Search Results - "Panigrahi, Adyasha"
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Transition-Metal-Free Decarboxylative Iodination: New Routes for Decarboxylative Oxidative Cross-Couplings
Published in Journal of the American Chemical Society (23-08-2017)“…Constructing products of high synthetic value from inexpensive and abundant starting materials is of great importance. Aryl iodides are essential building…”
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Ag(I)–C–H Activation Enables Near-Room-Temperature Direct α‑Arylation of Benzo[b]thiophenes
Published in Journal of the American Chemical Society (01-08-2018)“…The first example of near-room-temperature α-arylation of benzo[b]thiophenes is reported. The discovery rests on the observation of a switch in…”
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Ruthenium‐Catalyzed C−H Arylation of Benzoic Acids and Indole Carboxylic Acids with Aryl Halides
Published in Chemistry : a European journal (12-01-2017)“…Herein we report the first Ru‐catalyzed C−H arylation of benzoic acids with readily available aryl (pseudo)halides. The reaction, which does not require the…”
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Insights into the exfoliation mechanism of pyrene-assisted liquid phase exfoliation of graphene from lateral size-thickness characterisation
Published in Carbon (New York) (01-01-2022)“…Assisted Liquid-Phase Exfoliation (LPE) with pyrene derivatives has been shown to be very effective at producing stable and concentrated 2D material…”
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Ag/Pd Cocatalyzed Direct Arylation of Fluoroarene Derivatives with Aryl Bromides
Published in ACS catalysis (07-02-2020)“…Diverse C–H functionalizations catalyzed by Pd employ Ag(I) salts added as halide abstractors or oxidants. Recent reports have shown that Ag can also perform…”
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Palladium catalysed C-H arylation of pyrenes: access to a new class of exfoliating agents for water-based graphene dispersions
Published in Chemical science (Cambridge) (28-01-2020)“…A new and diverse family of pyrene derivatives was synthesised via palladium-catalysed C-H ortho -arylation of pyrene-1-carboxylic acid. The strategy affords…”
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Decarboxylative and C-H Activation Based Novel Methodologies for the Functionalisation of (Hetero)Arenes and Benzoic Acids
Published 01-01-2019“…Arylcarboxylic acids have been recognised as useful substrates for various chemical transformations either for their directing behaviour or decarboxylative…”
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Dissertation -
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Effects of Lateral Size, Thickness, and Stabilizer Concentration on the Cytotoxicity of Defect-Free Graphene Nanosheets: Implications for Biological Applications
Published in ACS applied nano materials (23-09-2022)“…In this work, we apply liquid cascade centrifugation to highly concentrated graphene dispersions produced by liquid-phase exfoliation in water with an…”
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Journal Article