Ahmad, Musheer, Ahmad, Aiman

“…The coordination polymer was constructed exhibit unique structural properties revealed through topological studies, possess quite better selective adsorption…”
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Grid-Based Correlation Analysis to Identify Rare Quantum Transport Behaviors by Bamberger, Nathan D., Dyer, Dylan, Parida, Keshaba N., McGrath, Dominic V., Monti, Oliver L. A.

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Beyond Simple Structure–Function Relationships: The Interplay of Geometry, Electronic Structure, and Molecule/Electrode Coupling in Single-Molecule Junctions by Bamberger, Nathan D., Dyer, Dylan, Parida, Keshaba N., El-Assaad, Tarek H., Pursell, Dawson, McGrath, Dominic V., Smeu, Manuel, Monti, Oliver L. A.

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Grid-Based Correlation Analysis to Identify Rare Quantum Transport Behaviors by Bamberger, Nathan D, Dyer, Dylan, Parida, Keshaba N, McGrath, Dominic V, Monti, Oliver L. A

“…Journal of Physical Chemistry C, 2021 Most single-molecule transport experiments produce large and stochastic datasets containing a wide range of behaviors,…”
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Beyond Simple Structure-Function Relationships: Interplay Between Cis/Trans Isomerization and Geometrically Constrained Metal/Molecule Coupling Efficiency in Single-Molecule Junctions by Bamberger, Nathan D, Dyer, Dylan, Parida, Keshaba N, El-Asssad, Tarek H, Pursell, Dawson, McGrath, Dominic V, Smeu, Manuel, Monti, Oliver L. A

“…Structure-function relationships constitute an important tool to investigate the fundamental principles of molecular electronics. Most commonly, this involves…”
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Unsupervised Segmentation-Based Machine Learning as an Advanced Analysis Tool for Single Molecule Break Junction Data by Bamberger, Nathan D, Ivie, Jeffrey A, Parida, Keshaba N, McGrath, Dominic V, Monti, Oliver L. A

“…Improved understanding of charge-transport in single molecules is essential for harnessing the potential of molecules e.g. as circuit components at the…”
Get full text

Correlated Energy-Level Alignment Effects Determine Substituent-Tuned Single-Molecule Conductance by Ivie, Jeffrey A, Bamberger, Nathan D, Parida, Keshaba N, Shepard, Stuart, Dyer, Dylan, Saraiva-Souza, Aldilene, Himmelhuber, Roland, McGrath, Dominic V, Smeu, Manuel, Monti, Oliver L. A

“…The rational design of single molecule electrical components requires a deep and predictive understanding of structure-function relationships. Here we explore…”
Get full text